Extension of the analysis of triply ionized aluminum (Al iv)

Marie-Christine Artru; Victor Kaufman

doi:10.1364/JOSA.65.000594

Journal of the Optical Society of America
Vol. 65,
Issue 5,
pp. 594-599
(1975)
•https://doi.org/10.1364/JOSA.65.000594

Extension of the analysis of triply ionized aluminum (Al iv)

Marie-Christine Artru and Victor Kaufman

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Marie-Christine Artru and Victor Kaufman, "Extension of the analysis of triply ionized aluminum (Al iv)," J. Opt. Soc. Am. 65, 594-599 (1975)

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Abstract

A total of 225 new lines of Al iv have been observed in the wavelength range 400–4700 Å, leading to the determination of all of the levels of the 2p⁵ 4p, 4d, 4f, 5s, 5f, and 5g configurations. Results of parametric calculations for these configurations are presented. An ionization energy of 967 804 ± 15 cm⁻¹ has been derived.

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Configuration	Designation	J	Energy (cm⁻¹)	Interval
$2 p^{5} (^{2} P_{3 / 2}) 4 p$	$4 p [1 / 2]$	1	821 408.9	−6390.6
		0	827 799.5	−6390.6
	$4 p [5 / 2]$	3	824 080.0	−464.7
		2	824 544.7	−464.7
	$4 p [3 / 2]$	1	825 277.9	461.7
		2	825 739.6	461.7
$2 p^{5} (^{2} P_{1 / 2}) 4 p$	$4 p^{'} [3 / 2]$	1	827 844.9	594.3
		2	828 439.2	594.3
	$4 p^{'} [1 / 2]$	1	828 498.8	−8167.7
		0	836 666.5	−8167.7
$2 p^{5} (^{2} P_{3 / 2}) 4 d$	$4 d [1 / 2] °$	0	851 722.1	285.4
		1	852 007.5	285.4
	4d [3/2]°	2	852 570.5	−2702.7
		1	855272.7	−2702.7
	4d [7/2]°	4	852 706.8	−332.3
		3	853 039.1	−332.3
	4d [5/2]°	2	853 749.4	222.1
		3	853 971.5	222.1
$2 p^{5} (^{2} P_{1 / 2}) 4 d$	4d^′ [5/2]°	2	856 625.8	234.1
		3	856 859.9	234.1
	4d^′ [3/2]°	2	856 843.1	−1798.9
		1	858 642.0	−1798.9
$2 p^{5} (^{2} P_{3 / 2}) 4 f$	4f [3/2]	1	857 409.6	27.1
		2	857 436.7	27.1
	4f [9/2]	5	857 642.7	−3.2
		4	857 645.9	−3.2
	4f [5/2]	3	857 810.5	−24.6
		2	857 835.1	−24.6
$2 p^{5} (^{2} P_{3 / 2}) 4 f$	4f [7/2]	3	858 051.4	4.2
		4	858 055.6	4.2
$2 p^{5} (^{2} P_{1 / 2}) 4 f$	4f^′ [7/2]	3	861 246.9	5.5
		4	861 252.4	5.5
	4f^′ [5/2]	3	861 257.7	−17.1
		2	861 274.8	−17.1
$2 p^{5} (^{2} P_{3 / 2}) 5 s$	5s [3/2]°	2	870 991.9	−520.3
		1	871 512.2	−520.3
$2 p^{5} (^{2} P_{1 / 2}) 5 s$	5s^′ [1/2]°	0	874 422.9	333.9
		1	874 756.8	333.9
$2 p^{5} (^{2} P_{3 / 2}) 5 f$	5f [3/2]	1	897 197.1	20.5
		2	897 217.6	20.5
	5f [9/2]	5	897 324.7	−3.7
		4	897 328.4	−3.7
	5f [5/2]	3	897 416.8	−18.9
		2	897 435.7	−18.9
	5f [7/2]	3	897 537.5	2.6
		4	897 540.1	2.6
$2 p^{5} (^{2} P_{1 / 2}) 5 f$	5f^′ [5/2]	3	900 836.9	−17.2
		2	900 854.1	−17.2
	5f^′ [7/2]	3	900 843.6	4.1
		4	900 847.7	4.1
$2 p^{5} (^{2} P_{3 / 2}) 5 g$	5g [5/2]	2, 3	897 470.3
	5g [11/2]°	5, 6	897 506.5
	5g [7/2]°	3, 4	897 571.0
	5g [9/2]°	4, 5	897 608.5
$2 p^{5} (^{2} P_{1 / 2}) 5 g$	5g^′ [9/2]°	4, 5	900 988.4
	5g^′ [7/2]°	3, 4	900 988.4

