Spectrum and energy levels of triply ionized lanthanum (La iv)

Gabriel L. Epstein; Joseph Reader

doi:10.1364/JOSA.69.000511

Journal of the Optical Society of America
Vol. 69,
Issue 4,
pp. 511-520
(1979)
•https://doi.org/10.1364/JOSA.69.000511

Spectrum and energy levels of triply ionized lanthanum (La iv)

Gabriel L. Epstein and Joseph Reader

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Gabriel L. Epstein and Joseph Reader, "Spectrum and energy levels of triply ionized lanthanum (La iv)," J. Opt. Soc. Am. 69, 511-520 (1979)

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Abstract

The spectrum of La iv has been observed in a sliding spark discharge with the NBS 10.7-m normal incidence vacuum spectrograph and the NBS 10.7-m Eagle spectrograph in air. A total of 368 lines have been observed in the region from 300 to 5000 Å. About 190 lines have been classified as transitions between 49 energy levels. All levels of the 5p⁶, 5p⁵ 5d, 6s, 6d, and 7s configurations as well as half of the levels of the 5p⁵ 4f configuration have been located. Because of the greatly contracted 4f orbital, the lowest excited configuration is 5p⁵ 4f. All configurations have been theoretically interpreted. The energy parameters determined from least-squares fits to the observed levels are compared with Hartree-Fock calculations. Some new measurements for La iii are presented that confirm the 1967 results of Odasbasi.

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Configuration	Term	J	E(cm⁻¹)	Unc. (cm⁻¹)
5p⁶	¹S	0	0.0	0.5
5p⁵ 4f	3/2[3/2]	1	143 354.72	0.05
	3/2[3/2]	2	145 948.96	0.04
	3/2[5/2]	3	149 927.18	0.05
	3/2[7/2]	3	153 339.10	0.07
	3/2[5/2]	2	160 486.34	0.09
	1/2[5/2]	2	175 013.82	0.12
5p⁵ 5d	3/2[1/2]°	0	156 100.3	0.2
	3/2[1/2]°	1	158 412.61	0.18
	3/2[3/2]°	2	162 867.66	0.13
	3/2[7/2]°	4	163 693.3	0.3
	3/2[7/2]°	3	165 070.77	0.19
	3/2[5/2]°	2	167 921.72	0.05
	3/2[5/2]°	3	173 335.41	0.04
	3/2[3/2]°	1	181 154.97	0.07
	1/2[5/2]°	2	184 885.80	0.06
	1/2[3/2]°	2	188 393.20	0.05
	1/2[5/2]°	3	190 831.70	0.07
	1/2[3/2]°	1	215 919.23	0.02
5p⁵ 6s	3/2[3/2]°	2	198 303.15	0.07
	3/2[3/2]°	1	200 183.26	0.04
	1/2[1/2]°	0	219 336.85	0.08
	1/2[1/2]°	1	220 506.85	0.07
5p⁵ 6p	3/2[1/2]	1	231 008.71	0.05
	3/2[5/2]	2	233 401.52	0.05
	3/2[5/2]	3	236 790.42	0.06
	3/2[3/2]	1	237 727.30	0.03
	3/2[3/2]	2	239 654.29	0.03
	3/2[1/2]	0	244 301.79	0.04
	1/2[3/2]	1	254 251.34	0.05
	1/2[1/2]	1	259 085.89	0.05
	1/2[3/2]	2	259 224.33	0.05
	1/2[1/2]	0	260 449.83	0.08
5p⁵ 6d	3/2[1/2]°	0	284 206.15	0.15
	3/2[1/2]°	1	284 981.97	0.07
	3/2[7/2]°	4	285 856.18	0.13
	3/2[7/2]°	3	285 951.00	0.07
	3/2[3/2]°	2	286 298.26	0.05
	3/2[5/2]°	2	287 402.66	0.10
	3/2[5/2]°	3	287 874.01	0.11
	3/2[3/2]°	1	290 596.17	0.09
	1/2[5/2]°	2	307 182.98	0.14
	1/2[3/2]°	2	307 398.42	0.11
	1/2[5/2]°	3	308 151.35	0.16
	1/2[3/2]°	1	310 049.76	0.09
5p⁵ 7s	3/2[3/2]°	2	292 080.31	0.11
	3/2[3/2]°	1	292 777.84	0.08
	1/2[1/2]°	0	313 512.37	0.14
	1/2[1/2]°	1	313 917.03	0.13

