Abstract

Solid-state mid- and near-IR photoacoustic (PA) spectra have been measured at room temperature for the group 6B metal(0) mixed carbonyl-<i>t</i>-butylisocyanide complexes <i>M</i>(CO)_6-<i>n</i>(CN^<i>t</i>Bu)<i>n</i> (<i>M</i> = Cr, Mo, W; <i>n</i> = 1-3). Vibrational assignments are proposed for many of the observed bands. The PA spectra in the near-IR region (4600-3600 cm⁻¹), where the binary ν(CN) and ν(CO) overtones and combinations absorb, are useful spectral fingerprints for these organometallic complexes.

Photoacoustic spectra of MoS₂

K. Douglas Carlson and David Hodul
Appl. Opt. 22(18) 2893-2896 (1983)

1.53 W all-solid-state nanosecond pulsed mid-infrared laser at 6.45 µm

Ze Lv, Yu Shen, Nan Zong, Qi Bian, Er-Peng Wang, Jin-Quan Chang, Yong Bo, Da-Fu Cui, and Qin-Jun Peng
Opt. Lett. 47(6) 1359-1362 (2022)

Method to derive the infrared complex refractive indices n(λ) and k(λ) for organic solids from KBr pellet absorption measurements

Kelly A. Peterson, Ryan M. Francis, Catherine A. Banach, Ashley M. Bradley, Sarah D. Burton, Jeremy D. Erickson, Schuyler P. Lockwood, Karissa L. Jensen, Michael O. Yokosuk, Timothy J. Johnson, and Tanya L. Myers
Appl. Opt. 63(6) 1553-1565 (2024)

Quenching of Infrared Chemiluminescence. 1: The Rates of De-Excitation of CO (4 ≤ v ≤ 13) by He, CO, NO, N₂, O₂, OCS, N₂O, and CO₂

G. Hancock and I. W. M. Smith
Appl. Opt. 10(8) 1827-1842 (1971)

Spectroscopic line parameters for the ν₆ band of carbonyl fluoride

Aaron Goldman, Curtis P. Rinsland, Ronald D. Blatherwick, and Francis S. Bonomo
Appl. Opt. 29(13) 1860-1863 (1990)