Sixth and seventh spectra of arsenic: As vi and As vii

Th.A.M. van Kleef; Y. N. Joshi

doi:10.1364/JOSA.70.000491

Journal of the Optical Society of America
Vol. 70,
Issue 5,
pp. 491-499
(1980)
•https://doi.org/10.1364/JOSA.70.000491

Sixth and seventh spectra of arsenic: As vi and As vii

Th.A.M. van Kleef and Y. N. Joshi

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Th.A.M. van Kleef and Y. N. Joshi, "Sixth and seventh spectra of arsenic: As vi and As vii," J. Opt. Soc. Am. 70, 491-499 (1980)

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Abstract

The spectrum of arsenic was photographed in the regions 1200–500 Å and 300–100 Å on a 6.65 normal-incidence and a 10.7 m grazing- incidence spectrograph, respectively. The source used was a triggered spark. These measurements enabled us to revise and extend the earlier analysis of As vi. In this spectrum we established all levels of the 3d¹⁰, 3d⁹ 4s, 3d⁹ 4p, and 3d⁹ 4d configurations except 3d⁹ 4d¹S₀. In addition the identification of the ³P^O₁, ^lP^O₁, and ³D°₁ level’s in the 3d⁹ 5p, 3d⁹ 4f, and 3d⁹ 5f configurations has led to a new value of the ionization limit of As vi: 974 000 cm⁻¹ (120.7 eV). In As vii the earlier analysis of the 3d⁹−3d⁸ 4p transitions has been revised and extended and the 3p⁵ 3d^{10 2}P levels were located. The parametric level fitting calculations support the analysis. 109 lines have been classified in As vi and 47 lines in As vii.

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Parameter^a	Fitted parameters values (cm⁻¹)

	3d⁹4s	3d⁹4p	3d⁹4d
E_av	334802 ± 7	446395 ± 38	606745 ± 37
ζ₃_d	2271 ± 7	2276 ± 45	2199 ± 44
ζ₄_p		3444 ± 77
ζ₄_d			231 ± 44
F²(3d4p)		31702 ± 287
F²(3d4d)			22972 ± 378
F⁴(3d4d)			11067 ± 361
G°(3d4d)			4842^b.
G¹(3d4p)		10421 ± 137
G²(3d4s)	13515 ± 55
G²(3d4d)			7942 ± 538
G³(3d4p)		10268 ± 644
G⁴(3d4d)			6418 ± 892
Mean error σ^c	13.5	124	142

Configuration	Designation	J	Level value (cm ⁻¹			Percentage composition^a

			Expt	Calc	Expt − Calc
3d¹⁰	¹S	0	0.0	0.0	0.0	100%
3d⁹4s	³D	3	331 171.4	331 179.6	−8.2	100%
		2	333 225.2	333 214.8	10.4	80% + 20% ¹D
		1	336 856.9	336.856.6	0.3	100%
	¹D	2	340 224.8	340 227.3	−2.5	80% + 20% ³D
3d⁹4p	³P°	2	435 424.6	435 580.4	−155.8	95% + 5% ³D + 1% ¹D
		1	440 846.7	440 910.2	−63.5	96% + 3% ³D + 1% ¹P
		0	444 051.3	444 056.6	−5.3	100%
	³F°	4	443 082.0	442 894.5	187.5	100%
		3	439 918.6	439 869.7	48.9	67% + 28% ¹F + 6% ³D
		2	443 802.8	443 683.4	119.4	94% + 5% ³D + 1% ¹D
	³D°	3	451 800.5	451 756.6	43.9	58% + 24% ³F + 18% ¹F
		2	455 556.5	455 613.3	−56.8	60% + 35% ¹D + 3% ³F + 1% ³P
		1	454 565.2	454 586.6	−21.4	73% + 23% ¹D + 4% ³P
	¹D°	2	449 462.0	449 526.9	−64.9	64% + 31% ³D + 3% ³P + 2% ³F
	¹F°	3	449 467.2	449 506.6	−39.4	54% + 36% ³D + 9% ³F
	¹P°	1	452 398.7	452 391.5	7.2	76% + 24% ³D
3d⁹4d	³S	1	595 239.2	595 382.8	−143.6	93% + 5%³P + 1% ¹P
	³G	5	602 235.6	601 985.4	250.2	100%
		4	602 465.8	602 351.2	114.6	66% + 34% ¹G + 1% ³F
		3	605 538.8	605 420.9	117.9	69% + 17% ¹F + 9% ³F + 5% ³D
	³P	2	602 801.8	602 903.0	−101.2	76% + 24% ³D + 1% ³F
		1	606 571.0	606 548.4	22.6	56% + 37% ¹P + 7% ³S
		0	605 513.2	605 518.7	−5.5	100%
	³D	3	604 648.6	604 655.7	−7.1	87% + 10% ³F + 3% ³G
		2	606 356.9	606 350.4	6.5	51% + 22% ¹D + 16% ³P + 11% ³F
		1	609 195.1	609 035.4	159.7	80% + 10% ³P + 9% ¹P
	³F	4	609 830.3	609 821.9	8.4	55% + 25% ¹G + 20% ³G
		3	612 715.4	612 854.0	−138.6	54% + 38% ¹F + 8% ³D
		2	612 954.0	613 015.6	−61.6	61% + 38% ¹D + 1% ³P
	¹P	1	602 730.5	602 857.6	−127.1	52% + 28% ³P + 19% ³D
	¹G	4	606 508.3	606 607.8	−99.5	41% + 44% ³F + 15% ³G
	¹F	3	608 930.5	608 982.4	−51.9	44% + 28% ³G + 28% ³F
	¹D	2	611 499.1	611 442.8	56.3	40% + 27%³F + 26%³D + 8%³P
	¹S	0		644 706.9		100%

