Table 1
Summary of the Hydrazine FIR Laser Lines Pumped by a 12 C 16 O 2 Laser
12 C 16 O 2 Laser Pump Line
a
Frequency (MHz) Wavelength (μ m)
b
Pressure [Pa (mTorr)] Relative Intensity
c
Relative Polarization Offset (MHz) Ref.
9 R ( 52 )
4 463 894.4 67.159 53(400) W ∥ 43
8
9 R ( 50 )
4 553 228.0 65.842 53(400) M ∥
- 9
7
9 R ( 48 )
574 117.3 522.180 7(50) W
6
9 R ( 46 )
1 945 888.1 154.065 11(80) M ∥
- 2
7
454.7 33(250) M ∥
- 2
7
9 R ( 42 )
858 156.2 349.345 20(150) VS ⊥
6 , 7
9 R ( 36 )
2 950 180.8 101.618 27(200) S ∥
- 38
7
9 R ( 34 )
1 055 803.2 283.947 13(100) VS ∥
7
9 R ( 26 )
916 511.7 327.102 20(150) S ∥
- 13
1 , 7
9 R ( 18 )
812 750.0 368.862 27(200) M
3
9 R ( 14 )
3 497 481.1 85.717 27(200) S ∥
- 50
7
9 R ( 12 )
3 975 563.7 75.409 60(450) W ∥ 35
8
9 R ( 10 ) ′
4 104 665.7 73.037 47(350) W ∥ 43
8
9 R ( 10 ) ″
1 203 541.3 249.092 20(150) M ∥
- 20
1 , 7
9 R ( 8 )
3 696 638.2 81.099 33(250) S ∥
- 12
7
9 R ( 4 )
3 918 281.0 76.511 13(100) M ∥ 40
7
125.7 20(150) M ∥
7
9 SP ( 11 )
85.9 13(100) S ∥
7
9 P ( 08 )
708.3 20(150) M ∥
7
9 P ( 12 ) ′
904 899.4 331.299 20(150) S ∥(⊥)
2 , 6
9 P ( 12 ) ″
903 889.6 331.669 20(150) S ∥(⊥)
1 , 2 , 6
9 P ( 12 ) ‴
567 925.4 527.873 7(50) M
2
9 P ( 14 )
3 317 269.0 90.373 53(400) VS ∥
- 32
7
9 P ( 16 ) ′
3 536 744.1 84.765 20(150) M ∥ 8
7
9 P ( 16 ) ″
3 304 457.8 90.724 20(150) S ∥
- 45
7
9 SP ( 13 )
2 884 000.7 103.950 53(400) VS ∥
- 12
7
9 P ( 20 )
963 731.4 311.075 4(30) M ∥
1 , 2
9 P ( 20 )
483.5 ∥
1
9 P ( 22 )
73.07 New 2 510 428.7 119.419 43(320) W ∥ 39
8
9 P ( 30 )
1 920 424.5 156.107 20(150) M ∥ 28
7
331.5 ∥
1
9 P ( 32 )
4 058 513.9 73.868 40(300) S ∥ 28
7
9 P ( 34 )
102.0 53(400) VS ∥ New
9 P ( 36 ) ′
2 946 196.7 101.756 20(150) M ∥
6
9 P ( 36 ) ″
2 225 036.9 134.736 27(200) W
6
9 P ( 36 ) ‴
1 619 248.8 185.143 13(100) W
6
9 P ( 46 )
1 866 375.4 160.628 27(200) VS ∥
- 7
7
960 791.1 312.027 27(200) VS ∥
- 7
6 , 7
9 P ( 50 )
2 104 368.9 142.462 20(150) VS ∥ 43
7
9 P ( 52 )
2 473 562.9 121.199 27(200) S ∥
- 45
7
9 P ( 56 )
1 644 081.4 182.346 20(150) S ∥
- 32
7
10 R ( 54 ) ′
2 729 129.8 109.849 21(160) M ∥
- 19
7
10 R ( 54 ) ″
2 340 717.5 128.077 33(250) S ∥ 19
7
10 R ( 52 )
2 106 238.3 142.335 43(320) S ∥ 40
7
10 R ( 50 ) ′
5 034 814.5 59.544 117(880) S ∥
- 16
7
61.9 96(720) M ∥
7
10 R ( 50 ) ″
2 638 540.7
d
113.621 29(220) S ∥ 7
7
2 638 537.7
d
113.621 29(220) S ∥ 7
7
1 635 937.6 183.254 29(220) M ⊥ 7
7
10 R ( 48 )
2 740 883.2 109.378 40(300) M ∥ 10
