Table 1
Radial parameters for Ru i (cm−1).
Parameter | Number of observations |
---|
Forty-two | Fifty-three |
---|
A(4d8) | 15 043±89 | 14 752±50 |
A(4d7 5s) | 14 576±91 | 14 518±40 |
A(4d6 5s2) | 20 001±1460 | 20 874±106 |
B(4d8) | 514.7±13 | 485.7±7 |
B(4d7 5s) | 535.1±7 | 542.6±3 |
B(4d6 5s2) | 560.4±69 | 596.7±4 |
C(4d8) | 2159.8±205 | 2412.6±60 |
C(4d7 5s) | 2567.4±25 | 2578.6±11 |
C(4d6 5s2) | 2801.3±78 | 2740.4±18 |
ζ(4d8) | 880.7±62 | 837.8±30 |
ζ(4d7 5s) | 906.7±22 | 915.9±16 |
ζ(4d6 5s2) | 1054.2±78 | 970.6±23 |
G2 | 1780.6±21 | 1736.0±11 |
H2 | 334.5±4 | 329.9±2 |
α | 28.6±3.5 | 29.41±0.8 |
Mean error | ±126 | ±63 |
Mean deviation | ±101 | ±54 |
Table 2
Eigenvalues and percent composition, J = 0 (Ru i).
Obs. E | 9492 | 11 753 | 14 828 | 24 174 | | | | | |
---|
Calc. E | 9503 | 11 733 | 14 904 | 22 346 | 27 948 | 33 411 | 38 893 | 41 454 | 76 048 |
---|
Diff. E | 11 | −20 | 76 | −1828 | | | | | |
---|
d6 s2 | 4 5D | 91.22 | 6.04 | *1.49 | *0.01 | 0.96 | 0.11 | 0.00 | *0.16 | *0.00 |
(2P) | 3P | *2.95 | 57.20 | 0.10 | *35.28 | *3.66 | *0.69 | *0.03 | 0.10 | 0.00 |
(4P) | 3P | 0.39 | 0.68 | 84.38 | 0.02 | 10.83 | 2.20 | *0.18 | 1.32 | 0.00 |
d8 | 3P | *1.80 | 32.72 | *0.18 | 62.41 | *0.74 | 0.21 | 0.70 | 1.24 | 0.00 |
d6 s2 | 4 3P | *1.47 | 0.59 | *12.61 | *1.17 | 37.04 | 17.77 | *2.92 | 26.39 | 0.05 |
d6 s2 | 2 3P | 2.10 | *2.46 | 1.05 | *0.00 | *25.22 | *2.26 | *0.97 | 65.64 | 0.30 |
d6 s2 | 4 1S | 0.04 | *0.05 | 0.15 | *0.00 | *16.26 | 50.25 | *11.70 | *4.05 | 17.49 |
d6 s2 | 0 1S | *0.02 | 0.04 | *0.03 | 0.02 | 4.58 | *14.27 | 0.24 | 0.03 | 80.77 |
d8 | 1S | 0.01 | *0.23 | 0.01 | *1.09 | *0.69 | 12.25 | 83.27 | 1.06 | 1.39 |
Table 3
Eigenvalues, g values, percent composition, J = 1 (Ru i).
