Rydberg Series in N v

S. G. Tilford

doi:10.1364/JOSA.53.001051

Journal of the Optical Society of America
Vol. 53,
Issue 9,
pp. 1051-1054
(1963)
•https://doi.org/10.1364/JOSA.53.001051

Rydberg Series in N v

S. G. Tilford

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S. G. Tilford, "Rydberg Series in N v," J. Opt. Soc. Am. 53, 1051-1054 (1963)

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Abstract

Three complete Rydberg series, 2p ²P°–ns ²S, 2s ²S–np ²P°, and 2p ²P°–nd ²D, extending to the ionization limit have been observed in the spectrum of N v excited in a low-pressure, high-voltage condensed capillary discharge. An ionization limit of 789 516±24 cm⁻¹=97.8816±0.0030 eV has been determined from these long series for N v.

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		$2 s {{}^{2}S}_{\frac{1}{2}} - n p {{}^{2}P}_{\frac{1}{2}} °$				$2 s {{}^{2}S}_{\frac{1}{2}} - n p {{}^{2}P}_{1 \frac{1}{2}} °$
n	Intensity obs	λ calc (Å)	λ obs (Å)	ν ohs (cm⁻¹)	Intensity obs	λ calc (Å)	λ obs (Å)	ν obs (cm⁻¹)
2			1242.803^b	80 463.3^b			1238.805^b	80 723.0^b
3	80		209.306	477 769	80		209.274	477 842
4					48	162.565^a	162.565	615 135
5					24	147.433^a	147.433	678 270
6					16	140.364^a	140.364	712 433
7					8	136.430	136.429	732 982
8					7	133.997	133.994	746 299
9					6	132.381	132.383	755 380
10					5	131.251	131.254	761 880
11					4	130.428	130.431	766 687
12					3	129.809	129.811	770 347
13					2	129.322	129.337	773 174
14					1	128.956	128.954	775 465
15					1	128.654	128.662	777 230
16					0	128.409	128.430	778 634
17					0	128.206	128.229	779 855

		$2 p {{}^{2}P}_{\frac{1}{2}} ° - n d {{}^{2}D}_{1 \frac{1}{2}}$				$2 p {{}^{2}P}_{1 \frac{1}{2}} ° - n d {{}^{2}D}_{2 \frac{1}{2}}$
n	Intensity obs	λ calc (Å)	λ obs (Å)	ν obs (cm⁻¹)	Intensity obs	λ calc (Å)	λ obs (Å)	ν obs (cm⁻¹)
3	85		247.564	403 936	100		247.709	403 700
4	52		186.069	537 433	62		186.153	537 193
5	44		166.881	599 226	52		166.947	598 992
6	24	158.030^a	158.030	632 791	36	158.090^a	158.090	632 549
7	18	153.136^a	153.136	653 016	28	153.192^a	153.192	652 773
8	7	150.116^a	150.116	666 149	14	150.171^a	150.171	665 906
9	4	148.114	148.116	675 145	7	148.167	148.168	674 910
10	3	146.714	146.716	681 585	6	146.766	146.767	681 348
11					5	145.747	145.742	686 143
12					4	144.980	144.978	689 760
13					3	144.390	144.392	692 559
14					2	143.925	143.914	694 858
15					1	143.551	143.520	696 767
16					1	143.247	143.241	698 124
17					0	142.997	142.981	699 394
18					0	142.787	142.797	700 344

		$2 p {{}^{2}P}_{\frac{1}{2}} ° - n s {{}^{2}S}_{\frac{1}{2}}$				$2 p {{}^{2}P}_{1 \frac{1}{2}} ° - n s {{}^{2}S}_{\frac{1}{2}}$
n	Intensity obs	λ calc (Å)	λ obs (Å)	ν obs (cm⁻¹)	Intensity obs	λ calc (Å)	λ obs (Å)	ν obs (cm⁻¹)
3	80		266.197	375 662	84		266.378	375 406
4	20	190.158^a	190.158	525 878	32	190.250^a	190.250	525 622
5	5	168.517^a	168.517	593 412	12	168.590^a	168.590	593 152
6	4	158.867^a	158.867	629 457	7	158.933^a	158.933	629 196
7	3	153.624	153.624	650 940	6	153.686	153.683	650 687
8	2	150.430	150.429	664 764	5	150.489	150.488	664 502
9	1	148.328	148.328	674 180	4	148.386	148.387	673 913
10					3	146.924	146.921	680 637