7
10 R ( 44 )
2 651 522.1 113.064 44(330) S ∥
- 22
7
10 R ( 42 ) ′
3 551 318.2 84.417 43(320) M ∥ 44
7
10 R ( 42 ) ″
3 343 021.8 89.677 33(250) M ∥
- 23
7
10 R ( 40 )
1 485 618.5 201.796 65(490) VS ∥
- 36
7
10 R ( 38 )
1 272 681.1 235.559 25(190) VS ∥
5 , 7
10 R ( 38 )
408 346.7 734.162 3
10 R ( 36 ) ′
2 746 267.9 109.164 25(190) M ∥
- 14
7
10 R ( 36 ) ″
1 868 475.0 160.448 33(250) S ∥ 44
7
960 791.1 312.027 37(280) S ⊥ 44
7
10 R ( 34 ) ′
2 082 274.2 143.974 40(300) VS ⊥ 41
7
10 R ( 34 ) ″
153.4 29(220) VS ∥
7
234.0 ∥
1
10 R ( 34 ) ‴
1 371 660.8 218.562 40(300) VS ∥ 44
7
10 R ( 30 )
1 132 510.3 264.715 33(250) S ∥
- 10
1 , 7
10 R ( 28 )
1 955 291.8 153.324 28(210) S ∥ 42
7
10 SR ( 27 )
1 860 374.8 161.146 37(280) S ∥ 7
7
10 SR ( 23 ) ′
3 275 035.8 91.359 32(240) VS ∥ 26
7
10 SR ( 23 ) ″
2 743 410.5 109.277 25(190) VS ∥
- 28
7
10 SR ( 23 ) ‴
267.4 32(240) M ∥ 47
7
10 R ( 24 )
802.4 ∥
1
10 R ( 20 )
2 092 854.4 143.246 24(180) S ⊥
5
165.0 25(190) ∥ New 1 132 140.6 264.801 27(200) S ∥
1 , 2
10 R ( 18 ) ′
2 790 942.8 107.416 36(270) M ∥
7
10 R ( 18 ) ″
116.7 40(300) M ∥
- 33
7
10 SR ( 21 )
939 054.3 319.249 27(200) VS ∥
7
10 SR ( 17 )
1 610 436.0 186.156 20(150) VS ∥ 19
7
10 HR ( 14 ) ′
1 977 072.4 151.635 13(100) M ∥
- 30
7
10 HR ( 14 ) ″
1 574 927.0 190.353 13(100) M ⊥
- 8
7
10 R ( 12 )
234.12 35(260) ∥ New
10 R ( 12 )
995 077.8 301.275 20(150) S ∥
1 , 2
802 492.8 373.576 ⊥
1 , 5
10 SR ( 11 )
2 381 482.4
d
125.885 13(100) S ∥ 36
7
2 381 478.9
d
125.885 13(100) S ∥ 36
7
1 510 382.3 198.488 11(80) W ∥
7
234.36 13(100) ∥ New
10 SR ( 9 )
1 126 495.9 266.128 20(150) VS ⊥ 0
7
645 737.5 464.264 19(140) VS ∥ 0
7
10 R ( 8 )
1 281 625.8 233.916 13(100) VS ∥
1 , 2
561 773.0
d
533.654 ⊥
1 , 5
561 771.3
d
533.656 ⊥
1 , 5
10 R ( 6 )
2 565 990.1 116.833 5(40) M
6
10 R ( 4 )
5 116 059.9 58.598 108(810) M ∥
7
2 574 085.5 116.466 39(290) VS ∥ 39
7
1 989 217.5 150.709
5
10 P ( 2 )
4 017 213.1 74.627 21(160) M ∥
7
1 811 655.9 165.480 23(170) M ∥
- 11
7
10 P ( 4 ) ′
49.2 24(180) M ∥
- 36
7
3 844 230.0 77.985 23(170) M ∥
- 36
7 , 8
10 P ( 4 ) ″
3 319 710.8 90.307 41(310) S ⊥
7
2 415 908.4 124.090 39(290) M ∥
7
2 098 942.5 142.830 20(150) M ∥
7
10 P ( 4 ) ‴
2 625 546.4 114.183 28(210) S ∥ 42
7
186.1 24(180) W ⊥ 42
7
10 P ( 6 ) ′
2 221 963.2 134.922
5
10 P ( 6 ) ″
2 174 579.3 137.862
5
10 P ( 6 ) ‴
1 647 877.4 181.926 20(150) S ⊥(∥)
2
10 P ( 6 ) ‴
246.5 ∥
1
10 P ( 10 )
1 880 947.4 159.384 5(40) W
6