Obs. E | 3105 | 9073 | 9620 | 11 786 | 13 982 | 16 713 | 20 242 | 22 293 | 27 561 | | | |
---|
Calc. E | 3102 | 9165 | 9619 | 11 766 | 14 044 | 16 723 | 20 224 | 22 282 | 27 538 | 29 621 | 36 524 | 42 236 |
---|
Diff. E | −3 | 92 | −1 | −20 | 62 | 10 | −18 | −11 | −23 | | | |
---|
Obs. g | 0.000 | 1.795 | 1.985 | 1.684 | 1.441 | 0.676 | 0.927 | 1.35 | | | | |
---|
Calc. g | 0.009 | 1.716 | 2.057 | 1.690 | 1.440 | 0.671 | 0.928 | 1.489 | 1.340 | 0.662 | 0.501 | 1.498 |
---|
Diff. g | 0.009 | −0.079 | 0.072 | 0.006 | −0.001 | −0.005 | 0.001 | 0.14 | | | | |
---|
(4F) | 5F | 98.24 | 0.02 | 0.00 | *0.09 | *0.03 | 1.30 | *0.21 | *0.01 | 0.01 | *0.04 | *0.04 | *0.00 |
d6 s2 | 4 5D | *0.00 | 57.24 | *35.76 | 4.72 | *1.08 | *0.06 | *0.02 | *0.00 | 1.01 | 0.01 | 0.00 | *0.11 |
(4P) | 5P | *0.00 | 22.05 | 55.82 | 21.17 | 0.43 | 0.09 | 0.00 | *0.41 | *0.01 | *0.01 | *0.01 | 0.00 |
(2P) | 3P | 0.02 | *11.39 | *6.07 | 40.60 | 0.90 | 0.56 | 0.13 | *36.14 | *3.23 | *0.85 | *0.00 | 0.10 |
(4P) | 3P | *0.00 | 0.29 | *0.48 | *0.60 | 75.12 | 4.10 | 4.02 | *0.18 | 11.98 | 1.70 | 0.07 | 1.56 |
(3 2D) | 3D | *1.26 | 0.23 | 0.05 | *1.56 | *1.16 | 60.28 | *16.76 | *1.16 | 0.20 | *2.52 | 14.83 | *0.00 |
(1 2D) | 3D | 0.45 | *0.02 | *0.00 | 0.33 | 0.06 | *9.19 | 1.92 | 0.13 | *0.87 | 4.14 | 82.90 | 0.00 |
(2P) | 1P | *0.02 | 0.02 | 0.07 | *0.25 | *10.27 | 15.50 | 73.27 | *0.16 | 0.18 | 0.25 | 0.01 | 0.01 |
d8 | 3P | 0.00 | *4.75 | * 1.59 | 26.40 | 0.19 | 4.46 | *0.00 | 61.13 | *0.47 | *0.09 | 0.00 | 0.91 |
d6 s2 | 4 3P | 0.00 | *1.59 | 0.11 | 1.69 | *10.05 | *0.61 | *1.74 | *0.63 | 43.31 | 6.86 | 0.00 | 33.39 |
d6 s2 | 2 3P | *0.00 | 2.24 | *0.02 | *2.55 | 0.71 | *0.02 | 0.32 | *0.00 | *23.87 | *6.57 | 0.00 | 63.70 |
d6 s2 | 4 3D | *0.02 | 0.15 | *0.03 | *0.05 | *0.00 | 3.81 | *1.59 | *0.13 | *14.87 | 76.96 | *2.16 | 0.22 |
Table 4
Eigenvalues, g values, percent composition, J = 2 (Ru i).
