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Rotational and predissociation lifetimes of the A 2+ state of OD

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Abstract

The lifetime and predissociation probabilities of various rotational levels of the A 2+ state of OD were measured. A strong predissociation at N′ = 35 was observed. This predissociation could be explained by the level crossing of the A 2+ state with the repulsive 4 state which are mixed by a weak spin–orbit interaction.

© 1975 Optical Society of America

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