Configuration	Parameter	HF	Fitted	Fitted/HF
$2 p^{5} 4 p$	E_av	814577	825993(8)	1.014
	$F^{2} (2 p, 4 p)$	6902	8394(53)	1.216
	$G^{0} (2 p, 4 p)$	2655	2431(6)	0.916
	$G^{2} (2 p, 4 p)$	2797	2998(110)	1.07
	$D^{1} (2 p, 4 p)$	⋯	671(56)	⋯
	$ζ_{4 p}$	73	93(15)	1.27
	$ζ_{2 p}$ >	2268	2278(13)	1.004
$2 p^{5} 4 d$	E_av	842855	854494(8)	1.014
	$F^{2} (2 p, 4 d)$	6238	6419(83)	1.029
	$G^{1} (2 p, 4 d)$	4268	3556(32)	0.833
	$G^{3} (2 p, 4 d)$	2430	2293(157)	0.94
	ζ₄_d	2.3	2.3 (fixed)	1.0(fixed)
	$ζ_{2 p}$	2269	2277(15)	1.004
$2 p^{5} 4 f$	E_av	846587	858930(3)	1.015
	$F^{2} (2 p, 4 f)$	2077	2229(31)	1.073
	$G^{2} (2 p, 4 f)$	99	66(25)	0.67
	$G^{4} (2 p, 4 f)$	64	125(53)	1.95
	ζ₄_f	0.5	0.5(fixed)	1.0(fixed)
	$ζ_{2 p}$	2271	2295(4)	1.011
$2 p^{5} 4 s$	E_av	860371	872350(13)	1.014
	$G^{1} (2 p, 5 s)$	1243	1282(76)	1.03
	$ζ_{2 p}$	2269	2286(17)	1.007
$2 p^{5} 4 f$	E_av	886115	898540(2)	1.014
	$F^{2} (2 p, 5 f)$	1062	1156(20)	1.089
	$G^{2} (2 p, 5 f)$	77	53(18)	0.69
	$G^{4} (2 p, 5 f)$	50	106(37)	2.12
	ζ₅_f	0.3	0.3(fixed)	1.0(fixed)
	$ζ_{2 p}$	2271	2295(3)	1.011
$2 p^{5} 5 g$	E_av	886184	898691.5(1.5)	1.014
	$F^{2} (2 p, 5 g)$	496.1	515.6(1.3)	1.039
	$G^{3} (2 p, 5 g)$	1.0	0(fixed)	⋯
	$G^{5} (2 p, 5 g)$	0.7	0(fixed)	⋯
	ζ₅_g	0.1	0(fixed)	⋯
	$ζ_{2 p}$	2272	2295.2(1.2)	1.010
rms error of least-squares level fit
	$2 p^{5} 4 p = 23 {cm}^{- 1}$		$2 p^{5} 5 s = 1$
	$2 p^{5} 4 d = 27$		$2 p^{5} 5 f = 6$
	$2 p^{5} 4 f = 9$		$2 p^{5} 5 g = 0.4$

J	Experimental level value (cm⁻¹)	ΔE exp. − calc.	J_cl composition, J_c[K]
0^a	827 799.5	29	50% 3/2[1/2],	50% 1/2[1/2]
	836 666.5	−1	50% 1/2[1/2],	50% 3/2[1/2]
1	821 408.9	1	87% 3/2[1/2],	13% 1/2[1/2]
	825 277.9	−21	93% 3/2[3/2],	7% 1/2[3/2]
	827 844.9	−5	93% 1/2[3/2],	7% 3/2[3/2]
	828 498.8	−11	87% 1/2[1/2],	13% 3/2[1/2]
2	824 544.7	4	82% 3/2[5/2],	14% 3/2[3/2]
	825 739.6	−6	84% 3/2[3/2],	15% 3/2[5/2]
	828 439.2	2	96% 1/2[3/2],	3% 3/2[5/2]
3	824 080.0	8	100% 3/2[5/2]

J	Experimental level value (cm⁻¹)	ΔE exp. − calc.	J_cl composition, J_c[K]
0	851 722.1	−10	100% 3/2[1/2]
1	852 007.5	−11	71% 3/2[1/2],	25% 3/2[3/2],	4% 1/2[3/2]
	855 272.7	8	71% 3/2[3/2],	17% 3/2[1/2],	11% 1/2[3/2]
	858 642.0	−3	85% 1/2[3/2],	11% 3/2[1/2],	4% 3/2[3/2]
2	852 570.0	−23	90% 3/2[3/2],	10% 1/2[3/2]
	853 749.4	−9	94% 3/2[5/2],	6% 1/2[5/2]
	856 625.8	17	94% 1/2[5/2],	6% 3/2[5/2]
	856 843.1	−23	90% 1/2[3/2],	10% 3/2[3/2]
3	853 039.1	13	91% 3/2[7/2],	7% 3/2[5/2]
	853 971.5	−22	90% 3/2[5/2],	8% 3/2[7/2]
	856 859.9	10	96% 1/2[5/2],	3% 3/2[5/2]
4	852 706.8	51	100% 3/2[7/2]