J	E(obs.)	E(calc.)	obs.-calc.	% J₁l	Percentage composition-LS
0	156 100	156 137	−37	100% 3/2[1/2]	−100% ³P
0	219 337	219 316	21	100% 1/2[1/2]*	100% ³P*
1	158 413	158 418	−5	65% 3/2[1/2]	−93% ³P − 6% ³D
	181 155	181 141	14	51% 3/2[3/2]	88% ³D − 7% ¹P − 5% ³P
	200 183	200 169	14	99% 3/2[3/2]*	−59% ¹P* + 40% ³P*
	215 919	215 921	−2	59% 1/2[3/2]	93% ¹P + 6% ³D − 1% ³P
	220 507	220 528	−21	99% 1/2[1/2]*	59% ³P* + 41% ¹P*
2	162 868	162 805	63	90% 3/2[3/2]	78% ³P + 16% ³D + 6% ¹D
	167 922	167 907	15	95% 3/2[5/2]	−42% ³F + 38% ¹D − 20% ³D
	184 886	184 904	−18	91% 1/2[5/2]	55% ³F + 38% ¹D − 6% ³D − 1% ³P
	188 393	188 407	−14	85% 1/2[3/2]	−58% ³D + 20% ³P − 18% ¹D + 3% ³F
	198 303	198 318	−15	98% 3/2[3/2]*	−98% ³P* − 1% ³P
3	165 071	165 043	28	78% 3/2[7/2]	74% ³F − 18% ¹F + 8% ³D
	173 335	173 370	−35	80% 3/2[5/2]	62% ³D + 38% ¹F
	190 832	190 815	17	96% 1/2[5/2]	−45% ¹F + 29% ³D − 26% ³F
4	163 693	163 722	−29	100% 3/2[7/2]	100% ³F

Configuration	Parameter	HF	Fitted	Fitted/HF
5p⁵ 4f	E_av	130 858	158 036 ± 103
	F²(5p4f)	47 462	38 215 ± 1204	0.805
	G²(5p4f)	26 806	25 865 ± 841	0.965
	G⁴(5p4f)	20 427	19 710^c
	ζ₅_p	10 858	11 574 ± 275	1.066
	ζ₄_f	591	591^b
5p⁵ 5d	E_av	168 651	175 379 ± 13
	F²(5p5d)	47 975	37 315 ± 143	0.778
	G¹(5p5d)	57 078	36 815 ± 43	0.645
	X²(5p5d)		3 854 ± 317
	G³(5p5d)	35 743	26 973 ± 270	0.755
	ζ₅_p	11 778	13 803 ± 26	1.172
	ζ₅_d	855	859 ± 15	1.005
5p⁵ 6s	E_av	209 052	205 921 ± 23
	G¹(5p6s)	5 474 (0.38)^a	5 027 ± 125	0.918
	ζ₅_p	12 166	14 126 ± 29	1.161
Configuration	R²(5p5d,5p6s)	−9 180 (−0.38)	−9 180^b
interaction	R¹(5p5d,6s5p)	−2 075 (−0.07)	−2 075^b
5p⁵ 6p	E_av	241 014	243 596 ± 26
	F²(5p6p)	16 916	14 216 ± 306	0.840
	G⁰(5p6p)	2 953 (0.18)	2 708 ± 23	0.917
	G²(5p6p)	4 218 (0.57)	4 065 ± 352	0.964
	ζ₅_p	12 265	14 181 ± 35	1.156
	ζ_6p	2 002	2 952 ± 43	1.474
5p⁵ 6d	E_av	284 041	293 827 ± 47
	F²(5p6d)	11 637	9 020 ± 549	0.775
	G¹(5p6d)	6 977 (0.79)	5 970 ± 188	0.856
	G³(5p6d)	4 959 (0.91)	3 360 ± 857	0.678
	ζ₅_p	12 254	14 034 ± 65	1.145
	ζ₆_d	203	174 ± 45	0.857
5p⁵ 7s	E_av	294 731	299 472 ± 82
	G¹(5p7s)	1 701 (0.35)	1 530 ± 446	0.900
	ζ₅_p	12 280	14 311 ± 106	1.165
Configuration	R²(5p6d,5p7s)	−1 162 (−0.17)	−1 162^b
interaction	R¹(5p6d,7s5p)	413 (0.06)	413^b

J	E(obs.)	E(calc.)	obs.-calc.	% J₁l	Percentage composition LS
0	244 302	244 374	−72	94% 3/2[1/2]	57% ³P − 43% ¹S
0	260 450	260 393	57	94% 1/2[1/2]	57% ¹S + 43% ³P
1	231 009	231 043	−34	86% 3/2[1/2]	70% ³S + 27% ³P + 2% ³D
	237 727	237 755	−28	88% 3/2[3/2]	56% ¹P − 20% ³D − 13% ³P + 10% ³S
	254 251	254 279	−28	91% 1/2[3/2]	70% ³D + 28% ¹P − 1% ³S
	259 086	259 078	8	90% 1/2[1/2]	−59% ³P + 18% ³S − 15% ¹P + 7% ³D
2	233 402	233 389	13	85% 3/2[5/2]	54% ³D − 35% ^lD + 11% ³P
	239 654	239 637	17	85% 3/2[3/2]	69% ³P + 30% ¹D
	259 224	259 252	−28	100% 1/2[3/2]	−45% ³D − 35% ^ID + 20% ³P
3	236 790	236 691	99	100% 3/2[5/2]	100% ³D