Obs. E | 2713 | 8044 | 9058 | 9184 | 10 624 | 11447 | 13 646 | 15 054 | 17 046 | 20 934 | 22 343 | 23 453 | 24 927 | | 29 352 | | | | | | |
---|
Calc. E | 2703 | 8227 | 9047 | 9167 | 10 660 | 11 481 | 13 670 | 14 970 | 17 055 | 20 934 | 22 194 | 23 485 | 24 887 | 26 875 | 29 397 | 33 905 | 36 779 | 42 331 | 43 019 | 44 308 | 60 368 |
---|
Diff. E | −10 | 183 | −11 | −17 | 36 | 34 | 24 | −84 | 9 | 0 | −149 | 32 | −40 | | 45 | | | | | | |
---|
Obs. g | 1.000 | 1.536 | 1.232 | 1.089 | 1.534 | 0.764 | 1.315 | 1.162 | 1.175 | 1.343 | 0.697 | 1.162 | | | | | | | | | |
---|
Calc. g | 1.001 | 1.562 | 1.474 | 0.851 | 1.541 | 0.762 | 1.301 | 1.172. | 1.176 | 1.335 | 0.693 | 1.149 | 1.462 | 0.677 | 1.180 | 1.005 | 1.162 | 1.021 | 0.694 | 1.451 | 1.000 |
---|
Diff. g | 0.001 | 0.026 | 0.242 | −0.237 | 0.007 | −0.002 | −0.014 | 0.010 | 0.001 | −0.008 | −0.004 | −0.013 | | | | | | | | | |
---|
(4F) | 5F | 98.56 | 0.01 | *0.01 | 0.14 | *0.08 | *0.05 | 0.00 | 0.07 | 0.99 | *0.02 | 0.02 | 0.00 | 0.00 | 0.01 | *0.02 | *0.00 | *0.02 | *0.00 | *0.00 | *0.00 | 0.00 |
(4P) | 5P | 0.00 | 35.73 | *24.45 | 0.32 | 35.46 | 0.84 | 1.22 | *0.82 | 0.18 | *0.67 | *0.02 | 0.20 | *0.00 | 0.00 | *0.02 | *0.00 | *0.05 | 0.00 | 0.00 | 0.00 | 0.00 |
d6s2 | 4 5D | *0.00 | 13.64 | 59.50 | 19.36 | 5.38 | 0.76 | *0.33 | 0.05 | *0.01 | 0.00 | *0.04 | *0.08 | 0.68 | 0.03 | *0.07 | *0.01 | 0.00 | 0.00 | *0.01 | *0.04 | 0.00 |
(4F) | 3F | *0.21 | *4.55 | *11.67 | 73.34 | *2.22 | 0.00 | *1.88 | *1.35 | 0.96 | 0.12 | 1.20 | 0.66 | 0.03 | *1.45 | *0.03 | 0.18 | *0.03 | *0.01 | *0.11 | 0.00 | 0.00 |
(2P) | 3P | 0.02 | *25.44 | 2.06 | *0.01 | 18.61 | 1.92 | 2.11 | *7.15 | 0.20 | *25.38 | *1.05 | 13.80 | *1.41 | 0.05 | *0.60 | 0.07 | *0.01 | *0.00 | 0.00 | 0.11 | 0.00 |
d8 | 3F | 0.00 | 0.04 | *0.09 | *0.00 | *3.69 | 77.05 | 5.97 | 3.96 | *0.14 | 0.01 | 7.13 | 0.60 | 0.04 | 0.41 | *0.01 | 0.03 | 0.01 | 0.03 | 0.77 | *0.00 | 0.00 |
(4P) | 3P | *0.00 | 1.64 | 0.15 | 0.23 | *7.76 | *2.26 | 48.55 | *20.92 | *0.01 | *0.45 | *0.05 | *0.08 | 15.85 | *0.01 | 0.36 | 0.02 | 0.06 | *0.48 | 0.04 | 1.08 | 0.00 |
(3 2D) | 1D | 0.00 | 1.27 | 0.11 | *2.17 | *0.94 | 1.45 | *10.00 | *19.04 | 1.34 | 12.56 | *0.15 | 24.09 | 2.63 | 1.02 | *0.51 | 0.26 | *0.00 | 19.67 | *1.04 | 1.73 | *0.00 |
