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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 45,
  • Issue 4,
  • pp. 543-545
  • (1991)

SERS Microscopy: Laser Illumination Effects

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Abstract

Hadamard transform SERS microscopy of pyridine at Ag electrodes with focused 514.5-nm, 532.0-nm, and 632.8-nm excitation is reported. It is shown that focused 514.5-nm and 532.0-nm laser excitation produces photochemical or photothermal damage at roughened Ag electrodes. Photo-damage limits the spatial resolution of SERS microprobe and raster-scanned point imaging techniques which use focused green excitation at Ag electrodes.

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