Configuration	Designation	Level value^a (cm⁻¹)
3d⁹5p	${3_{P}}_{1}^{°}$	698 340
	${1_{P}}_{1}^{°}$	703 310
	${3_{D}}_{1}^{°}$
3d⁹4f	${3_{P}}_{1}^{°}$	723 620
	${3_{D}}_{1}^{°}$	726 720
	${1_{P}}_{1}^{°}$	732 680
3d⁹5f	${3_{P}}_{0}^{1}$	813 430
	${3_{D}}_{1}^{°}$	816 770
	${3_{P}}_{1}^{°}$	822 520

Int^a	λ(A°)	σ(cm⁻¹)	Classification	Δ(cm⁻¹)^b	Notes
19	121.578	822 520	$3 d^{10} {1_{S}}_{0} - 3 d^{9} 5 f {1_{P}}_{1}^{°}$
17	122.433	816 770	$- 3 d^{9} 5 f {3_{D}}_{1}^{°}$
2	122.936	813 430	$- 3 d^{9} 5 f {3_{P}}_{1}^{°}$
24	136.485	732 680	$- 3 d^{9} 4 f {1_{P}}_{1}^{°}$
22	137.605	726 720	$- 3 d^{9} 4 f {3_{D}}_{1}^{°}$
6	138.194	723 620	$- 3 d^{9} 4 f {3_{P}}_{1}^{°}$
25	142.184	703 310	$- 3 d^{9} 5 p {1_{P}}_{1}^{°}$
20	143.197	698 340	$- 3 d^{9} 5 p {3_{P}}_{1}^{°}$
72	219.990	454 565.2	$- 3 d^{9} 4 p {3_{D}}_{1}^{°}$
73	221.044	452 398.7	$- 3 d^{9} 4 p {1_{P}}_{1}^{°}$
44	226.836	440 846.7	$- 3 d^{9} 4 p {3_{P}}_{1}^{°}$
5	584.296	171 146.1	$3 d^{9} 4 p {3_{P}}_{2}^{°} - 3 d^{9} 4 d {3_{P}}_{1}$	−0.3
7	585.981	170 653.9	${3_{P}}_{1}^{°} - {1_{D}}_{2}$	−1.5	c
63	590.930	169 224.9	${3_{P}}_{2}^{°} - {3_{D}}_{3}$	0.9
41	591.186	169 151.4	${3_{F}}_{2}^{°} - {3_{F}}_{2}$	0.2
27	591.671	169 012.8	${3_{F}}_{3}^{°} - {1_{F}}_{3}$	−0.9
7	594.002	168 349.6	${3_{P}}_{1}^{°} - {3_{D}}_{1}$	1.2	c
16	596.317	167 696.1	${3_{F}}_{2}^{°} - {1_{D}}_{2}$	−0.2
69	597.453	167 377.2	${3_{P}}_{2}^{°} - {3_{P}}_{2}$	0.0
27	597.706	167 306.2	${3_{P}}_{2}^{°} - {1_{P}}_{1}$	0.3
35	599.705	166 748.8	${3_{F}}_{4}^{°} - {3_{F}}_{4}$	0.5
17	600.837	166 434.6	${3_{F}}_{3}^{°} - {3_{D}}_{2}$	−0.2
27	603.411	165 724.5	${3_{P}}_{1}^{°} - {3_{P}}_{1}$	0.2
As iii	603.768	165 626.4	${3_{F}}_{3}^{°} - {3_{G}}_{3}$		d
59	604.195	165 509.4	${3_{P}}_{1}^{°} - {3_{D}}_{2}$	−1.0
7	604.621	165 392.9	${3_{F}}_{2}^{°} - {3_{D}}_{1}$	0.6
55	605.534	165 143.4	${3_{P}}_{0}^{°} - {3_{D}}_{1}$	−0.4
65	605.590	165 128.2	${3_{F}}_{2}^{°} - {1_{F}}_{3}$	0.5
34	607.054	164 730.1	${3_{F}}_{3}^{°} - {3_{D}}_{3}$	0.1
44	607.288	164 666.5	${3_{P}}_{1}^{°} - {3_{P}}_{0}$	0.0
25	611.659	163 489.9	${1_{D}}_{2}^{°} - {3_{F}}_{2}$	−1.6
25	611.659	163 489.9	${1_{F}}_{3}^{°} - {3_{F}}_{2}$	2.9
67	611.899	163 425.7	${3_{F}}_{4}^{°} - {1_{G}}_{4}$	−0.6