Configuration	Designation	J	Energy (cm⁻¹)	Interval
$2 p^{5} (^{2} P_{3 / 2}) 4 p$	$4 p [1 / 2]$	1	821 408.9	−6390.6
		0	827 799.5	−6390.6
	$4 p [5 / 2]$	3	824 080.0	−464.7
		2	824 544.7	−464.7
	$4 p [3 / 2]$	1	825 277.9	461.7
		2	825 739.6	461.7
$2 p^{5} (^{2} P_{1 / 2}) 4 p$	$4 p^{'} [3 / 2]$	1	827 844.9	594.3
		2	828 439.2	594.3
	$4 p^{'} [1 / 2]$	1	828 498.8	−8167.7
		0	836 666.5	−8167.7
$2 p^{5} (^{2} P_{3 / 2}) 4 d$	$4 d [1 / 2] °$	0	851 722.1	285.4
		1	852 007.5	285.4
	4d [3/2]°	2	852 570.5	−2702.7
		1	855272.7	−2702.7
	4d [7/2]°	4	852 706.8	−332.3
		3	853 039.1	−332.3
	4d [5/2]°	2	853 749.4	222.1
		3	853 971.5	222.1
$2 p^{5} (^{2} P_{1 / 2}) 4 d$	4d^′ [5/2]°	2	856 625.8	234.1
		3	856 859.9	234.1
	4d^′ [3/2]°	2	856 843.1	−1798.9
		1	858 642.0	−1798.9
$2 p^{5} (^{2} P_{3 / 2}) 4 f$	4f [3/2]	1	857 409.6	27.1
		2	857 436.7	27.1
	4f [9/2]	5	857 642.7	−3.2
		4	857 645.9	−3.2
	4f [5/2]	3	857 810.5	−24.6
		2	857 835.1	−24.6
$2 p^{5} (^{2} P_{3 / 2}) 4 f$	4f [7/2]	3	858 051.4	4.2
		4	858 055.6	4.2
$2 p^{5} (^{2} P_{1 / 2}) 4 f$	4f^′ [7/2]	3	861 246.9	5.5
		4	861 252.4	5.5
	4f^′ [5/2]	3	861 257.7	−17.1
		2	861 274.8	−17.1
$2 p^{5} (^{2} P_{3 / 2}) 5 s$	5s [3/2]°	2	870 991.9	−520.3
		1	871 512.2	−520.3
$2 p^{5} (^{2} P_{1 / 2}) 5 s$	5s^′ [1/2]°	0	874 422.9	333.9
		1	874 756.8	333.9
$2 p^{5} (^{2} P_{3 / 2}) 5 f$	5f [3/2]	1	897 197.1	20.5
		2	897 217.6	20.5
	5f [9/2]	5	897 324.7	−3.7
		4	897 328.4	−3.7
	5f [5/2]	3	897 416.8	−18.9
		2	897 435.7	−18.9
	5f [7/2]	3	897 537.5	2.6
		4	897 540.1	2.6
$2 p^{5} (^{2} P_{1 / 2}) 5 f$	5f^′ [5/2]	3	900 836.9	−17.2
		2	900 854.1	−17.2
	5f^′ [7/2]	3	900 843.6	4.1
		4	900 847.7	4.1
$2 p^{5} (^{2} P_{3 / 2}) 5 g$	5g [5/2]	2, 3	897 470.3
	5g [11/2]°	5, 6	897 506.5
	5g [7/2]°	3, 4	897 571.0
	5g [9/2]°	4, 5	897 608.5
$2 p^{5} (^{2} P_{1 / 2}) 5 g$	5g^′ [9/2]°	4, 5	900 988.4
	5g^′ [7/2]°	3, 4	900 988.4