J	E(obs.)	E(calc.)	obs.-calc.	% J₁l	Percentage composition LS
0	284 206	284 199	7	100% 3/2[1/2]	−100% ³P
0	313 512	313 532	−20	100% 1/2[1/2]*	100% ³P*
1	284 982	284 934	48	65% 3/2[1/2]	−86% ³P − 13% ³D − 1% ¹P
	290 596	290 564	32	63% 3/2[3/2]	52% ¹P − 41% ³D + 3% ³P − 2% ¹P*
	292 778	292 790	−12	97% 3/2[3/2]*	−62% ¹P* + 35% ³P* + 2% ³D − 1% ¹P
	310 050	310 086	−36	98% 1/2[3/2]	45% ¹P + 44% ³D − 11% ³P
	313 917	313 898	19	100% 1/2[1/2]*	−64% ³P* − 36% ¹P*
2	286 298	286 186	112	97% 3/2[3/2]	57% ³P + 32% ³D + 10% ¹D
	287 403	287 340	63	98% 3/2[5/2]	51% ¹D − 26% ³F − 22% ³D + 1% ³P
	292 080	292 069	11	100% 3/2[3/2]*	100% ³P*
	307 183	307 109	74	97% 1/2[5/2]	−72% ³F − 22% ¹D + 5% ³D + 1% ³P
	307 398	307 645	−247	97% 1/2[3/2]	41% ³P − 40% ³D − 17% ¹D + 2% ³F
3	285 951	286 111	−160	94% 3/2[7/2]	55% ³F − 41% ¹F + 4% ³D
	287 874	287 893	−19	94% 3/2[5/2]	71% ³D + 25% ¹F + 4% ³F
	308 151	307 945	206	100% 1/2[5/2]	−41% ³F − 34% ¹F + 25% ³D
4	285 856	285 927	−71	100% 3/2[7/2]	100% ³F