43	612.561	163 249.2	${1_{F}}_{3}^{°} - {3_{F}}_{3}$	0.8
52	613.917	162 888.5	${3_{F}}_{3}^{°} - {3_{P}}_{2}$	5.3	e
73	615.204	162 547.8	${3_{F}}_{3}^{°} - {3_{G}}_{4}$	0.6.
30	615.310	162 519.7	${3_{P}}_{0}^{°} - {3_{P}}_{1}$	0.0
31	617.141	162 037.6	${1_{D}}_{2}^{°} - {1_{D}}_{2}$	1.0	^f
38	617.724	161 884.7	${3_{P}}_{1}^{°} - {1_{P}}_{1}$	0.9
70	618.290	161 736.3	${3_{F}}_{2}^{°} - {3_{G}}_{3}$	0.3
24	618.941	161 566.3	${3_{F}}_{4}^{°} - {3_{D}}_{3}$	−0.3
40	621.446	160 915.0	${3_{D}}_{3}^{°} - {3_{F}}_{3}$	0.1
59	622.836	160 555.9	${1_{P}}_{1}^{°} - {3_{F}}_{2}$	0.6
25	623.587	160 362.6	${1_{F}}_{3}^{°} - {3_{F}}_{4}$	−0.5
72	625.724	159 814.8	${3_{P}}_{2}^{°} - {3_{S}}_{1}$	0.2
69	627.082	159 468.8	${1_{D}}_{2}^{°} - {1_{F}}_{3}$	0.8
33	627.417	159 383.7	${3_{F}}_{4}^{°} - {3_{G}}_{4}$	−0.1
73	628.340	159 153.6	${3_{F}}_{4}^{°} - {3_{G}}_{5}$	0.0
7	631.362	158 387.7	${3_{D}}_{1}^{°} - {3_{F}}_{2}$	−1.1	c
71	632.790	158 030.3	${3_{D}}_{3}^{°} - {3_{F}}_{4}$	0.5
47	635.330	157 398.4	${3_{D}}_{2}^{°} - {3_{F}}_{2}$	−1.1
69	636.301	157 158.3	${3_{D}}_{2}^{°} - {3_{F}}_{3}$	−0.6
9	636.412	157 131.0	${3_{D}}_{3}^{°} - {1_{F}}_{3}$	1.0
71	636.777	157 040.8	${1_{F}}_{3}^{°} - {1_{G}}_{4}$	−0.3
66	637.210	156 934.0	${3_{D}}_{1}^{°} - {1_{D}}_{2}$	0.1
63	637.371	156 894.4	${1_{D}}_{2}^{°} - {3_{D}}_{2}$	0.5
36	637.772	156 795.9	${1_{P}}_{1}^{°} - {3_{D}}_{1}$	−0.5
53	640.714	156 076.0	${1_{D}}_{2}^{°} - {3_{G}}_{3}$	0.6
43	641.264	155 942.0	${3_{D}}_{2}^{°} - {1_{D}}_{2}$	−0.6
65	644.404	155 182.1	${1_{F}}_{3}^{°} - {3_{D}}_{3}$	0.7
4	646.382	154 707.4	${3_{D}}_{3}^{°} - {1_{G}}_{4}$	−0.4
18	646.707	154 629.5	${3_{D}}_{1}^{°} - {3_{D}}_{1}$	−0.4
33	647.701	154 392.3	${3_{P}}_{1}^{°} - {3_{S}}_{1}$	−0.2
14	648.629	154 171.4	${1_{P}}_{1}^{°} - {3_{P}}_{1}$	−0.9
8	649.561	153 950.0	${1_{P}}_{1}^{°} - {3_{D}}_{2}$	−1.2	c
5	650.455	153738.5	$3 d^{9} 4 p {3_{D}}_{3}^{°} - {3_{G}}_{3}$	0.7
31	652.169	153334.5	${1_{F}}_{3}^{°} - {3_{P}}_{2}$	−0.1
22	652.450	153268.4	${1_{D}}_{2}^{°} - {1_{P}}_{1}$	0.4
6	653.604	152997.9	${1_{F}}_{3}^{°} - {3_{G}}_{4}$	−0.7
60	654.247	152847.6	${3_{D}}_{3}^{°} - {3_{D}}_{3}$	−0.5
18	657.872	152005.3	${3_{D}}_{1}^{°} - {3_{P}}_{1}$	−0.5