1 450 431.1 206.692 40(300) M ∥ 37
7
1 907 887.0 157.133 24(180) M ∥
- 43
7
721.0 ∥
1
10 P ( 16 ) ′
3 690 723.1 81.229 20(150) M ⊥
5
2 923 359.0 102.551 53(400) S ∥
5
10 P ( 16 ) ″
650 207.7 461.072 ⊥
1 , 2
10 P ( 18 ) ′
4 668 834.6 64.211 29(220) W ∥
- 43
8
10 P ( 18 ) ″
2 555 898.1 117.294 27(200) W ∥ 26
8
273.0 13(100) W ∥
1
10 P ( 18 ) ″
372.5 ⊥
1
10 P ( 20 )
3 559 814.8 84.216 67(500) M ∥
- 42
8
10 P ( 22 )
3 691 269.2 81.217 20(150) W ∥ 31
8
2 923 138.5 102.558 20(150) W ∥ 31
8
1007.0 ⊥
1
10 P ( 24 ) ′
3 676 638.9 81.540 29(220) M ∥ 40
8
10 P ( 24 ) ″
2 460 606.8 121.837 27(200) M ∥ 13
8
10 P ( 24 ) ‴
1 554 077.8 192.907 15(110) VS ⊥
- 32
1 , 2 , 6
336.0 ⊥
1
687 957.4 435.772 7(50) S ⊥
1 , 2
10 P ( 26 )
3 197 414.3 93.761 29(220) M ∥
- 46
8
10 P ( 28 )
262.0 ⊥
1
10 P ( 30 ) ′
3 442 096.1 87.096 13(100) M ∥
- 36
8
10 P ( 30 ) ″
2 695 149.6 111.234 13(100) M ∥
- 8
7
10 SP ( 29 )
2 432 134.3 123.263 27(200) VS ⊥
- 12
8
1 615 503.5 185.572 20(150) VS ∥
- 12
7
10 P ( 32 )
2 219 596.6 135.066 19(140) W ∥ 0
8
795.0 ⊥
1
10 SP ( 31 )
4 722 332.3 63.484 27(200) M ∥ 1
8
3 559 099.1 84.233 27(200) M ∥ 1
8
10 SP ( 33 )
5 494 676.8 54.561 27(200) M ∥
- 7
8
10 P ( 36 )
3 266 508.2 91.778 21(160) M ∥
- 33
8
10 P ( 40 )
1 241 985.4 241.382 7(50) M
6
568 210.2 527.608 7(50) W
6
10 P ( 42 )
954 857.6
d
313.966
6
954 850.7
d
313.968
6
569 599.7
d
526.321
6
569 589.7
d
526.331
6
10 P ( 44 )
89.5 New
10 P ( 44 )
3 172 777.9 94.489 27(200) S
6
10 P ( 44 )
2 452 677.4 122.231 27(200) VS
6
10 P ( 46 )
3 444 748.6 87.029 33(250) W ⊥ 34
8
10 P ( 52 )
1 860 374.6 161.146 W
6
1 833 951.7 163.468
6
10 HP ( 19 )
93.5 43(320) ∥ New
10 P ( 54 )
2 988 681.8 100.309 28(210) VS ⊥
6 , 8
1 980 809.4 151.348 11(80)
6
10 HP ( 20 )
1 573 986.2 190.467 10(75)
6
10 HP ( 22 )
1 037 179.7 289.046 24(180) M ⊥
8
10 P ( 56 ) – HP ( 23 )
3 896 540.2 76.938 24(180) VS ∥
8
1 556 427.9 192.616 VVS
6
885 606.8 338.516 S
6
10 HP ( 24 )
2 823 688.6 106.171 13(100) M
6
10 HP ( 24 )
1 864 680.0 160.774 10(75) W
6
10 HP ( 25 )
1 708 654.6 175.455 19(140) M ∥
8
10 HP ( 29 )
3 214 438.5 93.264 33(250) S ∥
8
1 858 872.0 161.277 7(50) VS
6
1 040 932.6 288.004 8(60) M ∥ 6 10 HP (32) 1 282 805.7 233.701 8(60) S
6
1 042 133.2 287.672 8(60) S
6
a
′ ,
″ , and
‴ indicate different
12 C 16 O 2 laser frequency offsets from line center.
b
Calculated from
c = 299 792 458 m / s .
c
Abbreviations here and in the tables that follow are defined in text.
d
Doublets.