Wavelength (Å)	Intensity	Wave number (cm⁻¹)	Classification
318.556	3	313 916.6	$5 p^{6} {¹ S}_{0} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
322.531	20	310 047.7	$5 p^{6} {¹ S}_{0} - 6 d 1 / 2 {[3 / 2]}_{1}^{°}$
341.555	70	292 778.6	$5 p^{6} {¹ S}_{0} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
344.120	100	290 596.3	$5 p^{6} {¹ S}_{0} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
350.901	1	284 980.7	$5 p^{6} {¹ S}_{0} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
453.500	7 000	220 507.2	$5 p^{6} {¹ S}_{0} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
463.138	10 000	215 918.4	$5 p^{6} {¹ S}_{0} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
499.540	15 000	200 184.2	$5 p^{6} {¹ S}_{0} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
552.015	40 000	181 154.5	$5 p^{6} {¹ S}_{0} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
631.261	30 000	158 413.1	$5 p^{6} {¹ S}_{0} - 5 d 3 / 2 {[1 / 2]}_{1}^{°}$
690.892	25	144 740.4
692.348	125	144 436.0
693.947	200	144 103.2
698.133	15	143 239.2
701.530	75	142 545.6
703.460	1	142 154.5	$4 f 3 / 2 {[5 / 2]}_{3} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
706.075	2	141 628.0	$4 f 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
709.965	1	140 852.0	$4 f 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{0}^{°}$
712.515	8p	140 347.9	$4 f 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
719.256	5	139 032.6	$4 f 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
723.803	15	138 159.1
724.919	25	137 946.4	$4 f 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
733.289	15	136 371.9	$4 f 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
733.388	10	136 353.5
738.640	150	135 384.0
740.813	1 000	134 986.8
744.784	300	134 267.1
748.297	150	133 636.8
750.399	1 000	133 262.4
750.605	1 500	133 225.9
753.728	1 000	132 673.9
757.765	1 000	131 967.0
763.760	1 500	130 931.2
767.216	3 500	130 341.4
768.584	2	130 109.4	$4 f 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
769.995	50	129 871.0
771.878	2 000u	129 554.2
773.260	500	129 322.6
775.649	10 000	128 924.3
776.146	75	128 841.7
776.576	750	128 770.4
783.093	200	127 698.8
784.537	4 000	127 463.7
787.921	1	126 916.3	$4 f 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
789.871	1 000	126 603.0
790.692	3 000	126 471.5
794.445	750	125 874.0
797.032	10	125 465.5	$4 f 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
807.006	2 500	123 914.8
824.475	4 000	121 289.3
838.937	1 700	119 198.5
887.781	3 000	112 640.4
889.765	2	112 389.2	$4 f 1 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
895.479	50	111 672.1
899.236	150	111 205.5
918.910	150	108 824.6
980.032	10c	102 037.5	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{0}$
991.941	1	100 812.4	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
993.319	3u	100 672.6	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
1 018.838	5	98 151.03	$5 d 3 / 2 {[1 / 2]}_{0}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
1 037.809	40	96 356.84	$5 d 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 039.305	50	96 218.15	$5 d 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
1 043.415	30	95 839.14	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
1 062.092	60p	94 153.80	$5 d 3 / 2 {[7 / 2]}_{3}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 095.259	1p	91 302.61	$5 d 3 / 2 {[5 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 158.347	75	86 329.92	$5 d 3 / 2 {[5 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
1 164.287	50	85 889.48	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 3 / 2 {[1 / 2]}_{0}$
1 225.089	30	81 626.72	$5 d 3 / 2 {[1 / 2]}_{0}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
1 230.901	800	81 241.30	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
1 245.980	40	80 258.11
1 250.337	40	79 978.44
1 258.091	15	79 485.51
1 260.792	75p	79 315.22	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
1 261.118	300	79 294.72	$5 d 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{0}$
1 283.188	150	77 930.90	$5 d 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
1 284.079	300	77 876.83
1 302.312	5 000	76 786.52	$5 d 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
1 309.075	1	76 389.82	$6 p 3 / 2 {[1 / 2]}_{1} - 6 d 1 / 2 {[3 / 2]}_{2}^{°}$
1 316.101	150	75 982.01	$4 f 3 / 2 {[3 / 2]}_{1} - 6 s 1 / 2 {[1 / 2]}_{0}^{°}$
1 317.942	25	75 875.87
1 320.677	200	75 718.74
1 333.527	1 200	74 989.11	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
1 334.960	3 500	74 908.61	$5 d 3 / 2 {[1 / 2]}_{0}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
1 335.836	500p	74 859.49	$5 d 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
1 340.776	60	74 583.67	$5 d 3 / 2 {[7 / 2]}_{3}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
1 341.243	5h	74 557.71	$4 f 3 / 2 {[3 / 2]}_{2} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
1 345.196	500	74 338.61	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 346.409	75	74 271.64
1 347.703	25	74 200.32	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
1 348.342	10	74 165.16
1 352.763	2 000	73 922.78	$5 d 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
1 367.479	10	73 127.27
