Oscillator Strengths of the Resonance Lines of Krypton and Xenon*

P. M. Griffin; J. W. Hutcherson

doi:10.1364/JOSA.59.001607

Journal of the Optical Society of America
Vol. 59,
Issue 12,
pp. 1607-1613
(1969)
•https://doi.org/10.1364/JOSA.59.001607

Oscillator Strengths of the Resonance Lines of Krypton and Xenon

P. M. Griffin and J. W. Hutcherson

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P. M. Griffin and J. W. Hutcherson, "Oscillator Strengths of the Resonance Lines of Krypton and Xenon*," J. Opt. Soc. Am. 59, 1607-1613 (1969)

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Abstract

The oscillator strengths of the ¹S₀–¹P₁ (1165 Å) and the ¹S₀–³P₁ (1236 Å) resonance transitions in krypton and the ¹S₀–¹P₁ (1296 Å) resonance transition in xenon were determined by the method of total absorption. A 2-m absorbing path and pressures in the range of 0.006–0.064 torr were used. The results were

Kr: ¹S₀–¹P₁ (1165 Å)	f = 0.193±0.009 (39 determinations)
Kr: ¹S₀–³P₁ (1236 Å)	f = 0.187±0.006 (49 determinations)
Xe: ¹S₀–¹P₁ (1296 Å)	f = 0.194±0.005 (35 determinations).

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Corrections

P. M. Griffin and J. W. Hutcherson, "Errata," J. Opt. Soc. Am. 61, 136-136 (1971)
https://opg.optica.org/josa/abstract.cfm?uri=josa-61-1-136

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Equations (19)

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T K	P torr	$N \times 1 0^{- 14} {cm}^{- \frac{3}{2}}$	$N^{\frac{1}{2}} \times 1 0^{- 7} {cm}^{- 3}$	A_G×10^–12 sec⁻¹
303	0.0061	1.94	1.39	0.80
303	0.0061	1.94	1.39	0.89
304	0.0063	2.00	1.41	0.90
304	0.0063	2.00	1.41	0.74
304	0.0063	2.00	1.41	0.86
304	0.0121	3.84	1.96	1.23
303	0.0122	3.89	1.97	1.38
303	0.0122	3.89	1.97	1.03
303	0.0122	3.89	1.97	1.13
303	0.0174	5.54	2.35	1.44
303	0.0174	5.54	2.35	1.67
303	0.0174	5.54	2.35	1.44
304	0.0182	5.78	2.40	1.65
304	0.0232	7.37	2.71	1.87
304	0.0232	7.37	2.71	1.76
304	0.0232	7.37	2.71	1.58
304	0.0240	7.62	2.76	2.11
303	0.0280	8.92	2.99	1.93
303	0.0280	8.92	2.99	1.83
303	0.0280	8.92	2.99	1.59
304	0.0299	9.49	3.08	1.92
304	0.0299	9.49	3.08	1.88
304	0.0299	9.49	3.08	1.96
305	0.0352	11.14	3.34	2.04
304	0.0384	12.19	3.49	2.51
304	0.0384	12.19	3.49	2.21
304	0.0384	12.19	3.49	2.62
305	0.0410	12.97	3.60	2.19
305	0.0469	14.84	3.85	2.36
304	0.0487	15.46	3.93	2.47
304	0.0487	10.46	3.93	2.21
304	0.0487	15.46	3.93	2.52
305	0.0526	16.65	4.08	2.41
305	0.0585	18.51	4.08	2.35
305	0.0585	18.51	4.08	2.66
305	0.0585	18.51	4.08	2.70
304	0.0639	20.29	4.50	3.39
304	0.0639	20.29	4.50	3.09
304	0.0639	20.29	4.50	2.85

T K	P torr	N × 10⁻¹⁴ cm⁻³	$N^{\frac{1}{2}} \times 1 0^{- 7} {cm}^{- \frac{3}{2}}$	A_G × 10⁻¹² sec⁻¹
303	0.0061	1.94	1.39	0.88
303	0.0061	1.94	1.39	0.74
303	0.0061	1.94	1.39	0.89
304	0.0061	1.94	1.39	0.72
304	0.0061	1.94	1.39	0.76
304	0.0061	1.94	1.39	0.73
304	0.0063	2.00	1.41	0.81
304	0.0063	2.00	1.41	0.83
304	0.0063	2.00	1.41	0.79
303	0.0120	3.82	1.95	1.01
304	0.0120	3.81	1.95	1.12
304	0.0121	3.84	1.96	1.13
304	0.0121	3.84	1.96	1.16
303	0.0122	3.89	1.97	1.15
303	0.0122	3.89	1.97	1.26
303	0.0122	3.89	1.97	1.01
304	0.0174	5.52	2.35	1.41
304	0.0174	5.52	2.35	1.46
303	0.0176	5.61	2.37	1.34
304	0.0182	5.78	2.40	1.29
304	0.0232	7.37	2.71	1.64
304	0.0232	7.37	2.71	1.59
304	0.0232	7.37	2.71	1.57
304	0.0240	7.62	2.76	1.40
302	0.0280	8.95	2.99	1.64
302	0.0280	8.95	2.99	1.62
302	0.0280	8.95	2.99	1.64
302	0.0280	8.95	2.99	1.62
304	0.0299	9.49	3.08	1.67
304	0.0299	9.49	3.08	1.61
304	0.0299	9.49	3.08	1.68
305	0.0319	10.10	3.18	1.78
305	0.0319	10.10	3.18	1.76
305	0.0319	10.10	3.18	1.71
304	0.0352	11.18	3.34	1.84
303	0.0384	12.23	3.50	1.98
303	0.0384	12.23	3.50	2.09
303	0.0384	12.23	3.50	1.86
305	0.0410	12.97	3.60	2.20
305	0.0469	14.84	3.85	1.99
304	0.0487	15.46	3.93	2.23
304	0.0487	15.46	3.93	2.72
304	0.0487	15.46	3.93	2.39
305	0.0526	16.65	4.08	2.31
305	0.0586	18.54	4.31	2.43
305	0.0586	18.54	4.31	2.51
305	0.0586	18.54	4.31	2.40
304	0.0639	20.29	4.50	2.89
304	0.0639	20.29	4.50	2.80