Table 2
Summary of the Hydrazine FIR Laser Lines Pumped by Isotopic CO 2 Laser
Laser Pump Line Wavelength (μ m) Relative Intensity
a
Ref.
12 C 18 O 2
10 P ( 24 )
705.0 S
10
13 C 16 O 2
10 P ( 18 )
219.0 VS
10
10 P ( 24 )
945.0 S
10
10 P ( 30 )
289.0 VVS
10
13 C 18 O 2
10 R ( 18 )
267.0 M
10
10 P ( 14 )
863.0 M
10
9 P ( 14 )
195.0 VS
10
a
The relative intensity estimations in this table do not correlate with ours; they are being reported according to the references in which they can be found.
Table 3
Summary of the Hydrazine FIR Laser Lines Pumped by an 14 N 2 16 O Laser
12 N 2 16 O Laser Pump Line
a
Frequency (MHz) Wavelength (μ m)
b
Pressure [Pa (mTorr)] Relative Intensity
14 N 2 16 O
Power (W) Ref.
10 R ( 38 )
339.4 19(140)
9
10 R ( 36 )
98.0 35(260) M 3.2
9
10 R ( 25 )
2 823 287.0 106.186 19(140) W 5.0
9
10 R ( 24 )
257.5 15(110) W 4.2
9
10 R ( 11 )
906 899.8 330.568 15(110) W 5.2
10
10 R ( 4 )
1 369 893.3 218.844 9(70) W 2.6
9
10 P ( 7 )
1 371 481.5 218.590 27(200) M 5.0
10
10 P ( 11 )
1 858 872.0 161.277 9(70) W 6.0
9
10 P ( 11 )
575.0
10
10 P ( 15 ) ‴
2 631 380.7 113.930 19(140) W 5.4
9
10 P ( 15 ) ″
1 288 113.7 232.738 7(50) W 5.8
9
10 P ( 15 ) ′
801 069.7 374.240 9(70) W 5.8
10
10 P ( 16 )
2 191 609.6
c
136.791 13(100) M 6.0
9
2 191 613.7
c
136.791 13(100) M 6.0
9
10 P ( 24 )
2 485 511.6 120.616 27(200) M 6.0
9
10 P ( 24 )
237.0
10
10 P ( 26 )
114.2 21(160) M 4.0
9
10 P ( 28 )
492.4 17(130) W 5.0
10
10 P ( 29 )
241.6 16(120) W 6.0
9
10 P ( 30 )
1 902 430.3 157.584 8(60) M 4.0
9
10 P ( 34 )
1 426 180.2 210.207 7(50) M 3.8
9
10 P ( 34 )
1 041 094.2 287.959 13(100) W 4.4
9
10 P ( 32 )
3 222 036.9 93.044 24(180) S 4.0
9
10 P ( 45 )
2 823 544.5 106.176 23(170) M 1.8
9
a
′ ,
″ , and
‴ indicate different
14 N 2 16 O laser frequency offsets from line center.
b
Calculated from
c = 299 792 458 m / s .
c
Doublets.
Table 4
Summary of the Hydrazine FIR Laser Lines Pumped by a 12 C 16 O 2 Laser, Sorted by Increasing Wavelength
12 C 16 O 2 Laser Pump Line
a
Frequency (MHz) Calculated Wavelength (μ m)
b
Calculated Wave Number ( cm - 1 )
Pressure [Pa (mTorr)] Relative Intensity Relative Polarization Offset (MHz) Ref.