17	662.192	151013.6	${3_{D}}_{2}^{°} - {3_{P}}_{1}$	−0.9
25	662.250	151000.4	${3_{D}}_{3}^{°} - {3_{P}}_{2}$	−0.9
59	663.152	150794.9	${3_{D}}_{2}^{°} - {3_{D}}_{2}$	−1.5	e
25	665.196	150331.5	${1_{P}}_{1}^{°} - {1_{P}}_{1}$	−0.3
11	674.923	148165.1	${3_{D}}_{1}^{°} - {1_{P}}_{1}$	−0.2
13	803.957	124384.8	$3 d^{9} 4 s {3_{D}}_{3} - 3 d^{9} 4 p {3_{D}}_{2}^{°}$	−0.3
27	817.448	122332.0	${3_{D}}_{2} - {3_{D}}_{2}^{°}$	0.7
38	824.132	121339.8	${3_{D}}_{2} - {3_{D}}_{1}^{°}$	−0.2
52	828.987	120629.1	${3_{D}}_{3} - {3_{D}}_{3}^{°}$	0.0
9	839.114	119173.3	${3_{D}}_{1} - {1_{P}}_{1}^{°}$	−0.2
42	842.467	118699.1	${3_{D}}_{1} - {3_{D}}_{2}^{°}$	−0.5
45	843.346	118575.3	${3_{D}}_{2} - {3_{D}}_{3}^{°}$	0.0
52	845.341	118295.4	${3_{D}}_{3} - {1_{F}}_{3}^{°}$	−0.4
47	849.561	117707.8	${3_{D}}_{1} - {3_{D}}_{1}^{°}$	−0.5
44	860.295	116239.3	${3_{D}}_{2} - {1_{F}}_{3}^{°}$	−2.7	e
49	860.318	116236.2	${3_{D}}_{2} - {1_{D}}_{2}^{°}$	−1.1
44	865.486	115542.0	${3_{D}}_{1} - {1_{P}}_{1}^{°}$	0.2
49	865.061	115332.1	${1_{D}}_{2} - {3_{D}}_{2}^{°}$	−0.4
16	874.575	114341.2	${1_{D}}_{2} - {3_{D}}_{1}^{°}$	0.8
4	887.849	112631.8	${3_{D}}_{3} - {3_{F}}_{2}^{°}$	0.4
27	888.058	112605.3	${3_{D}}_{1} - {1_{D}}_{2}^{°}$	−0.3
29	891.470	112174.3	${1_{D}}_{2} - {1_{P}}_{1}^{°}$	0.4
59	893.570	111910.6	${3_{D}}_{3} - {3_{F}}_{4}^{°}$	0.0
47	896.249	111576.1	${1_{D}}_{2} - {3_{D}}_{3}^{°}$	0.4
42	904.344	110577.4	${3_{D}}_{2} - {3_{F}}_{2}^{°}$	−0.2
64	915.398	109242.1	${1_{D}}_{2} - {1_{F}}_{3}^{°}$	−0.3
63	915.436	109237.6	${1_{D}}_{2} - {1_{D}}_{2}^{°}$	−0.1	e
58	919.568	108746.7	${3_{D}}_{3} - {3_{F}}_{3}^{°}$	0.5
58	929.186	107621.1	${3_{D}}_{2} - {3_{P}}_{1}^{°}$	−0.4
58	932.885	107194.4	${3_{D}}_{1} - {3_{P}}_{0}^{°}$	0.0
62	935.054	106945.7	${3_{D}}_{1} - {3_{F}}_{2}^{°}$	−0.2
70	937.256	106694.3	${3_{D}}_{2} - {3_{F}}_{3}^{°}$	0.9
65	959.204	104253.2	${3_{D}}_{3} - {3_{P}}_{2}^{°}$	0.0
63	961.670	103985.7	${3_{D}}_{1} - {3_{P}}_{1}^{°}$	−4.1	f
24	965.451	103578.5	${1_{D}}_{2} - {3_{F}}_{2}^{°}$	0.5
8	978.488	102198.4	${3_{D}}_{2} - {3_{P}}_{2}^{°}$	−1.0
39	993.820	100621.8	${1_{D}}_{2} - {3_{P}}_{1}^{°}$	−0.1
21	1003.075	99693.5	${1_{D}}_{2} - {3_{F}}_{3}^{°}$	−0.3
4	1050.429	95199.2	${1_{D}}_{2} - {3_{P}}_{2}^{°}$	−0.6

