Zeeman Effect of As ii*

Hui Li; Kenneth L. Andrew

doi:10.1364/JOSA.62.000255

Journal of the Optical Society of America
Vol. 62,
Issue 2,
pp. 255-260
(1972)
•https://doi.org/10.1364/JOSA.62.000255

Zeeman Effect of As ii

Hui Li and Kenneth L. Andrew

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Hui Li and Kenneth L. Andrew, "Zeeman Effect of As ii*," J. Opt. Soc. Am. 62, 255-260 (1972)

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Abstract

Spectrograms of As electrodeless-discharge tubes operated in a field of 24 025 G have given Zeeman patterns for 232 As ii spectral lines from 2361 to 10 556 Å and yielded 80 Landé g factors, of which more than half are new. There is agreement between these and the g values calculated by least-squares fitting for single configurations or for multiconfigurations, where configuration interaction is noticeable. All of the measured g values as well as the energy levels are used in the fitting process. However, in the case of one multiconfiguration group, 4s4p³–4p4d–4p5d–4p6d–4p7s, the experimental material does not agree with calculated results unless LS-dependent parameters are used in the least-squares calculations.

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Level code^a	Config.	J	No. trans.^b	No. meas.^c	Expt. av. g	Expt. unc.	G.B.^d
6	4p5p	1	17	41 + 3U	0.816	0.006	0.812
7	4p5p	1	17	29 + 4U	0.892	0.006	0.895
8	4p5p	2	15	21 + 9U	1.181	0.005	1.174
10	4p5p	1	20	41 + 7U	1.391	0.005	1.389
11	4p5p	3	11	21 + 6U	1.332	0.005	1.325
12	4p5p	2	16	25 + 7U	1.441	0.006	1.433
13	4p5p	1	13	34	1.901	0.006	1.896
14	4p5p	2	17	14 + 10U	1.044	0.006	1.046
17	4p6p	1	1	1U	(1.34)	0.04
18	4p6p	2	3	3 + 1U	1.16	0.02
19	4p4f	3	5	12 + 1U	0.926	0.010	1.00
20	4p4f	3	4	4 + 3U	1.077	0.010	1.10
21	4p4f	2	4	9	0.843	0.009	0.85
22	4p4f	4	2	6U	(1.113)	0.010	1.09
24	4p6p	1	1	1	1.11	0.04
25	4p6p	3	2	2U	(1.33)	0.02
26	4p4f	3	8	18 + 2U	0.932	0.007	0.98
27	4p6p	2	3	2 + 4U	1.37	0.02
28	4p4f	4	4	7 + 6U	1.166	0.009	1.17
30	4p4f	2	5	8 + 1U	0.961	0.009	1.00
31	4p4f	3	6	4 + 6U	1.247	0.013	1.27
32	4p4f	5	1	4U	(1.203)	0.010	1.21
33	4p4f	4	3	3 + 5U	1.016	0.007	1.07
34	4p6p	2	5	7 + 2U	1.083	0.012	0.82
35	4p4f	1	8	19	0.501	0.009	0.498
36	4p4f	2	6	9 + 2U	1.090	0.009	1.11
39	4p5f	3	1	1	0.84	0.04
40	4p5f	3	1	1U	(1.17)	0.04
41	4p5f	4	2	2U	(1.09)	0.02
42	4p5f	2	1	1 + 1U	0.904	0.02
52	4p5f	5	1	1U	(1.21)	0.04
55	4p5f	4	2	2U	(1.02)	0.03
56	4p5f	1	1	1	0.51	0.04
60	4p6f	4	1	1U	(1.09)	0.05
2°	4s4p³	1	6	14	0.518	0.010	0.508
3°	4s4p³	2	7	13 + 1U	1.170	0.009	1.176
4°	4s4p³	3	3	4 + 1U	1.33	0.02	1.335
6°	4p5s	1	9	19 + 2U	1.431	0.006	1.424
7°	4p5s	2	7	16 + 1U	1.501	0.009	1.492
8°	4p5s	1	9	17 + 1U	1.073	0.008	1.075
9°	4p4d	2	12	22 + 2U	1.120	0.006	1.15
10°	4s4p³	1	3	7 + 2U	1.49	0.02
12°	4s4p³	2	9	8 + 4U	1.366	0.014
13°	4p4d	2	4	12 + 1U	0.681	0.009	0.85
14°	4p4d	3	7	8 + 14U	1.080	0.006	1.12
15°	4p4d	4	3	4 + 5U	1.25	0.01	1.24
16°	4p4d	1	5	5 + 1U	0.68	0.01	0.75
17°	4p4d	2	10	17 + 3U	1.238	0.007	1.27
18°	4p4d	3	7	9 + 8U	1.290	0.009	1.25
19°	4p4d	1	6	10 + 2U	0.900	0.010	1.00
20°	4p4d	2	6	9 + 2U	1.422	0.009	1.433
21°	4p4d	3	8	7 + 5U	1.04	0.01	1.09
23°	4p4d	1	5	8 + 1U	1.427	0.009	1.44
25°	4s4p³	2	7	7 + 1U	1.002	0.010
27°	4p6s	1	4	8 + 2U	1.38	0.01	1.40
28°	4p6s	2	4	12 + 1U	1.500	0.009	1.49
29°	4p6s	1	7	12 + 3U	1.116	0.010	1.11
30°	4p5d	2	3	6 + 1U	0.697	0.008	0.71
31°	4s4p³	1	4	5 + 2U	1.02	0.01
32°	4p5d	3	2	2 + 2U	1.10	0.02	1.124
33°	4p5d	2	4	9 + 2U	1.308	0.009	1.44
34°	4p5d	1	3	4 + 1U	0.72	0.01	0.727
35°	4p5d	4	1	1U	(1.26)	0.02
36°	4p5d	3	2	4	1.27	0.01	1.283
37°	4p5d	2	7	13 + 2U	1.166	0.008	1.16
38°	4p5d	1	3	4 + 1U	1.31	0.02	1.34
40°	4p5d	2	6	15	1.160	0.006	1.131
41°	4p5d	3	2	3U	(1.034)	0.02	1.044
42°	4p5d	1	4	5 + 2U	0.98	0.01
44°	4p7s	1	4	8 + 2U	1.35	0.01
45°	4p6d	2	2	2U	(0.71)	0.02
46°	4p6d	3	2	2U	(1.12)	0.01
47°	4p6d	2	1	3	1.34	0.03
48°	4p6d	1	2	4 + 1U	0.98	0.01
49°	4p7s	2	2	4U	(1.44)	0.02
50°	4p7s	1	2	2 + 1U	0.95	0.03
55°	4p6d	3	1	1U	(1.21)	0.04
60°	4p6d	3	1	1U	(1.07)	0.02
63°	4p6d	1	1	1	0.98	0.04
72°	4p7d	3	1	1U	(1.12)	0.05

