Abstract
This study indicates that intermolecular complexes exist between tetraal-kylurea and carbon tetrachloride and between tetraalkylurea and chloroform. The type of complex or complexes formed is dependent upon the mole % CCl<sub>4</sub>/C<sub>6</sub>H<sub>14</sub> or mole % CHCl<sub>3</sub>/C<sub>6</sub>H<sub>14</sub>. Intermolecular hydrogen-bonded complexes between tetraalkylurea and chloroform (such as I; I and II; II and III; and III) are formed as the mole % CHCl<sub>3</sub>/C<sub>6</sub>H<sub>14</sub> increases. The steady decrease in the <i>v</i>C=O frequency is attributed in part to the bulk dielectric effects of the solvent system.
PDF Article
More Like This
Supercontinuum generation in an all-normal dispersion large core photonic crystal fiber infiltrated with carbon tetrachloride
Van Thuy Hoang, Rafal Kasztelanic, Adam Filipkowski, Grzegorz Stępniewski, Dariusz Pysz, Mariusz Klimczak, Sławomir Ertman, Van Cao Long, Tomasz R. Woliński, Marek Trippenbach, Khoa Dinh Xuan, Mateusz Śmietana, and Ryszard Buczyński
Opt. Mater. Express 9(5) 2264-2278 (2019)
Cited By
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Login to access Optica Member Subscription