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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 48,
  • Issue 4,
  • pp. 531-534
  • (1994)

Vibrational Studies of 13C- and 34S-Labeled Bis(ethylenedithio)tetrathiafulvalene (ET) Donor Molecule

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Abstract

FT-IR and FT-Raman studies of <sup>13</sup>C- and <sup>34</sup>S-labeled bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) electron-donor molecules were made, and the results are presented. Assignments for fundamental vibrations in ET were verified. Spectral data suggest that ET has no center of symmetry (confirming X-ray data) and that the data can be reconciled by a <i>D</i>-type point group with only slight interactions occurring between the four molecules per unit cell.

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