Abstract

The feasibility of predicting concentrations of methanol and methyl <i>tert</i>-butyl ether (MTBE) in gasolines from the mid-infrared absorption spectra was investigated. The C-O bond stretching band region was related to these oxygenated compounds' levels with the aid of multivariate statistics. The sample spectra were taken with the use of a circular internal reflectance (CIRCLE®) cell. With the use of partial least-squares (PLS) regression a model with 18 samples was built and used to predict a set of 10 gasolines with good agreement. Two additional samples prepared with other brands of gasoline were analyzed with the same model and no matrix effects were found.

Evaluation of univariate and multivariate calibration strategies for the direct determination of total carbon in soils by laser-induced breakdown spectroscopy: tutorial

Wesley Nascimento Guedes, Diego Victor Babos, Vinícius Câmara Costa, Carla Pereira De Morais, Vitor da Silveira Freitas, Kleydson Stenio, Alfredo Augusto Pereira Xavier, Luís Carlos Leva Borduchi, Paulino Ribeiro Villas-Boas, and Débora Marcondes Bastos Pereira Milori
J. Opt. Soc. Am. B 40(5) 1319-1330 (2023)

Terahertz quantitatively distinguishing gasoline mixtures using multiparameter-combined analysis

Yi-nan Li, Zhou-mo Zeng, Jian Li, Zhen Tian, Li-jun Sun, and Nan Zhou
Appl. Opt. 52(30) 7382-7388 (2013)

Quantitative analysis of chromium in potatoes by laser-induced breakdown spectroscopy coupled with linear multivariate calibration

Tianbing Chen, Lin Huang, Mingyin Yao, Huiqin Hu, Caihong Wang, and Muhua Liu
Appl. Opt. 54(25) 7807-7812 (2015)

Determination of glucose in whole blood samples by mid-infrared spectroscopy

Yoen-Joo Kim, Sangjoon Hahn, and Gilwon Yoon
Appl. Opt. 42(4) 745-749 (2003)

Determination of elemental impurities in plastic calibration standards using laser-induced breakdown spectroscopy

Krishna K. Ayyalasomayajula, Dustin L. McIntyre, Jinesh Jain, Jagdish P. Singh, and Fang Yu-Yueh
Appl. Opt. 51(7) B143-B148 (2012)