10 P ( 4 ) ′
49.2 24(180) M ∥
- 36
7
10 SP ( 33 )
5 494 676.8 54.561 183.2827 27(200) M ∥
- 7
8
10 R ( 4 )
5 116 059.9 58.598 170.6534 108(810) M ∥
7
10 R ( 50 ) ′
5 034 814.5 59.544 167.9433 117(880) S ∥
- 16
7
10 R ( 50 ) ″
61.9 96(720) M ∥
7
10 SP ( 31 )
4 722 332.3 63.484 157.5201 27(200) M ∥ 1
8
10 P ( 18 ) ′
4 668 834.6 64.211 155.7356 29(220) W ∥
- 43
8
9 R ( 50 )
4 553 228.0 65.842 151.8793 53(400) M ∥
- 9
7
9 R ( 52 )
4 463 894.4 67.159 148.8995 53(400) W ∥ 43
8
9 R ( 10 ) ′
4 104 665.7 73.037 136.9169 47(350) W ∥ 43
8
9 P ( 22 )
73.07 New
9 P ( 32 )
4 058 513.9 73.868 135.3775 40(300) S ∥ 28
7
10 P ( 2 )
4 017 213.1 74.627 133.9998 21(160) M ∥
7
9 R ( 12 )
3 975 563.7 75.409 132.6105 60(450) W ∥ 35
8
9 R ( 4 )
3 918 281.0 76.511 130.6998 13(100) M ∥ 40
7
10 P ( 56 ) – HP ( 23 )
3 896 540.2 76.938 129.9746 24(180) VS ∥
8
10 P ( 4 ) ′
3 844 230.0 77.985 128.2297 23(170) M ∥
- 36
7 , 8
9 R ( 8 )
3 696 638.2 81.099 123.3066 33(250) S ∥
- 12
7
10 P ( 22 )
3 691 269.2 81.217 123.1275 20(150) W ∥ 31
8
10 P ( 16 ) ′
3 690 723.1 81.229 123.1093 20(150) M ⊥
5
10 P ( 24 ) ″
3 676 638.9 81.540 122.6395 29(220) M ∥ 40
8
10 P ( 20 )
3 559 814.8 84.216 118.7426 67(500) M ∥
- 42
8
10 SP ( 31 )
3 559 099.1 84.233 118.7188 27(200) M ∥ 1
8
10 R ( 42 ) ′
3 551 318.2 84.417 118.4592 43(320) M ∥ 44
7
9 P ( 16 ) ′
3 536 744.1 84.765 117.9731 20(150) M ∥ 8
7
9 R ( 14 )
3 497 481.1 85.717 116.6634 27(200) S ∥
- 50
7
9 SP ( 11 )
85.9 13(100) S ∥
7
10 P ( 46 )
3 444 748.6 87.029 114.9044 33(250) W ⊥ 34
8
10 P ( 30 ) ′
3 442 096.1 87.096 114.8160 13(100) M ∥
- 36
8
10 P ( 44 )
89.5 New
10 R ( 42 ) ″
3 343 021.8 89.677 111.5112 33(250) M ∥
- 23
7
10 P ( 4 ) ″
3 319 710.8 90.307 110.7336 41(310) S ⊥
7
9 P ( 14 )
3 317 269.0 90.373 110.6522 53(400) VS ∥
- 32
7
9 P ( 16 ) ″
3 304 457.8 90.724 110.2248 20(150) S ∥
- 45
7
10 SR ( 23 ) ′
3 275 035.8 91.359 109.2434 32(240) VS ∥ 26
7
10 P ( 36 )
3 266 508.2 91.778 108.9590 21(160) M ∥
- 33
8
10 HP ( 29 )
3 214 438.5 93.264 107.2221 33(250) S ∥
8
10 HP ( 19 )
93.5 43(320) ∥ New
10 P ( 26 )
3 197 414.3 93.761 106.6543 29(220) M ∥
- 46
8
10 P ( 44 )
3 172 777.9 94.489 105.8325 27(200) S
6
10 P ( 54 )
2 988 681.8 100.309 99.6917 28(210) VS ⊥
6 , 8
9 R ( 36 )
2 950 180.8 101.618 98.4074 27(200) S ∥
- 38
7
9 P ( 36 ) ′
2 946 196.7 101.756 98.2745 20(150) M ∥
6
9 P ( 34 )
102.0 53(400) VS ∥ New
10 P ( 16 ) ′
2 923 359.0 102.551 97.5128 53(400) S ∥
5
10 P ( 22 )
2 923 138.5 102.558 97.5054 20(150) W ∥ 31
8
9 SP ( 13 )
2 884 000.7 103.950 96.1999 53(400) VS ∥
- 12
7
10 HP ( 24 )
2 823 688.6 106.171 94.1881 13(100) M
