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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 66,
  • Issue 3,
  • pp. 282-288
  • (2012)

Application of Raman Multivariate Curve Resolution to Solvation-Shell Spectroscopy

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<b>Raman spectroscopy and multivariate curve resolution (Raman-MCR) are combined to yield a powerful spectroscopic method for identifying solute-induced perturbations of solvent molecules. The principles and applications of the resulting solvation-shell spectroscopy are described and illustrated using both numerical model spectra and experimental Raman spectra, including water in acetone and aqueous OH<sup>−</sup>, as well as of both neutral and ionic acetic acid solutions. The results illustrate the quantitative capabilities of Raman-MCR as a solvation-shell spectroscopy, including fundamental limitations arising from “intensity” and “rotational” ambiguities.</b>

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