(1 2D) | 1D | *0.00 | *0.19 | *0.02 | 0.60 | 0.06 | *0.46 | 2.54 | 2.42 | *0.00 | *2.51 | 0.68 | *2.39 | *0.28 | *0.06 | 0.70 | *35.34 | 1.65 | 44.44 | *1.50 | 2.40 | *1.77 |
(3 2D) | 3D | *0.81 | 0.69 | 0.06 | *0.22 | *0.95 | *0.26 | 0.44 | 5.12 | 69.19 | *1.09 | *0.31 | 1.03 | 0.09 | *0.10 | *2.35 | 0.36 | 16.61 | *0.30 | *0.00 | *0.03 | 0.00 |
(1 2D) | 3D | 0.32 | *0.05 | *0.06 | 0.06 | 0.36 | 0.18 | *0.34 | *1.14 | *12.00 | 0.52 | *0.08 | 0.01 | *0.23 | *0.18 | 4.53 | 0.95 | 78.68 | *0.29 | 0.00 | *0.01 | *0.00 |
d8 | 3P | 0.00 | *9.98 | 0.44 | *0.01 | 14.78 | 0.69 | 5.15 | *4.16 | 6.31 | 40.50 | 1.18 | *13.35 | *2.70 | *0.01 | *0.01 | *0.04 | 0.00 | *0.06 | 0.01 | 0.63 | *0.00 |
(2F) | 33F | *0.04 | *0.00 | 0.02 | *0.00 | 0.20 | *4.70 | *0.37 | *0.39 | 0.12 | *1.25 | 49.37 | 0.01 | 0.01 | 42.58 | 0.07 | 0.15 | 0.36 | *0.34 | *0.00 | *0.02 | 0.00 |
d8 | 1D | *0.00 | *0.98 | *0.00 | 0.70 | 2.52 | *6.23 | 12,36 | 27.50 | *3.14 | 12.80 | 0.00 | 31.40 | 1.60 | 0.22 | *0.02 | 0.02 | *0.01 | 0.00 | *0.00 | *0.01 | 0.49 |
d6 s2 | 4 3P | 0.00 | *2.49 | *0.18 | *0.22 | 3.76 | 0.69 | *6.97 | 2.48 | 0.13 | *0.23 | 0.00 | *1.25 | 42.70 | *0.07 | 2.13 | *0.90 | 0.00 | *3.38 | 0.44 | 31.92 | 0.05 |
d6 s2 | 2 3P | *0.00 | 2.66 | 0.11 | 0.16 | *2.62 | *0.29 | 0.38 | *0.05 | *0.39 | 0.01 | *0.00 | 1.57 | *27.59 | 0.03 | *3.08 | *0.30 | 0.01 | *3.95 | 0.48 | 56.31 | 0.02 |
d6 s2 | 4 3F | *0.00 | *0.24 | *0.73 | 2.15 | *0.22 | 0.58 | 0.02 | 0.07 | 0.01 | 0.31 | *33.02 | *1.04 | 0.00 | 45.39 | *0.01 | *1.20 | 0.08 | 0.18 | 14.63 | *0.11 | 0.02 |
d6 s2 | 2 3F | *0.00 | 0.01 | 0.09 | *0.07 | 0.13 | *1.45 | *0.14 | *0.13 | *0.00 | *0.07 | 5.14 | 0.05 | 0.02 | *7.74 | *0.61 | 0.78 | 0.02 | 5.25 | 78.15 | *0.05 | 0.10 |
d6 s2 | 4 3D | *0.01 | 0.18 | 0.20 | 0.02 | *0.05 | *0.00 | 0.07 | 0.04 | 4.40 | *0.03 | *0.10 | 1.47 | *4.00 | 0.00 | 83.43 | 2.30 | *2.38 | 0.19 | 0.49 | 0.50 | *0.13 |
d6 s2 | 4 1D | *0.00 | *0.16 | *0.03 | 0.18 | 0.12 | *0.08 | 0.91 | 2.31 | *0.28 | *1.48 | *0.35 | *6.56 | 0.00 | 0.46 | *0.60 | 41.70 | *0.00 | 20.12 | *2.31 | 4.13 | 18.23 |
d6 s2 | 2 1D | *0.00 | 0.05 | 0.01 | *0.03 | *0.07 | 0.05 | *0.23 | *0.83 | 0.18 | 0.01 | 0.13 | 0.36 | *0.15 | *0.19 | 0.83 | *15.41 | 0.02 | *1.31 | 0.02 | *0.93 | 79.18 |
Table 5
Eigenvalues, g values, percent composition. J = 3 (Ru i).