6
10 R ( 18 ) ′
2 790 942.8 107.416 93.0958 36(270) M ∥
7
10 R ( 36 ) ′
2 746 267.9 109.164 91.6056 25(190) M ∥
- 14
7
10 SR ( 23 ) ″
2 743 410.5 109.277 91.5103 25(190) VS ∥
- 28
7
10 R ( 48 )
2 740 883.2 109.378 91.4260 40(300) M ∥ 10
7
10 R ( 54 ) ′
2 729 129.8 109.849 91.0340 21(160) M ∥
- 19
7
10 P ( 30 ) ″
2 695 149.6 111.234 89.9005 13(100) M ∥
- 8
7
10 R ( 44 )
2 651 522.1 113.064 88.4453 44(330) S ∥
- 22
7
10 R ( 50 ) ″
2 638 537.7
d
113.621 88.0121 29(220) S ∥ 7
7
2 638 540.7
d
113.621 88.0122 29(220) S ∥ 7
7
10 P ( 4 ) ‴
2 625 546.4 114.183 87.5788 28(210) S ∥ 42
7
10 R ( 4 )
2 574 085.5 116.466 85.8623 39(290) VS ∥ 39
7
10 R ( 18 ) ″
116.7 40(300) M ∥
- 33
7
10 R ( 6 )
2 565 990.1 116.833 85.5922 5(40) M
6
10 P ( 18 ) ″
2 555 898.1 117.294 85.2556 27(200) W ∥ 26
8
9 P ( 22 )
2 510 428.7 119.419 83.7389 43(320) W ∥ 39
8
9 P ( 52 )
2 473 562.9 121.199 82.5092 27(200) S ∥
- 45
7
10 P ( 24 ) ″
2 460 606.8 121.837 82.0770 27(200) M ∥ 13
8
10 P ( 44 )
2 452 677.4 122.231 81.8125 27(200) VS
6
10 SP ( 29 )
2 432 134.3 123.263 81.1273 27(200) VS ⊥
- 12
8
10 P ( 4 ) ″
2 415 908.4 124.090 80.5860 39(290) M ∥
7
9 R ( 4 )
125.7 20(150) M ∥
7
10 SR ( 11 )
2 381 482.4
c
125.885 79.4377 13(1000) S ∥ 36
7
2 381 478.9
c
125.885 79.4376 13(100) S ∥ 36
7
10 R ( 54 ) ″
2 340 717.5 128.077 78.0779 33(250) S ∥ 19
7
9 P ( 36 ) ″
2 225 036.9 134.736 74.2192 27(200) W
6
10 P ( 06 ) ′
2 221 963.2 134.922 74.1167
5
10 P ( 32 )
2 219 596.6 135.066 74.0378 19(140) W ∥ 0
8
10 P ( 6 ) ″
2 174 579.3 137.862 72.5362
5
10 R ( 52 )
2 106 238.3 142.335 70.2565 43(320) S ∥ 40
7
9 P ( 50 )
2 104 368.9 142.462 70.1942 20(150) VS ∥ 43
7
10 P ( 4 ) ″
2 098 942.5 142.830 70.0132 20(150) M ∥
7
10 R ( 20 )
2 092 854.4 143.246 69.8101 24(180) S ⊥
5
10 R ( 34 ) ′
2 082 274.2 143.974 69.4572 40(300) VS ⊥ 41
7
10 R ( 4 )
1 989 217.5 150.709 66.3532
5
10 P ( 54 )
1 980 809.4 151.348 66.0727 11(80)
6
10 HR ( 14 ) ′
1 977 072.4 151.635 65.9480 13(100) M ∥
- 30
7
10R(28) 1 955 291.8 153.324 65.2215 28(210) S ∥ 42
7
10 R ( 34 ) ″
153.4 29(220) VS ∥
7
9 R ( 46 )
1 945 888.1 154.065 64.9078 11(80) M ∥
- 2
7
9 P ( 30 )
1 920 424.5 156.107 64.0585 20(150) M ∥ 28
7
10 P ( 12 )
1 907 887.0 157.133 63.6403 24(180) M ∥
- 43
7
10 P ( 10 )
1 880 947.4 159.384 62.7417 5(40) W
6
10 R ( 36 ) ″
1 868 475.0 160.448 62.3256 33(250) S ∥ 44
7
9P(46) 1 866 375.4 160.628 62.2556 27(200) VS ∥
- 7
7
10 HP ( 24 )
1 864 680.0 160.774 62.1990 10(75) W
6
10 SR ( 27 )
1 860 374.8 161.146 62.0554 37(280) S ∥ 7
7
10 P ( 52 )
1 860 374.6 161.146 62.0554 W
6
10 HP ( 29 )