1 368.043	25 000	73 097.12	$5 d 3 / 2 {[7 / 2]}_{4}^{°} - p 3 / 2 {[5 / 2]}_{3}$
1 368.616	50	73 066.51
1 376.043	50	72 672.15
1 377.488	8 000	72 595.91	$5 d 3 / 2 {[1 / 2]}_{1}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
1 378.082	2	72 564.62	$4 f 3 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
1 381.783	3	72 370.26
1 385.136	35	72 195.08
1 385.559	50	72 173.04
1 388.402	20	72 025.25
1 394.325	3 000	71 719.29	$5 d 3 / 2 {[7 / 2]}_{3}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
1 401.328	1	71 360.88	$6 p 3 / 2 {[5 / 2]}_{3} - 6 d 1 / 2 {[5 / 2]}_{3}^{°}$
1 402.395	50	71 306.59
1 411.811	250	70 831.01	$5 d 1 / 2 {[3 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 413.427	100	70 750.03
1 414.577	5 000	70 692.51	$5 d 1 / 2 {[3 / 2]}_{2}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
1 417.758	300p	70 533.90	$5 d 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
1 432.550	7 000	69 805.59	$5 d 3 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
1 436.079	75	69 634.05
1 441.633	6 000	69 365.78	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
1 448.838	35	69 020.83
1 452.036	75	68 868.82	$5 d 3 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
1 462.149	7 500	68 392.48	$5 d 1 / 2 {[5 / 2]}_{3}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 463.467	20 000	68 330.89	$5 d 3 / 2 {[7 / 2]}_{3}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
1 467.543	8 000	68 141.10	$5 d 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
1 480.721	25	67 534.67
1 507.866	15 000	66 318.89	$5 d 3 / 2 {[5 / 2]}_{3}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
1 516.396	25	65 945.83
1 527.191	5 000	65 479.69	$5 d 3 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
1 527.516	15	65 465.76
1 564.216	15	63 929.79
1 575.920	2 500	63 455.00	$5 d 3 / 2 {[5 / 2]}_{3}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
1 583.609	1 500	63 146.90	$5 d 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[1 / 2]}_{0}$
1 585.110	750	63 087.10	$5 d 3 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
1 637.420	600	61 071.69	$6 p 3 / 2 {[1 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
1 641.470	150	60 921.00	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 645.213	500d	60 782.40	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
1 659.297	25	60 266.49	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{0}$
1 664.399	75	60 081.75
1 664.835	1 000	60 066.01	$5 d 3 / 2 {[5 / 2]}_{3}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
1 676.005	500c	59 665.69	$6 p 1 / 2 {[3 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
1 684.171	750	59 376.39	$6 p 3 / 2 {[5 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
1 687.453	250c	59 260.91	$6 p 1 / 2 {[3 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{0}^{°}$
1 693.735	75c	59 041.11	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
1 697.718	5	58 902.60	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
1 702.179	50	58 748.23
1 704.190	500	58 678.90	$6 p 3 / 2 {[5 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
1 707.353	15	58 570.20
1 709.419	40	58 499.41	$5 d 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
1 748.411	40	57 194.79	$6 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
1 759.677	50	56 828.61	$4 f 3 / 2 {[3 / 2]}_{1} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1 760.655	750	56 797.04
1 767.638	2 000p	56 572.67	$5 d 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
1 773.238	75	56 394.01	$6 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
1 787.368	3	55 948.19	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
1 792.169	400d	55 798.31	$6 p 1 / 2 {[3 / 2]}_{1} - 6 d 1 / 2 {[3 / 2]}_{1}^{°}$
1 798.842	750	55 591.32
1 808.655	4 000	55 289.70	$6 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
			$6 p 3 / 2 {[5 / 2]}_{3} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
1 816.517	400	55 050.41	$6 p 3 / 2 {[3 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
1 823.782	100d	54 831.11	$6 p 1 / 2 {[1 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
1 825.870	50	54 768.41	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
1 828.404	250	54 692.51	$6 p 1 / 2 {[3 / 2]}_{2} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
1 835.789	100	54 472.49	$6 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
1 837.340	150	54 426.51	$6 p 1 / 2 {[1 / 2]}_{1} - 7 s 1 / 2 {[1 / 2]}_{0}^{°}$
1 839.832	3	54 352.79	$6 p 3 / 2 {[3 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
1 843.855	100	54 234.20	$4 f 3 / 2 {[3 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
1 844.710	40	54 209.06
1 849.299	75	54 074.54
1 849.516	30d	54 068.20	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
1 851.811	1 000	54 001.19	$6 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
1 852.768	1 500	53 973.30	$6 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
1 870.299	50d	53 467.39	$6 p 1 / 2 {[1 / 2]}_{0} - 7 s 1 / 2 {[1 / 2]}_{1}^{°}$
1 879.790	750	53 197.43	$6 p 3 / 2 {[1 / 2]}_{1} - 6 d 3 / 2 {[1 / 2]}_{0}^{°}$
1 881.570	1 000	53 147.11	$6 p 1 / 2 {[3 / 2]}_{1} - 6 d 1 / 2 {[3 / 2]}_{2}^{°}$
1 882.403	500	53 123.59	$6 p 3 / 2 {[3 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
