Abstract
A mixture of SF<sub>6</sub>-O<sub>2</sub> is irradiated by an infrared (10.6 μm) cw CO<sub>2</sub> laser. Absorption by SF<sub>6</sub>, and subsequent collisional energy transfer, heats the mixture. Vibrationally excited ground-state O<sub>2</sub> is detected at levels v = 0, 1, and 2 by laser-induced fluorescence in the <i>B</i><sup>3</sup> Σ<sup>-</sup><sub>u</sub>-<i>X</i><sup>3</sup>Σ<sup>-</sup><sub><i>g</i></sub> – Schumann-Runge system with an ArF laser (193.3 nm). Comparison of the observed LIF spectrum with spectra simulated at various temperatures shows that the molecular oxygen in the IR laser beam is thermalized at a temperature of about 700 K.
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