1 858 872.0 161.277 62.0053 7(50) VS
6
10 P ( 52 )
1 833 951.7 163.468 61.1740
6
10 R ( 20 )
165.0 25(190) ∥ New
10 P ( 2 )
1 811 655.9 165.480 60.4303 23(170) M ∥
- 11
7
10 HP ( 25 )
1 708 654.6 175.455 56.9946 19(140) M
8
10 P ( 06 ) ‴
1 647 877.4 181.926 54.9673 20(150) S ⊥
2
9 P ( 56 )
1 644 081.4 182.346 54.8407 20(150) S ∥
- 32
7
10 R ( 50 ) ″
1 635 937.6 183.254 54.5690 29(220) M ⊥ 7
7
9 P ( 36 ) ‴
1 619 248.8 185.143 54.0123 13(100) W
6
10 SP ( 29 )
1 615 503.5 185.572 53.8874 20(150) VS ∥
- 12
7
10 P ( 04 ) ‴
186.1 24(180) W ⊥ 42
7
10 SR ( 17 )
1 610 436.0 186.156 53.7184 20(150) VS ∥ 19
7
10 HR ( 14 ) ″
1 574 927.0 190.353 52.5339 13(100) M ⊥
- 8
7
10 HP ( 20 )
1 573 986.2 190.467 52.5025 10(75)
6
10 P ( 56 ) – HP ( 23 )
1 556 427.9 192.616 51.9168 VVS
6
10 P ( 24 ) ‴
1 554 077.8 192.907 51.8385 15(110) VS ⊥
- 32
1 , 2 , 6
10 SR ( 11 )
1 510 382.3 198.488 50.3809 11(80) W ∥
7
10 R ( 40 )
1 485 618.5 201.796 49.5549 65(490) VS ∥
- 36
7
10 P ( 10 )
1 450 431.1 206.692 48.3812 40(300) M ∥ 37
7
10 R ( 34 ) ‴
1 371 660.8 218.562 45.7537 40(300) VS ∥ 44
7
10 HP ( 32 )
1 282 805.7 233.701 42.7898 8(60) S
6
10 R ( 08 )
1 281 625.8 233.916 42.7504 13(100) VS
1 , 2
10 R ( 34 ) ″
234.0
1
10 R ( 12 )
234.12 35(260) ∥ New
10 SR ( 11 )
234.36 13(100) ∥ New
10 R ( 38 )
1 272 681.1 235.559 42.4521 25(190) VS ∥
5 , 7
10 P ( 40 )
1 241 985.4 241.382 41.4282 7(50) M
6
10 P ( 6 ) ‴
246.5
1
9 R ( 10 ) ″
1 203 541.3 249.092 40.1458 20(150) M ∥
- 20
1 , 7
10 R ( 30 )
1 132 510.3 264.715 37.7765 33(250) S ∥
- 10
1 , 7
10 R ( 20 )
1 132 140.6 264.801 37.7641 27(200) S ∥
1 , 2
10 P ( 28 )
265.0 ⊥
1
10 SR ( 9 )
1 126 495.9 266.128 37.5759 20(150) VS ⊥ 0
7
10 SR ( 23 ) ‴
267.4 32(240) M ∥ 47
7
10 P ( 18 ) ″
273.0 13(100) W ∥
1
9 R ( 34 )
1 055 803.2 283.947 35.2178 13(100) VS ∥
7
10 HP ( 32 )
1 042 133.2 287.672 34.7618 8(60) S
6
10 HP ( 29 )
1 040 932.6 288.004 34.7218 8(60) M ∥
6
10 HP ( 22 )
1 037 179.7 289.046 34.5966 24(180) M ⊥
8
10 R ( 12 )
995 077.8 301.275 33.1922 20(150) S ∥
1 , 2
9 P ( 20 )
963 731.4 311.075 32.1466
1 , 2
10 R ( 36 ) ″
960 791.1 312.027 32.0485 37(280) S ⊥ 44
7
9 P ( 46 )
960 791.1 312.027 32.0485 27(200) VS ∥
- 7
7
10 P ( 42 )
954 857.6
c
313.966 31.8506
6
10 P ( 42 )
954 850.7
c
313.968 31.8504
6
10 SR ( 21 )
939 054.3 319.249 31.3235 27(200) VS ∥
7
9 R ( 26 )
916 511.7 327.102 30.5715 20(150) S ∥
- 13
1 , 7
9 P ( 12 ) ′
904 899.4 331.299 30.1842 20(150) S ∥
2 , 6
9 P ( 30 )
331.5
1
9 P ( 12 ) ″
903 889.6 331.669 30.1505 20(150) S ∥
1 , 2 , 6
10 P ( 24 ) ‴
336.0
1
10 P ( 56 ) – HP ( 23 )