1 889.223	800	52 931.81	$6 p 1 / 2 {[3 / 2]}_{1} - 6 d 1 / 2 {[5 / 2]}_{2}^{°}$
1 890.466	500d	52 897.01	$6 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
1 891.471	1 000	52 868.90	$6 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
1 892.448	200	52 841.61	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
1 902.968	5 000	52 549.49	$6 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
1 907.443	800	52 426.21	$6 p 3 / 2 {[3 / 2]}_{2} - 7 s 3 / 2 {[3 / 2]}_{2}^{°}$
1 910.066	75c	52 354.21	$4 f 3 / 2 {[3 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
1 914.005	90p	52 246.47	$5 d 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
1 926.610	10	51 904.64	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
1 938.724	200	51 580.32	$6 p 3 / 2 {[5 / 2]}_{2} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
1 950.797	1 500c	51 261.10	$5 d 1 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
1 957.571	1 200c	51 083.72	$6 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
1 962.171	75	50 963.96	$6 p 1 / 2 {[1 / 2]}_{1} - 6 d 1 / 2 {[3 / 2]}_{1}^{°}$
1 967.522	2p	50 825.35	$6 p 1 / 2 {[3 / 2]}_{2} - 6 d 1 / 2 {[3 / 2]}_{1}^{°}$
1 978.464	500	50 544.26
1 982.497	5	50 441.44
1 994.939	15d	50 126.85
1 999.749	12 000	50 006.28
2 004.826	20	49 863.50
2 005.222	100	49 853.65	$5 d 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
2 012.418	3 000	49 675.42	$6 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
2 015.481	200	49 599.93	$6 p 1 / 2 {[1 / 2]}_{0} - 6 d 1 / 2 {[3 / 2]}_{1}^{°}$
2 019.234	500	49 507.77	$6 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
2 026.097	10	49 340.10
2 026.341	25	49 334.14	$5 d 1 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
2 028.572	15	49 279.90
2 028.736	2 500	49 275.92
2 033.497	300	49 160.55	$6 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
2 037.426	750	49 065.76	$6 p 3 / 2 {[5 / 2]}_{3} - 6 d 3 / 2 {[7 / 2]}_{4}^{°}$
2 043.203	150c	48 927.05	$6 p 1 / 2 {[3 / 2]}_{2} - 6 d 1 / 2 {[5 / 2]}_{3}^{°}$
2 047.580	1	48 822.48	$5 d 1 / 2 {[5 / 2]}_{3}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
2 049.898	10	48 767.43
2 058.187	200	48 570.90	$6 p 3 / 2 {[3 / 2]}_{1} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
2 058.677	30	48 559.34
2 060.526	40	48 515.78	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
2 062.206	200	48 476.27	$6 p 3 / 2 {[1 / 2]}_{0} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
2 065.573	400c	48 397.25	$5 d 1 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
2 066.496	2 000c	48 375.64	$4 f 3 / 2 {[5 / 2]}_{3} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
2 069.198	40h	48 312.47	$6 p 1 / 2 {[1 / 2]}_{1} - 6 d 1 / 2 {[3 / 2]}_{2}^{°}$
2 073.184	3 000c	48 219.61	$6 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{3}^{°}$
2 075.148	150	48 173.97	$6 p 1 / 2 {[3 / 2]}_{2} - 6 d 1 / 2 {[3 / 2]}_{2}^{°}$
2 075.587	300	48 163.78
2 078.473	200c	48 096.91	$6 p 1 / 2 {[1 / 2]}_{1} - 6 d 1 / 2 {[5 / 2]}_{2}^{°}$
2 082.299	5	48 008.56
2 084.471	10	47 958.53	$6 p 1 / 2 {[3 / 2]}_{2} - 6 d 1 / 2 {[5 / 2]}_{2}^{°}$
2 093.657	20	47 748.15	$6 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[5 / 2]}_{2}^{°}$
2 095.865	25	47 697.84
2 143.227	1 500	46 643.91	$6 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
2 159.303	250	46 296.70	$6 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[7 / 2]}_{3}^{°}$
2 159.414	500	46 294.31	$6 p 3 / 2 {[1 / 2]}_{0} - 6 d 3 / 2 {[3 / 2]}_{1}^{°}$
2 167.440	25	46 122.91	$5 d 1 / 2 {[5 / 2]}_{2}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
2 170.270	300	46 062.78
2 175.183	100	45 958.73	$5 d 1 / 2 {[5 / 2]}_{3}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
2 189.061	400	45 667.41
2 191.618	500	45 614.13
2 197.453	4 000c	45 493.03	$4 f 1 / 2 {[5 / 2]}_{2} - 6 s 1 / 2 {[1 / 2]}_{1}^{°}$
2 202.848	400	45 381.61
2 204.342	500	45 350.86
2 205.471	500	45 327.64	$6 p 3 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
2 219.632	200	45 038.50	$4 f 3 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
2 221.115	1 000w	45 008.43	$5 d 1 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
2 223.312	300	44 963.96	$4 f 3 / 2 {[7 / 2]}_{3} - 6 s 3 / 2 {[3 / 2]}_{2}^{°}$
2 227.339	900	44 882.66	$4 f 3 / 2 {[7 / 2]}_{2} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
2 232.671	150	44 775.50
2 234.761	200	44 733.62
2 244.952	3 000	44 530.56	$5 d 1 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{0}$
2 264.837	250	44 139.63
2 265.914	7 500w	44 118.65	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[1 / 2]}_{0}$
2 296.801	500p	43 525.41
2 308.905	200	43 297.26
2 315.889	2 000	43 166.70	$5 d 1 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
2 348.355	750	42 569.96	$5 d 1 / 2 {[5 / 2]}_{3}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
2 355.313	750	42 444.21	$4 f 3 / 2 {[3 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
2 358.064	500	42 394.70
2 407.097	2 000c	41 531.19	$4 f 3 / 2 {[3 / 2]}_{1} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
2 414.635	75	41 401.54
2 417.577	25 000w	41 351.16	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
2 424.490	200	41 233.26
2 436.972	2 000	41 022.11
