Abstract
Thermal lensing colorimetry has been applied to the determination of nitrite ion. Color development was based on the diazo-coupling reaction among NO<sub>2</sub><sup>−</sup>, N-(naphthyl)-ethylenediamine dihydrochloride, and sulfanylamide. The source was the chopped output of an Ar<sup>+</sup> laser operated at 514.5 nm. The beam intensity was measured with a silicon photocell of 1 mm<sup>2</sup> surface area and the resultant electrical signal was processed with a microcomputer system. The minimal detectable amount of nitrite ion using a cell of 1 cm path length is 0.2 n<i>M</i>. This is more than 200 times smaller than the detection limit of ordinary spectrophotometry using a commercial spectrophotometer.
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