885 606.8 338.516 29.5407 S
6
9 R ( 42 )
858 156.2 349.345 28.6250 20(150) VS ⊥
6 , 7
9 R ( 18 )
812 750.0 368.862 27.1104 27(200) M
3
10 P ( 18 ) ″
372.5
1
10 R ( 12 )
802 492.8 373.576 26.7683
1 , 5
10 P ( 24 ) ‴
687 957.4 435.772 22.9478
1 , 2
9 R ( 46 )
454.7 33(250) M ∥
- 2
7
10 P ( 16 ) ″
650 207.7 461.072 21.6886
1 , 2
10 SR ( 09 )
645 737.5 464.264 21.5395 19(140) VS ∥ 0
7
9 P ( 20 )
483.5
1
9 R ( 48 )
574 117.3 522.180 19.1505 7(50) W
6
10 P ( 42 )
569 599.7
c
526.321 18.9998
6
10 P ( 42 )
569 589.7
c
526.331 18.9995
6
10 P ( 40 )
568 210.2 527.608 18.9535 7(50) W
6
9 P ( 12 ) ‴
567 925.4 527.873 18.9440
2
10 R ( 8 )
561 773.0
c
533.654 18.7387
1 , 5
10 R ( 8 )
561 771.3
c
533.656 18.7387
1 , 5
9 P ( 08 )
708.3 20(150) M ∥
7
10 P ( 12 )
721.0
1
10 R ( 38 )
408 346.7 734.162 13.6210
3
10 P ( 32 )
795.0
1
10 R ( 24 )
802.4
1
10 P ( 22 )
1007.0
1
a
′ ,
″ , and
‴ indicate different
CO 2 laser frequency offsets from line center.
b
Calculated from
c = 299 792 458 m / s .
c
Doublets.
Table 5
Summary of the Hydrazine FIR Laser Lines Pumped by an 14 N 2 16 O Laser, Sorted by Increasing Wavelength
14 N 2 16 O Laser Pump Line
a
Measured Frequency (MHz) Calculated Wavelength (μ m)
b
Calculated Wave Number ( cm - 1 )
Pressure [Pa (mTorr)] Relative Intensity
14 N 2 16 O
Laser Power (W) Ref.
10 P ( 32 )
3 222 036.9 93.044 107.4756 24(180) S 4.0
9
10 R ( 36 )
98.0 35(260) M 3.2
9
10 P ( 45 )
2 823 544.5 106.176 94.1833 23(170) M 1.8
9
10 R ( 25 )
2 823 287.0 106.186 94.1747 19(140) W 5.0
9
10 P ( 15 ) ‴
2 631 380.7 113.930 87.7734 19(140) W 5.4
9
10 P ( 26 )
114.2 21(160) M 4.0
9
10 P ( 24 )
2 485 511.6 120.616 82.9077 27(200) M 6.0
9
10 P ( 16 )
2 191 609.6
d
136.791 73.1042 13(100) M 6.0
9
2 191 613.7
d
136.791 73.1044 13(100) M 6.0
9
10 P ( 30 )
1 902 430.3 157.584 63.4582 8(60) M 4.0
9
10 P ( 11 )
1 858 872.0 161.277 62.0053 9(70) W 6.0
9
10 P ( 34 )
1 426 180.2 210.207 47.5723 7(50) M 3.8
9
10 P ( 7 )
1 371 481.5 218.590 45.7477 27(200) M 5.0
10
10 R ( 4 )
1 369 893.3 218.844 45.6947 9(70) W 2.6
9
10 P ( 15 ) ″
1 288 113.7 232.738 42.9668 7(50) W 5.8
9
10 P ( 24 )
237.0 M
10
10 P ( 29 )
241.6 16(120) W 6.0
9
10 R ( 24 )
257.5 15(110) W 4.2
9
10 P ( 34 )
1 041 094.2 287.959 34.7272 13(100) W 4.4
9
10 R ( 11 )
906 899.8 330.568 30.2509 15(110) W 5.2
10
10 R ( 38 )
339.4 19(140)
9
10 P ( 15 ) ′
801 069.7 374.240 26.7208 9(70) W 5.8
10
10 P ( 28 )
492.4 17(130) W 5.0
10
10 P ( 11 )
575.0 M
10
a
′ ,
″ , and
‴ indicate different
12 N 2 16 O laser frequency offsets from line center.
b
Calculated from
c = 299 792 458 m / s .
c
Doublets.