Wavelength^a (Å)	Int.	Wave number^b (cm⁻¹)	Classification
4626.06	5	21 610.6	${4 s^{'} [1 / 2]}_{1}^{°} - 4 p^{'} {[3 / 2]}_{1}$
4620.35	15	21 637.3	${4 s [3 / 2]}_{1}^{°} - 4 p {[5 / 2]}_{2}$
4549.27	5	21 975.4	$4 p^{'} {[1 / 2]}_{0} - {4 d^{'} [3 / 2]}_{1}^{°}$
4503.74	40	22 197.5	${4 s [3 / 2]}_{2}^{°} - 4 p {[5 / 2]}_{3}$
4502.25	30	22 204.9	${4 s^{'} [1 / 2]}_{1}^{°} - 4 p^{'} {[3 / 2]}_{2}$
4468.85	20	22 370.8	${4 s [3 / 2]}_{1}^{°} - 4 p {[3 / 2]}_{1}$
4436.15	7	22 535.7	${4 s^{'} [1 / 2]}_{1}^{°} - 4 p^{'} {[3 / 2]}_{1}$
4411.38	5	22 662.3	${4 s [3 / 2]}_{2}^{°} - 4 p {[5 / 2]}_{2}$
4378.58	10	22 832.0	${4 s [3 / 2]}_{1}^{°} - 4 p {[3 / 2]}_{2}$
4190.41	10	23 857.3	${4 s [3 / 2]}_{2}^{°} - 4 p {[3 / 2]}_{2}$
3805.81	10	26 268.2	$4 p {[3 / 2]}_{2} - {4 d [1 / 2]}_{1}^{°}$
3725.92	300	26 831.4	$4 p {[3 / 2]}_{2} - {4 d [3 / 2]}_{2}^{°}$
3662.88	2	27 293.1	$4 p {[3 / 2]}_{1} - {4 d [3 / 2]}_{2}^{°}$
3662.01	1	27 299.6	$4 p {[3 / 2]}_{2} - {4 d [7 / 2]}_{3}^{°}$
3638.86	50	27 473.3	$4 p {[1 / 2]}_{0} - {4 d [3 / 2]}_{1}^{°}$
3546.770	10	28 186.6	$4 p^{'} {[3 / 2]}_{2} - {4 d^{'} [5 / 2]}_{2}^{°}$
3541.076	500	28 231.9	$4 p {[3 / 2]}_{2} - {4 d [5 / 2]}_{3}^{°}$
3527.034	400	28 344.3	$4 p^{'} {[1 / 2]}_{1} - {4 d^{'} [3 / 2]}_{2}^{°}$
3519.638	5	28 403.9	$4 p^{'} {[3 / 2]}_{2} - {4 d^{'} [3 / 2]}_{2}^{°}$
3517.556	700	28 420.7	$4 p^{'} {[3 / 2]}_{2} - {4 d^{'} [5 / 2]}_{3}^{°}$
3511.284	500	28 471.5	$4 p {[3 / 2]}_{1} - {4 d [5 / 2]}_{2}^{°}$
3508.457	800	28 494.4	$4 p {[5 / 2]}_{1} - {4 d [7 / 2]}_{3}^{°}$
3492.226	900	28 626.8	$4 p {[5 / 2]}_{3} - {4 d [7 / 2]}_{4}^{°}$
3473.536	500	28 780.9	$4 p^{'} {[3 / 2]}_{1} - {4 d^{'} [5 / 2]}_{2}^{°}$
3452.159	50	28 959.1	$4 p {[5 / 2]}_{3} - {4 d [7 / 2]}_{3}^{°}$
3423.125	350	29 204.7	$4 p {[5 / 2]}_{2} - {4 d [5 / 2]}_{2}^{°}$
3344.46	400	29 891.6	$4 p {[5 / 2]}_{3} - {4 d [5 / 2]}_{3}^{°}$
3332.962	300	29 994.7	$4 p {[3 / 2]}_{1} - {4 d [3 / 2]}_{1}^{°}$
3316.546	200	30 143.2	$4 p^{'} {[1 / 2]}_{1} - {4 d^{'} [3 / 2]}_{1}^{°}$
3297.943	150	30 313.2	$4 p {[1 / 2]}_{1} - {4 d [1 / 2]}_{0}^{°}$
3285.13	600	30 431.4	${4 s^{'} [1 / 2]}_{1}^{°} - 4 p^{'} {[1 / 2]}_{0}$
3267.213	500	30 598.3	$4 p {[1 / 2]}_{1} - {4 d [1 / 2]}_{1}^{°}$
3253.426	15	30 728.0	$4 p {[5 / 2]}_{2} - {4 d [3 / 2]}_{1}^{°}$
3246.143	100	30 796.9	$4 p^{'} {[3 / 2]}_{1} - {4 d^{'} [3 / 2]}_{1}^{°}$
3241.343	20	30 842.5	$4 p {[1 / 2]}_{0} - {4 d^{'} [3 / 2]}_{1}^{°}$
3214.13	10	31 103.6	$4 p {[3 / 2]}_{2} - {4 d^{'} [3 / 2]}_{2}^{°}$
3208.20	500	31 161.1	$4 p {[1 / 2]}_{1} - {4 d [3 / 2]}_{2}^{°}$
2961.29	300	33 759.2	${4 s [3 / 2]}_{1}^{°} - 4 p^{'} {[1 / 2]}_{0}$
2868.98	5	34 845.4	$4 p^{'} {[1 / 2]}_{0} - {5 s [3 / 2]}_{1}^{°}$
2624.54	5	38 090.6	$4 p^{'} {[1 / 2]}_{0} - {5 s^{'} [1 / 2]}_{1}^{°}$
2529.90	10	39 515.4	$4 f {[7 / 2]}_{4} - {5 g [7 / 2]}_{3, 4}^{°}$
2529.63	6	39 519.6	$4 f {[7 / 2]}_{3} - {5 g [7 / 2]}_{3, 4}^{°}$
2527.50	200	39 552.9	$4 f {[7 / 2]}_{4} - {5 g [9 / 2]}_{4, 5}^{°}$