Configuration	Designation	J	Level	Interval^a
2s	2s ²S	$\frac{1}{2}$	0.0
2p	2p ²P°	$\frac{1}{2}$	80 464.3	259.7
		$1 \frac{1}{2}$	80 723.0
3s	3s ²S	$\frac{1}{2}$	456 127
3p	3p ²P°	$\frac{1}{2}$	477 769	73
		$1 \frac{1}{2}$	477 842
3d	3d ²D	$1 \frac{1}{2}$	484 399	24
		$2 \frac{1}{2}$	484 423	[24]
4s	4s ²S	$\frac{1}{2}$	606 343
4p	4p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	615 135	[32]
4d	4d ²D	$1 \frac{1}{2}$	617 896	20
		$2 \frac{1}{2}$	617 916	[10]
5s	5s ²S	$\frac{1}{2}$	673 875
5p	5p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	678 270	[16]
5d	5d ²D	$1 \frac{1}{2}$	679 689	26
		$2 \frac{1}{2}$	679 715	[5]
6s	6s ²S	$\frac{1}{2}$	709 920
6p	6p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	712 433
6d	6d ²D	$1 \frac{1}{2}$	713 254	18
		$2 \frac{1}{2}$	713 272	[0]
7s	7s ²S	$\frac{1}{2}$	731 407
7p	7p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	732 982
7d	7d ²D	$1 \frac{1}{2}$	733 479	17
		$2 \frac{1}{2}$	733 496	[0]
8s	8s ²S	$\frac{1}{2}$	745 226
8p	8p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	746 299
8d	8d ²D	$1 \frac{1}{2}$	746 612	17
		$2 \frac{1}{2}$	746 629	[0]
9s	9s ²S	$\frac{1}{2}$	754 640
9p	9p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	755 380
9d	9d ²D	$1 \frac{1}{2}$	755 608	25
		$2 \frac{1}{2}$	755 633	[0]
10s	10s ²S	$\frac{1}{2}$	761 360
10p	10p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	761 880
10d	10d ²D	$1 \frac{1}{2}$	762 048	23
		$2 \frac{1}{2}$	762 071	[0]
11p	11p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	766 687
11d	11d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	766 866
12p	12p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	770 347
12d	12d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	770 483
13p	13p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	773 174
13d	13d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	773 282
14p	14p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	775 465
14d	14d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	775 581
15p	15p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	777 230
15d	15d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	777 490
16p	16p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	778 634
16d	16d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	778 847
17p	17p ²P°	${\begin{array}{r} \frac{1}{2} \\ 1 \frac{1}{2} \end{array}}$	779 855
17d	17d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	780 117
18d	18d ²D	${\begin{array}{l} 1 \frac{1}{2} \\ 2 \frac{1}{2} \end{array}}$	781 067

Series designation	Series limit	Ionization limit

	(cm⁻¹)	(cm⁻¹)	(eV)
$2 s {{}^{2}S}_{\frac{1}{2}} - n p {{}^{2}P}_{1 \frac{1}{2}} °$	789 526	789 526	97.8828
$2 p {{}^{2}P}_{1 \frac{1}{2}} ° - n s {{}^{2}S}_{\frac{1}{2}}$	708 771	789 494	97.8789
$2 p {{}^{2}P}_{\frac{1}{2}} ° - n s {{}^{2}S}_{\frac{1}{2}}$	709 033	789 497	97.8793
$2 p {{}^{2}P}_{1 \frac{1}{2}} ° - n d {{}^{2}D}_{2 \frac{1}{2}}$	708 817	789 540	97.8846
$2 p {{}^{2}P}_{\frac{1}{2}} ° - n d {{}^{2}D}_{1 \frac{1}{2}}$	709 058	789 522	97.8824
Average		789 516±24	97.8816±0.0030

Abstract

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Journal of the Optical Society of America