Configuration	Parameter	Ga iv (Ref. 14)	Ge v (Ref. 14)	As vi (This work)	Se vii^a (Ref. 15)
3d⁹4s	E_av	1.019	0.995	0.984	0.978
	ζ₃_d	1.008	1.008	1.008	1.008
	G²(3d4s)	0.946	0.970	0.989	1.003
3d⁹4p	E_av	1.038	1.016	1.005	0.999
	ζ₃_d	1.003	1.006	1.009	1.010
	ζ₄_d	1.199	1.179	1.165	1.153
	F²(3d4p)	0.961	0.971	0.978	0.984
	G¹(3d4p)	0.939	0.948	0.955	0.961
	G³(3d4p)	0.928	0.970	1.005	1.033
3d⁹4d	E_av	1.042	1.023	1.013	1.007
	F²(3d4d)	1.063	1.086	1.077	1.071
	F⁴(3d4d)	1.203	1.202	1.205	1.207
	ζ₃_d	0.941	0.967	0.971	0.974
	ζ₄_d	0.429	1.144	1.129	1.112
	G°(3d4d)^b	0.65	0.65	0.65	0.65
	G²(3d4d)	0.953	0.981	0.992	0.996
	G⁴(3d4d)	0.668	1.049	1.083	1.103

Parameter^a	As vii		Se viii
Parameter^a	3d⁹	3d⁸4p	3d⁸4p
E_av	2282	553 927 ± 73	688 571 ± 82
F²(3d3d)		140 625 ± 322	151 437 ± 352
F⁴(3d3d)		88 252 ± 268	94 591 ± 303
ζ₃_d	2282	2 363 ± 58	2 954 ± 65
ζ₄_p		4 064 ± 85	5 300 ± 96
F²(3d4p)		35 678 ± 344	39 488 ± 377
G¹(3d4p)		11 302 ± 139	12 321 ± 159
G³(3d4p)		12 172 ± 450	13 530 ± 511
α		111 ± 8	122 ± 9
σ^b		144	154