		Level (cm⁻¹)		g value

Config.	J	Calc.^a	Obs.	LS^b	LK^b	jK^b	jj^b	Calc.^a	Obs.	Unc.
4p5s	0	78 738	78 731
	1	79 121	79 128	1.500			1.333	1.427	1.431	0.006
	1	82 820	82 819	1.000			1.167	1.073	1.073	0.008
	2	81 508	81 509	1.500			1.500	1.500	1.500	0.009

4p6s	0	114 522	114 499
	1	114 679	114 701	1.500			1.333	1.371	1.38	0.01
	1	117 753	117 745	1.000			1.167	1.129	1.116	0.01
	2	117 378	117 386	1.500			1.500	1.500	1.500	0.009

4p5p	0	98 231	98 238
	0	105 795	105 790
	1	95 331	95 331	1.000	0.500	0.611	0.677	0.806	0.816	0.006
	1	96 924	96 915	0.500	1.333	1.556	1.500	0.890	0.892	0.006
	1	99 207	99 181	1.500	1.167	1.056	1.333	1.397	1.391	0.005
	1	101 092	101 090	2.000	2.000	1.778	1.500	1.907	1.901	0.006
	2	97 106	97 115	1.167	1.100	1.167	1.167	1.181	1.181	0.005
	2	100 257	100 261	1.500	1.500	1.433	1.167	1.439	1.441	0.006
	2	102 381	102 393	1.000	1.067	1.067	1.333	1.047	1.044	0.006
	3	99 191	99 199	1.333	1.333	1.333	1.333	1.333	1.332	0.005

		Level value (cm⁻¹)		g value

Config.	J	Calc.	Obs.	Calc. single^a	Calc. multi^b	Obs.	Expt. unc.
4p6p	0	121 817	121 816	1.439	1.438
	0	126 199	126 193	1.061	1.062
	1	120 772	120 775	0.713	0.712
	1	121 412	121 403	1.318	1.318	1.34	0.04
	1	123 699	123 704	1.112	1.112	1.11	0.04
	1	124 596	124 599	1.857	1.857
	2	121 464	121 472	1.188	1.155	1.16	0.02
	2	124 178	124 164	1.389	1.379	1.37	0.02
	2	124 943	124 965	1.089	1.095	1.083	0.012
	3	123 963	123 957	1.333	1.333	1.33	0.02