T K	P torr	N×10⁻¹⁴ cm⁻³	$N^{\frac{1}{2}} \times 1 0^{- 7} {cm}^{- \frac{3}{2}}$	A_G×10⁻¹² sec⁻¹
304	0.0053	1.68	1.30	0.77
304	0.0053	1.68	1.30	0.79
304	0.0053	1.68	1.30	0.79
305	0.0095	3.01	1.73	1.06
305	0.0095	3.01	1.73	0.92
305	0.0095	3.01	1.73	1.07
304	0.0100	3.18	1.78	1.07
304	0.0100	3.18	1.78	1.27
304	0.0100	3.18	1.78	1.11
304	0.0149	4.73	2.17	1.27
304	0.0149	4.73	2.17	1.30
305	0.0197	6.23	2.50	1.52
305	0.0197	6.23	2.50	1.42
305	0.0197	6.23	2.50	1.31
305	0.0230	7.28	2.70	1.57
305	0.0230	7.28	2.70	1.68
305	0.0230	7.28	2.70	1.49
305	0.0244	7.72	2.78	1.65
305	0.0244	7.72	2.78	1.63
305	0.0244	7.72	2.78	1.70
305	0.0336	10.63	3.26	2.05
305	0.0336	10.63	3.26	1.98
305	0.0336	10.63	3.26	1.97
306	0.0426	13.44	3.67	2.21
306	0.0426	13.44	3.67	2.18
306	0.0426	13.44	3.67	2.09
305	0.0446	14.11	3.76	2.10
305	0.0446	14.11	3.76	2.32
305	0.0446	14.11	3.76	2.21
303	0.0507	16.15	4.02	2.52
303	0.0507	16.15	4.02	2.49
303	0.0507	16.15	4.02	2.44
304	0.0589	18.70	4.32	2.55
304	0.0589	18.70	4.32	2.42
304	0.0589	18.70	4.32	2.61

	Kr 1164.856 Å (¹S₀–5s¹P₁⁰)	Kr 1235.826 Å (¹S₀–5s³P₁⁰)	Xe 1295.580 Å (¹S₀–6s¹P₁⁰)
a[sec⁻¹]	(−0.0563±0.0981)×10¹²	(−0.0652±0.0536)×10¹²	(0.0162±0.0438)×10¹²
$b [\frac{{sec}^{- 1}}{{cm}^{- \frac{3}{2}}}]$	(0.6529±0.0312)×10⁵	(0.5953±0.0182)×10⁵	(0.5908±0.0146)×10⁵
f	0.193 ±0.009	0.187 ±0.006	0.194 ±0.005
τ[sec]	(3.16 ±0.15)×10⁻⁹	(3.68 ±0.11)×10⁻⁹	(3.88 ±0.10)×10⁻⁹
Number of determinations	39	49	35

Experimental	Kr 1164.856 Å ¹S₀–5s¹P₁⁰	Kr 1235.826 Å ¹S₀–5s³P₁⁰	Sum	Xe 1295.580 Å ¹S₀–6s¹P₁⁰
This work	0.193±0.009	0.187±0.006	0.380±0.015	0.194±0.005
R. Turner11	⋯	0.166	⋯	⋯
J. Geiger12	⋯	⋯	0.346±0.06	⋯
Chaschina and Shreider13,14	0.21±0.05	0.21±0.05	0.42±0.10	0.23±0.05
D. K. Anderson16	⋯	⋯	⋯	0.238±0.015
J. M. Vaughan15	0.184±0.02	0.204±0.02	0.388±0.04	⋯
Theoretical

Dow and Knox17	0.136	0.138	0.274	0.147
P. F. Gruzdev19	0.20	0.20	0.400	0.25
J. W. Cooper18	⋯	⋯	0.405	⋯

Abstract

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Figures (6)

Tables (5)

Equations (19)

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