Configuration	Designation	J	Energy level (cm ⁻¹)			Percentage compositioion^a

			Expt value	Calc value	Δ
3d⁹	²D	2½	0	0	0	100%
3d⁹		1½	5705	5 705	0	100%
3d⁸(³F)4p	(³F)⁴D°	3½		524 841.9		86% + 7%(³F)⁴F + 5%(³P)⁴D + 2%(³F)²F
		2½		529 827.2		84% + 8%(³F)⁴F + 7%(³P)⁴D + 1%(³F)²F
		1½		533 559.0		84% + 9%(³P)⁴D + 6%(³F)⁴F + 1%(¹D)²P
		½		535 820.1		87% + 11%(³P)⁴D + 2%(¹D)²P
3d⁸(³F)4p	(³F)⁴G°	5½		532 542.7		100%
		4½		529 391.7		53% + 27%(³F)²G + 20%(³F)⁴F
		3½		532 617.0		75% + 13%(³F)⁴F + 10%(³F)²G + 2%(³F)⁴D
		2½		534 726.0		86% + 7%(³F)⁴F + 20%(¹D)²F + 1%(³F)²F
3d⁸(³F)4p	(³F)⁴F°	4½		536 812.0		78% + 15%(³F)²G + 7%(³F)⁴G
		3½	538 621.5	538 549.8	71.7	53% + 30%(³F)²F + 9%(³F)⁴G + 6%(³F)⁴D
		2½	539 938.1	539 861.7	76.4	53% + 26%(³F)²D + 8%(³F)⁴G + 5%(¹D)²D
		1½	539 412.1	539 523.9	−111.8	55% + 24%(³F)²D + 13%(¹D)²D + 4%(³F)⁴D
3d⁸(³F)4p	(³F)²G°	4½		539 811.6		58% + 40%(³F)⁴G + 2%(³F)⁴F
3d⁸(³F)4p		3½	544 423.3	544 439.3	−16.0	75% + 14%(³F)⁴G + 5%(³F)²F + 4%(¹D)²F
3d⁸(³F)4p	(³F)²D°	2½	542 563.3	542 643.4	−80.1	52% + 19%(³F)⁴F + 16%(³F)²F + 5%(¹D)²D
3d⁸(³F)4p		1½	546 046.5	546 025.5	21.0	45% + 37%(³F)⁴F + 8%(¹D)²D + 5%(¹D)²P
3d⁸(³F)4p	(³F)²F°	3½	543 280.6	543 323.9	−43.3	60% + 25%(³F)⁴F + 12%(³F)²G + 2%(¹G)²F
3d⁸(³F)4p		2½	547 900.8	547 795.5	105.3	71% + 12%(³F)²D + 10%(³F)⁴F + 3%(³F)⁴G
3d⁸(³P)4p	(³P)²P°	2½	553 105.0	553 259.8	−154.8	61% + 13%(¹D)²F + 11%(¹D)²D + 5%(³P)⁴D
		1½	552 201.4	552 297.8	−96.4	71% + 11%(³F)²D + 8%(¹D)²P + 4%(³P)²P
		½		553 446.2		91% + 5%(¹D)²P + 3%(³P)²P + 1%(³P)⁴D
3d⁸(¹D)4p	(1D)²F°	3½	559 802.8	559 590.3	212.5	67% + 15%(¹G)²F + 12%(³P)⁴D + 2%(³F)²G
3d⁸(¹D)4p		2½	556 445.1	556 414.7	30.4	65% + 24%(³P)⁴P + 4%(¹G)²F + 3%(³P)²D
3d⁸(¹D)4p	(1D)²D°	2½	561 740.8	561 898.0	−157.2	71% + 11%(³P)²D + 6%(³P)⁴P + 4%(³P)⁴D
3d⁸(¹D)4p		1½	559 596.8	559 574.0	22.8	40% + 18%(³P)⁴P + 17%(³P)²D + 15%(¹D)²P
3d⁸(¹D)4p	(1D)²P°	1½	563 092.7	563 165.3	−72.6	43% + 31%(¹D)²D + 8%(³P)⁴D + 6%(³P)²P
3d⁸(¹D)4p		½	560 445.9	560 396.5	49.4	57% + 30%(³P)²P + 7%(³P)⁴P + 2%(³P)²S
3d⁸(³P)4p	(³P)⁴D°	3½	567 151.1	566 969.6	181.5	71% + 22%(¹G)²F + 3%(³P)⁴D + 2%(¹D)²F
		2½	565 302.4	565 474.9	−172.5	55% + 17%(³P)²D + 8%(³P)⁴P + 7%(¹D)²F
		1½	565 188.3	564 968.6	219.7	67% + 12%(¹D)²P + 5%(³F)⁴D + 5%(³P)²D
		½	565 053.7	564 823.3	230.4	84% + 10%(³F)⁴D + 3%(³P)²P + 3%(¹D)²P
3d⁸(³P)4p	(³P)⁴D°	1½	569 925.5	569 909.5	16.0	74% + 11%(¹D)²P + 7%(³P)²D + 3%(³P)⁴D
3d⁸(³P)4p		½	574 417.6	574 313.4	104.2	55% + 21%(¹D)²P + 18%(³P)²S + 4%(³P)⁴D
3d⁸(³P)4p	(³P)²D°	2½	570 760.4	570 800.6	−40.2	64% + 28%(³P)⁴D + 4%(¹G)²F + 2%(³F)⁴D
3d⁸(³P)4p		1½	572 713.0	572 722.1	−9.1	83% + 10%(³P)⁴D + 2%(³P)²P + 1%(³P)²D
3d⁸(¹G)4p	(¹G)²F°	3½	572 411.0	572 585.9	−174.9	56% + 26%(¹D)²F + 11%(³P)⁴D + 3%(^JG)²G
3d⁸(¹G)4p		½	575 315.9	575 310.1	5.8	82%+9%(¹D)²F+4%(³F)²P+3%(³P)²D
3d⁸(¹G)4p	(¹G)²H°	5½		572 871.3		100%
3d⁸(¹G)4p		4½		567 955.6		97% + 3%(¹G)²G
3d⁸(³P)4p	(³P)²S°	½	577 086.7	577 344.6	−257.9	79% + 11%(¹D)²P+9%(³P)²P+1%(³P)⁴P
3d⁸(³P)4p	(³P)⁴S°	1½		577 120.1		96% + 2%(³P)⁴P+1%(¹D)²P+1%(³P)²P
3d⁸(¹G)4p	(¹G)²G°	4½		585 166.9		97% + 3%(¹G)²H
3d⁸(¹G)4p		3½	584 347.7	584 325.0	22.7	96% + 4%(¹G)²F
3d⁸(¹S)4p	(¹S)²P°	1½	630 256.1	630 212.4	43.7	98% + 2%(¹D)²P
3d⁸(¹S)4p		½	624 443.7	624 470.5	−26.8	97% + 2%(1D)²P
3p⁵3d¹⁰	²P°	1½	799 920	799 920	0	100%
3p⁵3d¹⁰		½	840 575	840 575	0	100%