4p4f	1	125 192	125 208	0.500	0.500	0.501	0.009
	2	121 601	121 625	0.804	0.839	0.843	0.009
	2	124 600	124 653	0.932	0.950	0.961	0.009
	2	125 255	125 246	1.098	1.081	1.090	0.009
	3	121 517	121 521	0.923	0.920	0.926	0.010
	3	121 574	121 570	1.079	1.082	1.077	0.010
	3	124 145	124 140	0.927	0.928	0.932	0.007
	3	124 619	124 658	1.238	1.237	1.247	0.013
	4	121 636	121 627	1.117	1.116	1.113	0.010
	4	124 221	124 209	1.165	1.166	1.166	0.009
	4	124 900	124 870	1.018	1.018	1.016	0.007
	5	124 709	124 706	1.200	1.200	1.203	0.010
Standard deviation = 27.4 cm⁻¹

		Level value (cm⁻¹)		g value

Config.	J	Calc.	Obs.	Calc. single^a	Calc. multi^b	Obs.	Expt. unc.
4p7p	0	132 093	132 112	1.391	1.390
	0	135 700	135 694	1.109	1.110
	1	131 442	131 429	0.681	0.678
	1	131 931	131 898	1.420	1.425
	1	134 504	134 513	1.076	1.071
	1	134 940	134 949	1.823	1.822
	2	131 962	131 992	1.178	1.107
	2	134 724	134 704	1.305	1.198
	2	135 188	135 185	1.184	1.177
	3	134 620	134 631	1.333	1.293

4p5f	1	135 118	135 116	0.500	0.504	0.51	0.04
	2	131 875	131 896	0.847	0.917	0.904	0.02
	2	134 826	134 820	0.890	0.993
	2	135 126	135 147	1.097	1.108
	3	131 811	131 805	0.847	0.850	0.84	0.04
	3	131 874	131 872	1.164	1.161	1.17	0.04
	3	134 551	134 559	0.948	0.952
	3	134 843	134 839	1.208	1.244
	4	131 894	131 879	1.098	1.098	1.09	0.02
	4	134 603	134 605	1.182	1.181
	4	134 970	134 952	1.020	1.020	1.02	0.03
	5	134 834	134 832	1.200	1.200	1.21	0.04
Standard deviation = 22.3 cm⁻¹

		Level value (cm⁻¹)		g value

Config.	J	Calc.	Obs.	Calc.	Obs.	Unc.
4s4p³	0	84 656	84 649
	1	73 813	73 750	0.512	0.518	0.010
	1	84 638	84 636	1.490	1.49	0.02
	1	109 039	109 036	1.974
	1	118 982	119 015	1.002	1.02	0.01
	2	54 815	54 817	1.998
	2	73 854	73 863	1.173	1.170	0.009
	2	85 145	85 106	1.371	1.366	0.014
	2	111 561	111 532	1.004	1.002	0.010
	3	74 173	74 245	1.333	1.33	0.02

4p4d	0	102 560	102 550
	1	99 098	99 066	0.654	0.68	0.01
	1	101 477	101 488	0.926	0.900	0.010
	1	102 592	102 595	1.430	1.427	0.009
	2	83 082	83 101	1.115	1.120	0.006
	2	88 792	88 829	0.677	0.681	0.009
	2	99 560	99 549	1.227	1.238	0.007
	2	102 284	102 316	1.434	1.422	0.009
	3	89 569	89 550	1.084	1.080	0.006
	3	100 360	100 391	1.301	1.290	0.009
	3	102 501	102 487	1.031	1.04	0.01
	4	90 947	90 928	1.250	1.25	0.01

4p5d	0	123 521	123 522
	1	121 310	121 360	0.730	0.72	0.01
	1	123 498	123 500	1.298	1.31	0.02
	1	126 620	126 608	0.988	0.98	0.01
	2	118 917	118 892	0.699	0.697	0.008
	2	120 805	120 775	1.306	1.308	0.009
	2	123 238	123 228	1.172	1.166	0.008
	2	123 774	123 789	1.156	1.160	0.006
	3	119 518	119 538	1.102	1.10	0.02
	3	122 863	122 843	1.275	1.27	0.01
	3	124 402	124 396	1.040	1.034	0.02
	4	121 432	121 444	1.250	1.26	0.02

4p6d	0	134 281	134 284
	1	131 401	131 447	0.968	0.98	0.01
	1	134 260	134 262	1.261
	1	135 147	135 137	0.964	0.98	0.04
	2	130 705	130 671	0.731	0.71	0.02
	2	131 275	131 257	1.345	1.34	0.03
	2	133 910	133 923	0.998
	2	134 239	134 231	1.322
	3	131 139	131 147	1.115	1.12	0.01
	3	133 939	133 907	1.233	1.21	0.04
	3	134 658	134 656	1.069	1.07	0.02
	4	133 515	133 546	1.250

4p7s	0	128 591	128 573
	1	128 704	128 690	1.351	1.35	0.01
	1	131 877	131 919	0.953	0.95	0.03
	2	131 550	131 541	1.438	1.44	0.02
Standard deviation = 26 cm⁻¹

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Journal of the Optical Society of America