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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 41,
  • Issue 7,
  • pp. 1251-1253
  • (1987)

Identification of the Isomers of Carvomenthol by an Infrared Study of the OH-Stretching Vibration

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Abstract

A natural mixture of carvomenthols has been separated by HPLC into its four possible isomers. The infrared spectra of the OH-stretching vibration have been recorded for each of these components as a solution in CCI<sub>4</sub> and CS<sub>2</sub>. Identification of the isomers followed, on the basis of these spectral data and those of some reference compounds. Evidence is found for a ring-conversion equilibrium in iso-carvomenthol at ambient temperature.

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