2527.27	150aff	39 556.5	$4 f {[7 / 2]}_{3} - {5 g [9 / 2]}_{4}^{°}$
2522.28	5	39 634.7	$4 f {[5 / 2]}_{2} - {5 g [5 / 2]}_{2, 3}^{°}$
2520.68	10	39 659.9	$4 f {[5 / 2]}_{3} - {5 g 5 / 2]}_{2, 3}^{°}$
2517.29	200	39 713.3	$4 f^{'} {[5 / 2]}_{2} - {5 g^{'} [7 / 2]}_{3}^{°}$
2516.20	80aff	39 730.5	$4 f^{'} {[5 / 2]}_{2} - {5 g^{'} [7 / 2]}_{3, 4}^{°}$
2515.87	400	39 735.7	$4 f {[5 / 2]}_{2} - {5 g [7 / 2]}_{3}^{°}$
			$4 f^{'} {[7 / 2]}_{4} - {5 g^{'} [9 / 2]}_{4, 5}^{°}$
			$4 f^{'} {[7 / 2]}_{4} - {5 g^{'} [7 / 2]}_{3, 4}^{°}$
2515.48	100	39 741.9	$4 f {[7 / 2]}_{3} - {5 g^{'} [9 / 2]}_{4}^{°}$
			$4 f {[7 / 2]}_{3} - {5 g^{'} [7 / 2]}_{3, 4}^{°}$
2514.30	200	39 760.5	$4 f {[5 / 2]}_{3} - {5 g [7 / 2]}_{3, 4}^{°}$
2508.01	300	39 860.2	$4 f {[9 / 2]}_{4} - {5 g [11 / 2]}_{5}^{°}$
2507.76	300	39 864.2	$4 f {[9 / 2]}_{5} - {5 g [11 / 2]}_{5, 6}^{°}$
2501.60	3aff	39 962.4	$4 f {[9 / 2]}_{4} - {5 g [9 / 2]}_{4, 5}^{°}$
2501.37	5	39 966.0	$4 f {[9 / 2]}_{5} - {5 g [9 / 2]}_{4, 5}^{°}$
2497.14	200	40 033.7	$4 f {[3 / 2]}_{2} - {5 g [5 / 2]}_{2, 3}^{°}$
2495.47	80	40 060.5	$4 f {[3 / 2]}_{1} - {5 g [5 / 2]}_{2}^{°}$
2383.355	5	41 944.9	${4 d [3 / 2]}_{1}^{°} - 5 f {[3 / 2]}_{2}$
2371.027	50	42 162.9	${4 d [3 / 2]}_{1}^{°} - 5 f {[5 / 2]}_{2}$
2368.272	40	42 212.0	${4 d^{'} [3 / 2]}_{1}^{°} - 5 f {[5 / 2]}_{2}$
2324.13	20	43 013.6	$4 p^{'} {[1 / 2]}_{1} - {5 s [3 / 2]}_{1}^{°}$
2301.04	3	43 445.2	${4 d [5 / 2]}_{3}^{°} - 5 f {[5 / 2]}_{3}$
2294.524	50	43 568.6	${4 d [5 / 2]}_{3}^{°} - 5 f {[7 / 2]}_{4}$
2288.29	2	43 687.3	${4 d [5 / 2]}_{2}^{°} - 5 f {[5 / 2]}_{2}$
2287.01	2	43 711.8	$4 p {[1 / 2]}_{0} - {5 s [3 / 2]}_{1}^{°}$
2283.027	40	43 788.0	${4 d [5 / 2]}_{2}^{°} - 5 f {[7 / 2]}_{3}$
2272.66	50	43 987.7	${4 d^{'} [5 / 2]}_{3}^{°} - 5 f^{'} {[7 / 2]}_{4}$
2272.348	20	43 993.7	${4 d^{'} [3 / 2]}_{2}^{°} - 5 f^{'} {[5 / 2]}_{3}$
2260.838	60	44 217.7	${4 d^{'} [5 / 2]}_{2}^{°} - 5 f^{'} {[7 / 2]}_{3}$
2257.187	100	44 289.3	${4 d [7 / 2]}_{3}^{°} - 5 f {[9 / 2]}_{4}$
2240.563	300	44 617.8	${4 d [7 / 2]}_{4}^{°} - 5 f {[9 / 2]}_{5}$
2240.47	50aff	44 619.7	${4 d [7 / 2]}_{4}^{°} - 5 f {[9 / 2]}_{4}$
2229.13	30	44 846.6	${4 d [3 / 2]}_{2}^{°} - 5 f {[5 / 2]}_{3}$
2212.21	2	45 189.6	${4 d [1 / 2]}_{1}^{°} - 5 f {[3 / 2]}_{1}$
2211.21	3	45 210.0	${4 d [1 / 2]}_{1}^{°} - 5 f {[3 / 2]}_{2}$
2209.14	15	45 252.4	$4 p {[3 / 2]}_{2} - {5 s [3 / 2]}_{2}^{°}$
2184.05	10	45 772.2	$4 p {[3 / 2]}_{2} - {5 s [3 / 2]}_{1}^{°}$
2176.84	5	45 923.8	$4 p^{'} {[1 / 2]}_{1} - {5 s^{'} [1 / 2]}_{0}^{°}$
2162.24	15	46 233.8	$4 p {[3 / 2]}_{1} - {5 s [3 / 2]}_{1}^{°}$
2161.12	5	46 257.8	$4 p^{'} {[1 / 2]}_{1} - {5 s^{'} [1 / 2]}_{1}^{°}$
2158.32	100	46 317.8	$4 p^{'} {[3 / 2]}_{2} - {5 s^{'} [1 / 2]}_{1}^{°}$
2152.29	30	46 447.5	$4 p {[5 / 2]}_{2} - {5 s [3 / 2]}_{2}^{°}$
2146.25	15	46 578.2	$4 p^{'} {[3 / 2]}_{1} - {5 s^{'} [1 / 2]}_{0}^{°}$
2130.92	200aff	46 913.4	$4 p {[5 / 2]}_{3} - {5 s [3 / 2]}_{2}^{°}$
2128.45	40	46 967.7	$4 p {[5 / 2]}_{2} - {5 s [3 / 2]}_{2}^{°}$
2016.19	30	49 582.5	$4 p {[1 / 2]}_{1} - {5 s [3 / 2]}_{2}^{°}$