Int^a	λ(A°)	σ(cm⁻¹)		Classification
15	119.779	834 870	0	$3 d^{9} {2_{D}}_{1 ½} - 3 p {5_{3} d}^{10} {2_{P}}_{1 / 2}^{°}$
40	125.014	799 920	0	${2_{D}}_{2 ½} - 3 p {5_{3} d}^{10} {2_{P}}_{1 ½}^{°}$
10	125.910	794 220	5	${2_{D}}_{1 ½} - 3 p {5_{3} d}^{10} {2_{P}}_{1 ½}^{°}$
28	158.666	630 256.1	0.0	${2_{D}}_{2 ½} - (1_{S}) {2_{P}}_{1 ½}^{°}$
4	160.115	624 551.1	0.0	${2_{D}}_{1 ½} - (1_{S}) {2_{P}}_{1 ½}^{°}$
25	161.619	618 738.7	0.0	${2_{D}}_{1 ½} - (1_{S}) {2_{P}}_{½}^{°}$
18	171.131	584 347.7	0.0	${2_{D}}_{2 ½} - (1_{G}) {2_{G}}_{3 ½}^{°}$
13	173.817	575 316.3	0.4	${2_{D}}_{2 ½} - (1_{G}) {2_{F}}_{2 ½}^{°}$
35	174.606	572 713.1	0.1	${2_{D}}_{2 ½} - (3_{P}) {2_{D}}_{1 ½}^{°}$
56	174.699	572 411.0	0.0	${2_{D}}_{2 ½} - (1_{G}) {2_{F}}_{3 ½}^{°}$
34	175.014	571 381.7	0.0	${2_{D}}_{1 ½} - (3_{P}) {2_{S}}_{½}^{°}$
15	175.205	570 760.4	0.0	${2_{D}}_{2 ½} - (3_{P}) {2_{D}}_{2 ½}^{°}$
50	175.462	569 925.3	−0.2	${2_{D}}_{2 ½} - (3_{P}) {2_{P}}_{1 ½}^{°}$
56	175.559	569 610.5	−0.4	${2_{D}}_{1 ½} - (1_{G}) {2_{F}}_{2 ½}^{°}$
44	175.836	568 712.6	0.0	${2_{D}}_{1 ½} - (3_{P}) {2_{P}}_{½}^{°}$
52	176.320	567 151.1	0.0	${2_{D}}_{2 ½} - (3_{P}) {4_{D}}_{3 ½}^{°}$
22	176.364	567 007.9	−0.1	${2_{D}}_{1 ½} - (3_{P}) {2_{D}}_{1 ½}^{°}$
39	176.932	565 188.8	0.0	${2_{D}}_{2 ½} - (3_{P}) {4_{D}}_{1 ½}^{°}$
25	176.974	565 055.4	0.0	${2_{D}}_{1 ½} - (3_{P}) {2_{D}}_{2 ½}^{°}$
40	177.236	564 220.7	0.2	${2_{D}}_{1 ½} - (3_{P}) {2_{P}}_{1 ½}^{°}$
24	177.591	563 092.3	−0.4	${2_{D}}_{2 ½} - (1_{D}) {2_{P}}_{1 ½}^{°}$
55	178.018	561 741.1	0.3	${2_{D}}_{2 ½} - (1_{D}) {2_{D}}_{2 ½}^{°}$
51	178.634	559 802.8	0.0	${2_{D}}_{2 ½} - (1_{D}) {2_{F}}_{3 ½}^{°}$
30	178.700	559 597.4	0.6	${2_{D}}_{2 ½} - (1_{D}) {2_{D}}_{1 ½}^{°}$
30	178.700	559 597.4	0.0	${2_{D}}_{1 ½} - (3_{P}) {4_{D}}_{2 ½}^{°}$
15	178.779	559 348.7	0.0	${2_{D}}_{1 ½} - (3_{P}) {4_{D}}_{½}^{°}$
28	179.408	557 388.1	0.4	${2_{D}}_{1 ½} - (1_{D}) {2_{P}}_{1 ½}^{°}$
16	179.843	556 035.4	−0.4	${2_{D}}_{1 ½} - (1_{D}) {2_{D}}_{2 ½}^{°}$