2 443.925	1 200p	40 905.39	$4 f 1 / 2 {[5 / 2]}_{2} - 5 d 1 / 2 {[3 / 2]}_{1}^{°}$
2 443.971	500p	40 904.62	$4 f 3 / 2 {[5 / 2]}_{3} - 5 d 1 / 2 {[5 / 2]}_{3}^{°}$
2 455.155d	8 000	40 718.29
2 457.453	60	40 680.23	$6 p 3 / 2 {[1 / 2]}_{0} - 6 d 3 / 2 {[1 / 2]}_{1}^{°}$
2 462.389	5 000p	40 598.68
2 469.274	3 000w	40 485.50
2 471.794	200	40 444.22
2 474.702	400	40 396.71
2 477.849	600	40 345.40
2 484.109	6 000	40 243.72
2 491.455	2 000	40 125.08
2 498.666	600	40 009.29
2 502.806	18 000c	39 943.12	$6 s 1 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{0}$
2 504.524	9 000	39 915.71
2 506.098	500	39 890.66
2 515.025	15 000	39 749.07	$6 s 1 / 2 {[1 / 2]}_{0}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
2 518.330	25	39 696.91	$4 f 3 / 2 {[5 / 2]}_{2} - 6 s 3 / 2 {[3 / 2]}_{1}^{°}$
2 532.746	250 000w	39 470.98	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
2 535.763	900d	39 424.01	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
2 540.711	50	39 347.25
2 542.864	25	39 313.93
2 547.373	300	39 244.35
2 548.437	10 000	39 227.97
2 549.753	200	39 207.71
2 549.940	200	39 204.84
2 552.984	500p	39 158.10
2 556.496	500	39 104.30
2 556.891	1 000	39 098.27
2 558.373	400p	39 075.62
2 558.751	600p	39 069.86
2 561.378	3 000	39 029.79
2 563.184	5 000	39 002.28
2 563.369	500	38 999.47
2 567.856	750	38 931.32
2 569.376	75	38 908.29
2 569.696	10 000	38 903.45
2 575.447	25 000	38 816.58
2 582.053	160 000d	38 717.28	$6 s 1 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[3 / 2]}_{2}$
2 582.936	7 500p	38 704.05
2 584.495	750	38 680.70
2 590.899	5 000	38 585.10
2 591.303	18 000c	38 579.09	$6 s 1 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[1 / 2]}_{1}$
2 593.041	150	38 553.23
2 593.509	25	38 546.27
2 594.846	5w	38 526.42	$6 p 1 / 2 {[3 / 2]}_{1} - 7 s 3 / 2 {[3 / 2]}_{1}^{°}$
2 596.878	500	38 496.26
2 597.501	2 500 000w	38 487.03	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{3}$
2 598.922	100	38 466.00	$4 f 3 / 2 {[5 / 2]}_{3} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
2 608.007	5000c	38 332.00	$5 d 1 / 2 {[3 / 2]}_{1}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
2 608.908	500	38 318.76
2 628.881	750	38 027.66
2 630.654	10 000d	38 002.03
2 641.465	500	37 846.50
2 643.369	7 500p	37 819.24
2 644.690	400	37 800.35	$4 f 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
2 649.159	5 000p	37 736.59
2 657.717	500	37 615.08
2 662.754	500 000w	37 543.94	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
2 666.860	100	37 486.13
2 685.157	1 000d	37 230.71
2 685.853	100	37 221.07
2 690.869	3 000d	37 151.69
2 693.454	9 000d	37 116.03
2 701.325	250d	37 007.90
2 706.988	250d	36 930.47
2 723.935	200	36 700.73
2 725.856	9 000d	36 674.86
2 726.286	15 000d	36 669.08
2 728.285	500	36 642.22
2 732.239	25 000d	36 589.18
2 733.880	3 000d	36 567.23
2 736.850	500p	36 527.55
2 760.719	100	36 211.75
2 761.269	300	36 204.53
2 765.808	1 500	36 145.12
2 767.705	250	36 120.35
2 769.067	300	36 102.59
2 834.705	1 500d	35 266.67
2 839.595	250	35 205.94	$4 f 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[3 / 2]}_{1}^{°}$
2 848.302	250 000w	35 098.32	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
2 851.892	15	35 054.14	$4 f 3 / 2 {[7 / 2]}_{3} - 5 d 1 / 2 {[3 / 2]}_{2}^{°}$
2 859.662	10p	34 958.89	$4 f 3 / 2 {[5 / 2]}_{3} - 5 d 1 / 2 {[5 / 2]}_{2}^{°}$
2 863.301	12 000c	34 914.47	$6 s 1 / 2 {[1 / 2]}_{0}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
2 874.071	500	34 783.65
2 879.503	750	34 718.03
2 882.646	200	34 680.18
2 883.779	300	34 666.55
2 952.432	900w	33 860.49
2 962.581	30 000c	33 744.49	$6 s 1 / 2 {[1 / 2]}_{1}^{°} - 6 p 1 / 2 {[3 / 2]}_{1}$
3 002.215	250	33 299.034
3 009.506	600 000w	33 218.365	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[5 / 2]}_{2}$
3 011.759	100	33 193.517
3 056.678	1500 000c	32 705.745	$6 s 3 / 2 {[3 / 2]}_{2}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
3 133.684	100	31 902.078
3 243.139	100	30 825.431	$6 s 3 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[1 / 2]}_{1}$
3 277.312	200h	30 504.020
3 282.373	500	30 456.989
3 522.282	5 000	28 382.571	$5 d 1 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[1 / 2]}_{0}$
3 562.110	50	28 065.234
3 650.399	2 000	27 386.464	$4 f 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[5 / 2]}_{3}^{°}$
3 692.542	15c	27 073.909	$6 p 1 / 2 {[3 / 2]}_{2} - 6 d 3 / 2 {[3 / 2]}_{2}^{°}$
3 796.966	100	26 329.342
3 806.71	200p	26 262.01
3 868.055	150c	25 845.460
3 868.928	500c	25 839.628
3 882.910	100	25 746.584
3 895.786	200	25 661.490
3 970.542	300	25 178.356
3 993.289	150	25 034.935
3 995.015	50	25 024.120
4 008.818	150c	24 937.959
4 064.003	125	24 599.335
4 069.357	2h	24 566.970	$4 f 3 / 2 {[3 / 2]}_{1} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
4 081.831	100	24 491.895
4 211.681	750c	23 736.802
4 211.988	25w	23 735.072	$5 d 1 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{2}$
4 270.804	2 000w	23 408.207	$4 f 3 / 2 {[5 / 2]}_{3} - 5 d 3 / 2 {[5 / 2]}_{3}^{°}$
4 549.796	1 500w	21 972.848	$4 f 3 / 2 {[3 / 2]}_{2} - 5 d 3 / 2 {[5 / 2]}_{2}^{°}$
4 584.174	75c	21 808.070	$5 d 1 / 2 {[3 / 2]}_{1}^{°} - 6 p 3 / 2 {[3 / 2]}_{1}$
4 739.078	50	21 095.251
4 756.708	125	21 017.066
4 774.678	50h	20 937.967
4 800.028	500	20 827.391