1754.120	20	57 008.6	$3 d^{1} P_{1}^{°} - 4 p^{'} {[3 / 2]}_{1}$
1734.24	40	57 662.1	$3 d^{1} P_{1}^{°} - 4 p^{'} {[1 / 2]}_{1}$
1712.43	200	58 396.5	$3 d^{3} D_{1}^{°} - 4 p {[3 / 2]}_{1}$
1672.722	20	59 782.8	$3 d^{1} F_{3}^{°} - 4 p {[5 / 2]}_{3}$
1647.79	1	60 687.3	$3 d^{3} D_{2}^{°} - 4 p^{'} {[3 / 2]}_{2}$
1646.15	200	60 747.8	$3 d^{3} D_{2}^{°} - 4 p^{'} {[1 / 2]}_{1}$
1644.47	200	60 809.9	$3 d^{1} D_{2}^{°} - 4 p^{'} {[3 / 2]}_{1}$
1641.55	50	60 918.0	$3 d^{3} D_{1}^{°} - 4 p {[1 / 2]}_{0}$
1641.20	200	60 931.0	$3 d^{3} F_{2}^{°} - 4 p {[5 / 2]}_{2}$
1641.05	300	60 936.6	$3 d^{3} P_{2}^{°} - 4 p {[1 / 2]}_{1}$
1636.822	500	61 094.0	$3 d^{3} D_{3}^{°} - 4 p^{'} {[3 / 2]}_{2}$
1628.58	50	61 403.2	$3 d^{1} D_{2}^{°} - 4 p^{'} {[3 / 2]}_{2}$
1627.536	600	61 442.6	$3 d^{1} F_{3}^{°} - 4 p {[3 / 2]}_{2}$
1621.68	350	61 664.4	$3 d^{3} F_{2}^{°} - 4 p {[3 / 2]}_{1}$
1617.93	200	61 807.4	$3 d^{3} F_{3}^{°} - 4 p {[5 / 2]}_{3}$
1617.81	400	61 812.0	$3 d^{3} P_{1}^{°} - 4 p {[1 / 2]}_{1}$
1607.31	1	62 215.8	$3 d^{3} P_{0}^{°} - 4 p {[1 / 2]}_{1}$
1602.77	300	62 392.0	$3 d^{3} F_{4}^{°} - 4 p {[5 / 2]}_{3}$
1559.03	500	64 142.4	$3 d^{1} F_{3}^{°} - 4 p^{'} {[3 / 2]}_{2}$
1556.88	1	64 231.0	$3 d^{3} F_{2}^{°} - 4 p^{'} {[3 / 2]}_{1}$
1532.16	300	65 267.3	$3 d^{3} P_{2}^{°} - 4 p {[3 / 2]}_{2}$
1519.07	400	65 829.7	$3 d^{1} P_{1}^{°} - 4 p^{'} {[1 / 2]}_{0}$
1513.20	10	66 085.1	$3 d^{3} P_{0}^{°} - 4 p {[3 / 2]}_{1}$
1511.88	100	66 142.8	$3 d^{3} P_{1}^{°} - 4 p {[3 / 2]}_{2}$
1471.303	40	67 967.0	$3 d^{3} P_{2}^{°} - 4 p^{'} {[3 / 2]}_{2}$
1470.024	30	68 026.1	$3 d^{3} P_{2}^{°} - 4 p^{'} {[1 / 2]}_{1}$
1466.24	15	68 201.7	$3 d^{3} P_{1}^{°} - 4 p {[1 / 2]}_{0}$
1432.97	10	69 785.1	$3 d^{3} D_{1}^{°} - 4 p^{'} {[1 / 2]}_{0}$
1154.730	250	86 600.3	$3 d^{1} P_{1}^{°} - 4 f {[3 / 2]}_{2}$
1149.450	200	86 998.1	$3 d^{1} P_{1}^{°} - 4 f {[5 / 2]}_{2}$
1105.738	400	90 437.3	$3 d^{1} P_{1}^{°} - 4 f^{'} {[5 / 2]}_{2}$
1105.402	50	90 464.8	$3 d^{3} D_{3}^{°} - 4 f {[5 / 2]}_{3}$
1104.617	20	90 529.1	$3 d^{3} D_{1}^{°} - 4 f {[3 / 2]}_{1}$
1104.285	70	90 556.3	$3 d^{3} D_{1}^{°} - 4 f {[3 / 2]}_{2}$
1102.417	200	90 709.8	$3 d^{3} D_{3}^{°} - 4 f {[7 / 2]}_{4}$
1101.34	20	90 798.5	$3 d^{1} D_{2}^{°} - 4 f {[5 / 2]}_{2}$
1099.461	300	90 953.7	$3 d^{3} D_{1}^{°} - 4 f {[5 / 2]}_{2}$
1098.718	200	91 015.2	$3 d^{1} D_{2}^{°} - 4 f {[7 / 2]}_{3}$
1071.241	100	93 349.7	$3 d^{1} F_{3}^{°} - 4 f {[9 / 2]}_{4}$
1069.437	600	93 507.1	$3 d^{3} D_{2}^{°} - 4 f^{'} {[5 / 2]}_{3}$
1066.567	500	93 758.8	$3 d^{1} F_{3}^{°} - 4 f {[7 / 2]}_{4}$
1064.891	600	93 906.3	$3 d^{3} D_{3}^{°} - 4 f^{'} {[7 / 2]}_{4}$
1061.429	500	94 212.6	$3 d^{1} D_{2}^{°} - 4 f^{'} {[7 / 2]}_{3}$
1061.135	40	94 238.7	$3 d^{1} D_{2}^{°} - 4 f^{'} {[5 / 2]}_{2}$
1059.396	150	94 393.4	$3 d^{3} D_{1}^{°} - 4 f^{'} {[5 / 2]}_{2}$
1058.901	500	94 437.5	$3 d^{3} F_{2}^{°} - 4 f {[7 / 2]}_{3}$
1048.515	700	95 373.0	$3 d^{3} F_{3}^{°} - 4 f {[9 / 2]}_{4}$