Obs. E | 2092 | 8084 | 8575 | 8771 | 10 655 | 13 699 | 16 191 | 22 419 | | 26 076 | 27 517 | 29 979 | | | |
---|
Calc. E | 2073 | 8083 | 8502 | 8812 | 10 682 | 13 697 | 16 239 | 22 246 | 25 210 | 26 031 | 27 535 | 29 397 | 37 179 | 39 308 | 43 571 |
---|
Diff. E | −19 | −1 | −73 | 41 | 27 | −2 | 48 | −173 | | −45 | 18 | −582 | | | |
---|
Obs. g | 1.249 | 1.196 | 1.420 | 1.624 | 1.086 | 0.757 | 1.333 | 1.070 | | | | | | | |
---|
Calc. g | 1.249 | 1.200 | 1.391 | 1.652 | 1.084 | 0.757 | 1.332 | 1.076 | 0.970 | 0.902 | 0.975 | 1.329 | 1.326 | 1.015 | 1.074 |
---|
Diff. g | 0 | 0.004 | −0.029 | 0.028 | −0.002 | 0 | −0.001 | 0.006 | | | | | | | |
---|
(4F) | 5F | 98.77 | 0.30 | 0.13 | *0.06 | *0.03 | *0.10 | 0.53 | 0.05 | 0.00 | 0.00 | 0.01 | *0.01 | *0.00 | 0.00 | *0.00 |
(4F) | 3F | *0.54 | 65.77 | 25.68 | *2.08 | *0.99 | 1.01 | 0.87 | 1.67 | *0.01 | *0.24 | *0.99 | *0.00 | *0.01 | *0.04 | *0.09 |
d6 s2 | 4 5D | *0.00 | *26.68 | 72.03 | *0.22 | 0.38 | 0.00 | *0.05 | *0.22 | 0.01 | 0.02 | 0.12 | *0.23 | 0.00 | *0.00 | *0.02 |
(4P) | 5P | 0.01 | 0.89 | 1.30 | 96.91 | *0.00 | *0.00 | 0.67 | 0.00 | 0.00 | *0.00 | 0.00 | *0.03 | *0.18 | 0.00 | 0.00 |
d8 | 3F | 0.00 | 0.76 | *0.00 | *0.01 | 92.03 | 0.30 | *0.00 | 5.74 | 0.09 | 0.19 | 0.12 | *0.00 | 0.02 | 0.11 | 0.62 |
(2G) | 3G | 0.15 | *0.71 | *0.27 | 0.02 | *0.10 | 94.89 | 0.02 | *0.58 | 1.24 | 0.56 | *1.44 | *0.01 | *0.00 | *0.02 | 0.00 |
(3 2D) | 3D | *0.32 | *0.69 | *0.15 | *0.16 | 0.02 | *0.03 | 75.81 | *0.03 | *0.55 | 0.00 | *0.17 | *0.95 | 20.86 | *0.25 | *0.02 |
(12 D) | 3D | 0.14 | 0.30 | 0.11 | 0.47 | 0.00 | 0.01 | *17.88 | *0.25 | *0.25 | 0.00 | *0.16 | 5.92 | 73.26 | *1.2S | *0.00 |
(2F) | 3F | *0.06 | *0.23 | *0.00 | 0.00 | *4.44 | 0.17 | 0.03 | 45.41 | 7.16 | 17.05 | 24.68 | 0.09 | 0.65 | *0.00 | *0.01 |
(2F) | 1F | *0.00 | *0.05 | *0.02 | 0.00 | *0.00 | *0.33 | 0.04 | 0.15 | 57.72 | *26.65 | *0.11 | *0.30 | 0.07 | *13.53 | 1.03 |
d6 s2 | 4 3G | *0.00 | 0.04 | 0.01 | *0.00 | 0.03 | *3.13 | 0.00 | *2.07 | 16.22 | 46.44 | *31.39 | *0.09 | *0.01 | *0.17 | 0.42 |
d6 s2 | 4 3F | *0.00 | 3.05 | 0.16 | *0.05 | 0.37 | 0.00 | 0.10 | *36.21 | 4.37 | 3.89 | 34.62 | *0.47 | 0.23 | 2.09 | 14.38 |
d6 s2 | 2 3F | 0.00 | *0.39 | 0.01 | 0.00 | *1.58 | 0.00 | *0.03 | 7.44 | *0.81 | *2.10 | *5.81 | *0.31 | 0.27 | 9.90 | 71.33 |
d6 s2 | 4 3D | *0.00 | *0.13 | 0.13 | *0.01 | 0.02 | *0.00 | 3.95 | *0.17 | 0.19 | *0.00 | 0.00 | 91.23 | *3.03 | *0.05 | 1.08 |
d6 s2 | 4 1F | *0.00 | *0.00 | 0.00 | *0.00 | *0.00 | *0.04 | 0.02 | *0.00 | 11.38 | *2.86 | *0.39 | 0.35 | 1.39 | 72.58 | *11.00 |
Table 6
Eigenvalues, g values, percent composition, J = 4 (Ru i).