8	180.264	554 740.9	0.0	${2_{D}}_{1 ½} - (1_{D}) {2_{P}}_{½}^{°}$
50	180.541	553 891.2	−0.1	${2_{D}}_{1 ½} - (1_{D}) {2_{D}}_{1 ½}^{°}$
38	180.797	553 105.5	0.5	${2_{D}}_{2 ½} - (3_{P}) {4_{P}}_{2 ½}^{°}$
18	181.093	552 201.6	0.2	${2_{D}}_{2 ½} - (3_{P}) {4_{P}}_{1 ½}^{°}$
39	181.574	550 740.1	0.0	${2_{D}}_{1 ½} - (1_{D}) {2_{F}}_{2 ½}^{°}$
53	182.515	547 900.8	0.0	${2_{D}}_{2 ½} - (3_{F}) {2_{F}}_{2 ½}^{°}$
31	182.682	547 399.5	−0.5	${2_{D}}_{1 ½} - (3_{P}) {4_{P}}_{2 ½}^{°}$
40	182.984	546 496.3	−0.1	${2_{D}}_{1 ½} - (3_{P}) {4_{P}}_{1 ½}^{°}$
21	183.135	546 046.2	−0.3	${2_{D}}_{2 ½} - (3_{F}) {2_{D}}_{1 ½}^{°}$
33	183.681	544 423.3	0.0	${2_{D}}_{2 ½} - (3_{F}) {2_{G}}_{3 ½}^{°}$
52	184.067	543 280.6	0.0	${2_{D}}_{2 ½} - (3_{F}) {2_{F}}_{3 ½}^{°}$
53	184.310	542 563.0	−0.3	${2_{D}}_{2 ½} - (3_{F}) {2_{D}}_{2 ½}^{°}$
33	184.435	542 195.8	0.0	${2_{D}}_{1 ½} - (3_{F}) {2_{F}}_{2 ½}^{°}$
47	185.068	540 341.7	0.2	${2_{D}}_{1 ½} - (3_{F}) {2_{D}}_{1 ½}^{°}$
55	185.206	539 938.1	0.0	${2_{D}}_{2 ½} - (3_{F}) {4_{F}}_{2 ½}^{°}$
13	185.381	539 411.6	−0.5	${2_{D}}_{2 ½} - (3_{F}) {4_{F}}_{1 ½}^{°}$
49	195.659	538 621.5	0.0	${2_{D}}_{2 ½} - (3_{F}) {4_{F}}_{3 ½}^{°}$
40	186.269	536 858.5	0.2	${2_{D}}_{1 ½} - (3_{F}) {2_{D}}_{2 ½}^{°}$
40	187.369	533 707.6	0.5	${2_{D}}_{1 ½} - (3_{F}) {4_{F}}_{1 ½}^{°}$

Parameter	Ga v	Ge vi	As vii	Se viii
Parameter	(Ref. 20)	(Ref. 21)	(This work)	(Ref. 19)
E_av	1.016	1.006	1.000	0.997
F²(3d3d)	0.866	0.874	0.883	0.888
F⁴(3d3d)	0.868	0.880	0.877	0.876
F²(3d4p)	1.025	0.987	0.983	0.979
G¹(3d4p)	0.931	0.932	0.934	0.922
G³(3d4p)	0.990	1.030	1.057	1.054
ζ₃_d	0.989	0.985	0.981	0.998
ζ₄_p	1.124	1.120	1.120	1.112

Parameter	LSF	HF	LSF/HF
E_av	813 470	826 145	0.985
ζ₃_p	27 103	25 651	1.057

Parameter	LSF	HF	LSF/HF
E_av	813 470	826 145	0.985
ζ₃_p	27 103	25 651	1.057

Abstract

References

Cited By

Figures (3)

Tables (10)

Equations (168)

Journal of the Optical Society of America

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