1044.064	200	95 779.6	$3 d^{3} F_{3}^{°} - 4 f {[7 / 2]}_{3}$
1042.169	800	95 953.7	$3 d^{3} F_{4}^{°} - 4 f {[9 / 2]}_{5}$
1040.340	30	96 122.4	$3 d^{3} F_{4}^{°} - 4 f {[5 / 2]}_{3}$
1031.39	100	96 956.5	$3 d^{1} F_{3}^{°} - 4 f^{'} {[7 / 2]}_{4}$
1027.343	500	97 338.5	$3 d^{3} P_{2}^{°} - 4 f {[5 / 2]}_{3}$
1027.08	5	97 363.4	$3 d^{3} P_{2}^{°} - 4 f {[5 / 2]}_{2}$
1024.248	150	97 632.6	$3 d^{3} F_{2}^{°} - 4 f^{'} {[7 / 2]}_{3}$
1023.93	5	97 662.9	$3 d^{3} F_{2}^{°} - 4 f^{'} {[5 / 2]}_{2}$
1022.362	100	97 812.7	$3 d^{3} P_{1}^{°} - 4 f {[3 / 2]}_{1}$
1022.082	200	97 839.5	$3 d^{3} P_{1}^{°} - 4 f {[3 / 2]}_{2}$
1018.168	100	98 215.6	$3 d^{3} P_{0}^{°} - 4 f {[3 / 2]}_{1}$
1017.940	30	98 237.6	$3 d^{3} P_{1}^{°} - 4 f {[5 / 2]}_{2}$
769.13	10	130 017.2	$3 d^{1} P_{1}^{°} - 4 f^{'} {[5 / 2]}_{2}$
766.31	3	130 501.8	$3 d^{1} D_{2}^{°} - 5 f {[7 / 2]}_{3}$
765.97	6	130 554.9	$3 d^{3} D_{1}^{°} - 5 f {[5 / 2]}_{2}$
751.68	2	133 031.3	$3 d^{1} F_{3}^{°} - 5 f {[9 / 2]}_{4}$
751.41	40	133 086.3	$3 d^{3} D_{2}^{°} - 5 f^{'} {[5 / 2]}_{3}$
750.52	40	133 240.4	$3 d^{1} F_{3}^{°} - 5 f {[7 / 2]}_{3, 4}$
749.07	60	133 498.1	$3 d^{3} D_{3}^{°} - 5 f^{'} {[7 / 2]}_{3, 4}$
748.63	2	133 583.5	$3 d^{3} F_{2}^{°} - 5 f {[3 / 2]}_{1}$
747.35	40	133 803.2	$3 d^{3} F_{2}^{°} - 5 f {[5 / 2]}_{3}$
		133 807.9	$3 d^{1} D_{2}^{°} - 5 f^{'} {[7 / 2]}_{3}$
746.71	20	133 923.9	$3 d^{3} F_{2}^{°} - 5 f {[7 / 2]}_{3}$
746.43	5	133 973.3	$3 d^{3} D_{1}^{°} - 5 f^{'} {[5 / 2]}_{2}$
740.44	100	135 055.9	$3 d^{3} F_{3}^{°} - 5 f {[9 / 2]}_{4}$
739.93	5	135 144.3	$3 d^{3} F_{3}^{°} - 5 f {[5 / 2]}_{3}$
739.31	5	135 265.0	$3 d^{3} F_{3}^{°} - 5 f {[7 / 2]}_{3, 4}$
737.27	200	135 636.3	$3 d^{3} F_{4}^{°} - 5 f {[9 / 2]}_{5}$
736.11	5	135 849.1	$3 d^{3} F_{4}^{°} - 5 f {[7 / 2]}_{3, 4}$
732.35	3	136 546.5	$3 d^{1} F_{3}^{°} - 5 f^{'} {[7 / 2]}_{3, 4}$
730.22	60	136 944.5	$3 d^{3} P_{2}^{°} - 5 f {[5 / 2]}_{3}$
728.71	60	137 230.0	$3 d^{3} F_{2}^{°} - 5 f^{'} {[7 / 2]}_{3}$
726.63	30	137 620.8	$3 d^{3} P_{1}^{°} - 5 f {[3 / 2]}_{2}$
724.62	7	138 003.7	$3 d^{3} P_{0}^{°} - 5 f {[3 / 2]}_{1}$
712.43	10	140 364.6	$3 d^{3} P_{2}^{°} - 5 f^{'} {[5 / 2]}_{3}$
708.34	10	141 175.8	$3 p^{1} S_{0} - {4 d [3 / 2]}_{1}^{°}$
691.82	30	144 545.1	$3 p^{1} S_{0} - {4 d^{'} [3 / 2]}_{1}^{°}$
635.31	1	157 415.3	$3 p^{1} S_{0} - {5 s [3 / 2]}_{1}^{°}$
607.04	10	164 740.0	$3 p^{3} P_{2} - {4 d [3 / 2]}_{2}^{°}$
603.83	2	165 611.4	$3 p^{1} P_{1} - {4 d [3 / 2]}_{2}^{°}$
598.95	10	166 963.1	$3 p^{3} P_{0} - {4 d [3 / 2]}_{1}^{°}$
594.55	30	168 193.7	$3 p^{3} P_{1} - {4 d^{'} [3 / 2]}_{2}^{°}$
594.38	40	168 243.3	$3 p^{1} D_{2} - {4 d [5 / 2]}_{3}^{°}$
592.42	2	168 795.3	$3 p^{3} P_{2} - {4 d^{'} [5 / 2]}_{2}^{°}$
591.62	60	169 025.7	$3 p^{3} D_{1} - {4 d [1 / 2]}_{1}^{°}$
		169 029.4	$3 p^{3} P_{2} - {4 d^{'} [5 / 2]}_{3}^{°}$
589.39	20	169 666.7	$3 p^{1} P_{1} - {4 d^{'} [5 / 2]}_{2}^{°}$
587.11	5	170 324.2	$3 p^{3} D_{2} - {4 d [1 / 2]}_{1}^{°}$
585.44	3	170 811.5	$3 p^{3} P_{2} - {4 d^{'} [3 / 2]}_{1}^{°}$