Obs. E | 1191 | 6545 | 7483 | 9121 | 12 817 | 14 700 | 17 097 | 21 643 | 23 005 | 23 393 | 25 643 | 27 289 | | 42 895 | |
---|
Calc. E | 1166 | 6530 | 7413 | 9084 | 12 802 | 14 691 | 17 101 | 21 703 | 22 997 | 23 397 | 25 655 | 27 311 | 31 719 | 42 888 | 48 417 |
---|
Diff. E | −25 | −15 | −70 | −37 | −15 | −9 | 4 | 60 | −8 | 4 | 12 | 22 | | −7 | |
---|
Obs. g | 1.349 | 1.284 | 1.447 | 1.255 | 1.033 | 0.992 | 0.834 | 1.08 | 0.91 | 0.950 | | | | | |
---|
Calc. g | 1.347 | 1.274 | 1.462 | 1.254 | 1.030 | 0.998 | 0.835 | 1.128 | 0.982 | 0.971 | 1.088 | 1.172 | 1.010 | 1.245 | 1.004 |
---|
Diff. g | −0.002 | −0.010 | 0.015 | −0.001 | −0.003 | 0.006 | 0.001 | −0.05 | 0.07 | 0.021 | | | | | |
---|
(4F) | 5F | 98.38 | 0.96 | 0.14 | *0.03 | *0.36 | *0.06 | *0.01 | *0.03 | *0.01 | 0.00 | 0.00 | 0.02 | *0.00 | *0.00 | *0.00 |
(4F) | 3F | *0.95 | 79.24 | 12.99 | *1.11 | 2.25 | *0.50 | 0.19 | * 1.15 | *0.67 | 0.17 | *0.05 | *0.56 | 0.04 | *0,13 | *0.01 |
d6 s2 | 4 5D | 0.00 | *11.61 | 85.24 | 1.89 | 0.00 | *0.02 | 0.00 | 0.64 | 0.18 | *0.01 | 0.07 | 0.27 | *0.03 | *0.03 | *0.00 |
d8 | 3F | 0.00 | 1.34 | *0.67 | 91.91 | 0.21 | 0.00 | 0.04 | *3.42 | *1.15 | *0.06 | 0.33 | 0.20 | 0.01 | 0.65 | 0.00 |
(2G) | 3G | 0.60 | *0.96 | *0.15 | *0.05 | 77.63 | 13.65 | 2.78 | 1.26 | *0.03 | *0.50 | 0.96 | *1.43 | 0.01 | 0.00 | *0.00 |
(2G) | 1G | *0.01 | 1.48 | 0.31 | *0.00 | *7.53 | 61.15 | *8.02 | *0.62 | 3.02 | *14.54 | 0.00 | 0.03 | 2.38 | *0.01 | 0.90 |
(2H) | 3H | *0.00 | 0.05 | 0.01 | 0.00 | *8.59 | 6.71 | 77.66 | 2.29 | *4.20 | *0.17 | *0.23 | *0.00 | *0.08 | *0.00 | *0.00 |
d6 s2 | 4 3F | *0.01 | 3.27 | *0.12 | 0.18 | 0.04 | *0.26 | 0.00 | 29.49 | 10.57 | *0.67 | 3.98 | 26.82 | *4.94 | 18.87 | 0.80 |
d6 s2 | 2 3F | 0.00 | *0.52 | 0.33 | *1.25 | *0.00 | 0.09 | 0.00 | *7.82 | *2.30 | 0.33 | *2.23 | *5.32 | 0.56 | 78.28 | 0.96 |