J	E(obs.)	E(calc.)	obs.-calc.	% J₁l	Percentage composition LS
1	143 355	143 218	137	100% 3/2[3/2]	100% ³D
2	145 949	145 957	−8	64% 3/2[3/2]	92% ³D + 7% ³F + 1% ¹D
	160 486	160 514	−28	69% 3/2[5/2]	57% ³F − 41% ¹D − 2% ³D
	175 014	174 994	20	91% 1/2[5/2]	58% ¹D + 37% ³F − 5% ³D
3	149 927	150 155	−228	86% 3/2[5/2]	76% ³D + 18% ³F + 5% ¹F + 1% ³G
	153 339	153 233	106	88% 3/2[7/2]	−54% ³G + 29% ¹F − 15% ³F + 2% ³D
		168 161		90% 1/2[7/2]	45% ³G + 36% ¹F − 19% ³F
		171 265		88% 1/2[5/2]	−48% ³F − 30% ¹F + 22% ³D
4		149 137		89% 3/2[9/2]	70% ³G − 27% ¹G + 3% ³F
		157 093		87% 3/2[7/2]	53% ³F + 41% ¹G + 6% ³G
		171 654		95% 1/2[7/2]	44% ³F − 32% ¹G − 24% ³G
5		148 854		100% 3/2[9/2]	100% ³G

λ(Å) (Ref. 14)	λ(Å) (Ref. 13)	λ(Å) (present)
2216.08	0.067	0.067
2297.75	0.737	0.740
2379.38	0.374	0.372
2476.72	0.599	0.606
2478.8^a	0.652	0.657
2651.60	0.501	0.497
2682.46	0.345	0.347
2684.90	0.757	0.754
3171.68	0.632^b	0.678
	0.735^b
3517.14	0.090^b	0.061
	0.217^b	0.226

Abstract

Cited By

Figures (4)

Tables (8)

Equations (187)

Journal of the Optical Society of America