585.13	5	170 897.6	$3 p^{1} D_{2} - {4 d^{'} [5 / 2]}_{2}^{°}$
583.59	70	171 355.8	$3 p^{3} D_{2} - {4 d [7 / 2]}_{3}^{°}$
581.91	100	171 847.0	$3 p^{3} D_{3} - {4 d [7 / 2]}_{4}^{°}$
581.18	10	172 066.1	$3 p^{3} D_{2} - {4 d [5 / 2]}_{2}^{°}$
580.41	40	172 288.2	$3 p^{3} D_{2} - {4 d [5 / 2]}_{3}^{°}$
		172 290.9	$3 p^{3} D_{1} - {4 d [3 / 2]}_{1}^{°}$
578.32	5	172 913.8	$3 p^{1} D_{2} - {4 d^{'} [3 / 2]}_{1}^{°}$
577.66	10	173 111.7	$3 p^{3} D_{3} - {4 d [5 / 2]}_{3}^{°}$
575.89	20	173 644.0	$3 p^{3} D_{1} - {4 d^{'} [5 / 2]}_{2}^{°}$
571.61	20	174 942.5	$3 p^{3} D_{2} - {4 d^{'} [5 / 2]}_{2}^{°}$
552.67	15	180 938.0	$3 p^{3} S_{1} - {4 d [3 / 2]}_{2}^{°}$
548.43	2	182 342.5	$3 p^{3} P_{1} - {5 s [3 / 2]}_{2}^{°}$
545.97	10	183 161.4	$3 p^{3} P_{2} - {5 s [3 / 2]}_{2}^{°}$
541.86	5	184 553.1	$3 p^{1} P_{1} - {5 s [3 / 2]}_{1}^{°}$
537.34	5	186 107.4	$3 p^{3} P_{1} - {5 s^{'} [1 / 2]}_{1}^{°}$
536.36	3	186 447.2	$3 p^{3} P_{0} - {5 s^{'} [1 / 2]}_{1}^{°}$
534.98	15	186 926.3	$3 p^{3} P_{2} - {5 s^{'} [1 / 2]}_{1}^{°}$
532.49	1	187 797.7	$3 p^{1} P_{1} - {5 s^{'} [1 / 2]}_{1}^{°}$
530.42	2	188 530.4	$3 p^{3} D_{1} - {5 s [3 / 2]}_{1}^{°}$
528.26	5	189 308.6	$3 p^{3} D_{2} - {5 s [3 / 2]}_{2}^{°}$
526.81	5	189 828.9	$3 p^{3} D_{2} - {5 s [3 / 2]}_{1}^{°}$
525.95	20	190 132.1	$3 p^{3} D_{3} - {5 s [3 / 2]}_{2}^{°}$
501.62	5	199 359.4	$3 p^{3} S_{1} - {5 s [3 / 2]}_{2}^{°}$
500.42	10	199 827.2	${3 s^{1} P}_{1}^{°} - 4 p {[5 / 2]}_{2}$
500.29	30	199 879.7	${3 p^{3} S}_{1}^{°} - {5 s [3 / 2]}_{1}^{°}$
498.61	5	200 560.4	${3 s^{1} P}_{1}^{°} - 4 p {[3 / 2]}_{1}$
497.47	15	201 022.1	${3 s^{1} P}_{1}^{°} - 4 p {[3 / 2]}_{2}$
496.66	10	201 348.8	${3 s^{3} P}_{0}^{°} - 4 p {[1 / 2]}_{1}$
492.78	25	202 935.0	${3 s^{3} P}_{1}^{°} - 4 p {[1 / 2]}_{1}$
492.31	20	203 124.3	${3 p^{3} S}_{1}^{°} - 5 s^{'} {[1 / 2]}_{1}^{°}$
		203 127.4	${3 s^{1} P}_{1}^{°} - 4 p^{'} {[3 / 2]}_{1}$
490.88	40	203 721.7	${3 s^{1} P}_{1}^{°} - 4 p^{'} {[3 / 2]}_{2}$
490.73	20	203 781.3	${3 s^{1} P}_{1}^{°} - 4 p^{'} {[1 / 2]}_{1}$
488.36	100	204 764.7	${3 s^{3} P}_{2}^{°} - 4 p {[1 / 2]}_{1}$
485.28	40	206 070.8	${3 s^{3} P}_{1}^{°} - 4 p {[5 / 2]}_{2}$
483.55	20	206 804.0	${3 s^{3} P}_{1}^{°} - 4 p {[3 / 2]}_{1}$
482.48	10	207 265.7	${3 s^{3} P}_{1}^{°} - 4 p {[3 / 2]}_{2}$
482.08	100	207 435.8	${3 s^{3} P}_{2}^{°} - 4 p {[5 / 2]}_{3}$
481.29	10	207 784.8	${3 s^{3} P}_{0}^{°} - 4 p^{'} {[3 / 2]}_{1}$
481.01	30	207 900.5	${3 s^{3} P}_{2}^{°} - 4 p {[5 / 2]}_{2}$
479.76	20	208 438.7	${3 s^{3} P}_{0}^{°} - 4 p^{'} {[1 / 2]}_{1}$
479.30	5	208 633.7	${3 s^{3} P}_{2}^{°} - 4 p {[3 / 2]}_{1}$
478.26	30	209 095.4	${3 s^{3} P}_{2}^{°} - 4 p {[3 / 2]}_{2}$
477.73	10	209 325.6	${3 s^{3} P}_{1}^{°} - 4 p {[1 / 2]}_{0}$
477.60	5	209 371.0	${3 s^{3} P}_{1}^{°} - 4 p^{'} {[3 / 2]}_{1}$
476.27	20	209 965.3	${3 s^{3} P}_{1}^{°} - 4 p^{'} {[3 / 2]}_{2}$
476.13	5	210 024.9	${3 s^{3} P}_{1}^{°} - 4 p^{'} {[1 / 2]}_{1}$

Abstract

Cited By

Figures (2)

Tables (5)

Equations (1)

Journal of the Optical Society of America