d6 s2 | 4 3H | 0.00 | *0.00 | 0.00 | *0.00 | *0.07 | 0.34 | 5.74 | *12.38 | 48.56 | 17.40 | 12.02 | *0.35 | *3.01 | 0.01 | *0.10 |
d8 | 1G | *0.00 | 0.13 | 0.01 | 0.41 | *0.96 | 13.85 | *4.72 | 8.55 | *5.10 | 60.43 | *0.01 | *0.98 | *4.16 | *0.04 | 0.67 |
d6 s2 | 4 3G | *0.01 | 0.05 | *0.00 | 0.02 | *2.20 | *1.03 | *0.49 | 7.05 | *1.89 | *3.45 | 52.27 | *31.01 | 0.00 | 0.37 | *0.16 |
(2F) | 3F | *0.03 | *0.35 | 0.03 | *3.15 | 0.05 | 0.85 | *0.03 | *18.04 | *19.53 | 0.30 | 27.53 | 29.28 | *0.82 | *0.01 | 0.00 |
d6 s2 | 4 1G | 0.00 | *0.00 | *0.01 | 0.01 | 0.08 | *1.13 | 0.01 | 4.14 | *1.90 | 1.10 | 0.29 | 1.81 | 60.84 | *0.18 | 28.51 |
d6 s2 | 2 1G | 0.00 | *0.03 | 0.00 | *0.01 | 0.02 | *0.35 | 0.32 | *3.14 | 0.89 | *0.85 | 0.01 | *1.93 | *23.13 | *1.44 | 67.88 |
Table 7
Eigenvalues, g-values, percent composition, J = 5 (Ru i).
Obs. E | 0 | 12 207 | 16 240 | 20 056 | 22 519 | 25 603 |
---|
Calc. E | −17 | 12 244 | 16 270 | 20 080 | 22 595 | 25 562 |
---|
Diff. E | −17 | 37 | 30 | 24 | 76 | −41 |
---|
Obs. g | 1.397 | 1.190 | 1.041 | 1.007 | 0.99 | |
---|
Calc. g | 1.397 | 1.191 | 1.040 | 1.006 | 1.058 | 1.175 |
---|
Diff. g | 0 | 0.001 | −0.001 | −0.001 | 0.07 | |
---|
(4F) | 5F | 98.67 | * 1.28 | *0.03 | *0.01 | 0.01 | *0.01 |
(2G) | 3G | 1.31 | 89.16 | 3.93 | 1.65 | *1.46 | 2.47 |
(2H) | 3H | *0.01 | *5.58 | 86.65 | 1.66 | *5.93 | *0.18 |
(2H) | 1H | *0.00 | *1.18 | *3.40 | 94.55 | *0.80 | 0.06 |
d6 s2 | 4 3H | 0.00 | *0.02 | 5.28 | 1.30 | 78.40 | 15.00 |
d6 s2 | 4 3G | *0.01 | *2.78 | *0.71 | *0.82 | *13.40 | 82.28 |
Table 8
Eigenvalues, g values, percent composition, J = 6 (Ru i).
Obs. E | 15 550 | 22 162 | |
---|
Calc. E | 15 609 | 22 243 | 29 788 |
---|
Diff. E | 59 | 81 | |
---|
Obs. g | 1.164 | 1.160 | |
---|
Calc. g | 1.167 | 1.163 | 1.004 |
---|
Diff. g | 0.003 | 0.003 | |
---|
(2H) | 3H | 94.89 | *5.09 | 0.03 |
d6 s2 | 4 3H | 5.08 | 92.50 | *2.42 |
d6 s2 | 4 1I | 0.04 | 2.41 | 97.55 |