A Comparison of the Widths of Liquid-Phase Infrared Absorption Bands and of the Corresponding Raman Bands

J. C. Evans

doi:10.1364/JOSA.50.001337

Journal of the Optical Society of America
Vol. 50,
Issue 12,
pp. 1337-1338
(1960)
•https://doi.org/10.1364/JOSA.50.001337

A Comparison of the Widths of Liquid-Phase Infrared Absorption Bands and of the Corresponding Raman Bands

J. C. Evans

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J. C. Evans, "A Comparison of the Widths of Liquid-Phase Infrared Absorption Bands and of the Corresponding Raman Bands," J. Opt. Soc. Am. 50, 1337-1338 (1960)

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Molecule	Band, cm⁻¹	Raman depolarization	Raman^a bandwidth, cm⁻¹	Infrared^a bandwidth, cm⁻¹
Aniline	998	0.08	5.9	5.5
Aniline	1028	0.08	4.9	4.6
Toluene	1030	0.08	2.5^a	3.6^c
Chlorobenzene	1083	0.10	8.1	8.6
Chlorobenzene	1024	0.05	2.0	3.1
Chlorobenzene	1002	0.05	1.6	2.5
Chlorobenzene	702	0.12	5.0	5.0
Chlorobenzene	615	0.74	6.5	3.6
Ethynyl benzene	1599	0.72	6.6	5.4
Acetophenone	1682	0.38	13.9	18.0
Acetophenone	1597	0.56	5.9	4.5
Acetophenone	1264	0.28	8.2	9.4
Acetophenone	1074	0.26	10.3	8.6
Acetophenone	1024	0.10	4.5	5.0
Hexachlorobutadiene	1610	0.17	10.2	10.2
Hexachlorobutadiene	1564	0.89	16.4	14.7
Ethanol	882	0.22	14.2	11.5
Nitromethane	917	0.07	3.0	5.4
Cyclopentanone	886	0.08	5.1	5.0
Acetonitrile	2249	0.20	7.2	7.6^d
Pyridine	1217	dp	13.5	7.7
Pyridine	1030	0.05	3.1	4.8
Pyridine	990	0.05	2.8	3.6
Thiophene	1404	0.35	7.4	8.6
Thiophene	1079	0.43	7.7	10.0
Thiophene	1032	0.11	3.5	5.5
Thiophene	832	0.08	5.1	7.1
Bromoform	3022	0.25	11.4	11.3
Bromoform	655	dp	24.6	<28^b
Bromoform	539	0.10	3.2	4.5
Methylene bromide	3061	dp	17.6	13.7
Methylene bromide	637	0.84	15.6	<18^b
Methylene bromide	576	0.11	5.8	6.9
Br CCl₃	716	0.7	18.3	~17.5
Br CCl₃	778	0.7	26.2	<30^b
Chloroform	667	0.07	5.5	6.3

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