Lifetime measurements in neutral and singly ionized vanadium

Huailiang Xu; Zhankui Jiang; Hans Lundberg

doi:10.1364/JOSAB.23.002597

Journal of the Optical Society of America B
Vol. 23,
Issue 12,
pp. 2597-2600
(2006)
•https://doi.org/10.1364/JOSAB.23.002597

Lifetime measurements in neutral and singly ionized vanadium

Huailiang Xu, Zhankui Jiang, and Hans Lundberg

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Huailiang Xu, Zhankui Jiang, and Hans Lundberg, "Lifetime measurements in neutral and singly ionized vanadium," J. Opt. Soc. Am. B 23, 2597-2600 (2006)

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Abstract

Radiative lifetimes of ten odd-parity levels of V I belonging to the $3 d^{3} 4 s 4 p$ and $3 d^{4} 4 p$ configurations and of 11 odd-parity levels of V $II$ belonging to the $3 d^{3} 4 p$ configuration are reported. The lifetimes were measured with use of single-step excitation and time-resolved fluorescence spectroscopy. The neutral and singly ionized vanadium atoms were produced in a laser-induced vanadium plasma.

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Configuration	Term	J	Energy $({cm}^{- 1})$	Excitation		Observed λ ${(nm)}_{vac.}$	Lifetime (ns)
Configuration	Term	J	Energy $({cm}^{- 1})$	Origin	λ ${(nm)}_{vac.}$	Observed λ ${(nm)}_{vac.}$	This Work	Previous
V I
$3 d^{3} 4 s 4 p$	$y {}^{4}G^{0}$	2.5	30 635.59	0.0	326.417	326	74 (5)
		3.5	30 694.35	137.38	327.257	327	87 (6)
		4.5	30 771.73	323.46	328.425	328	105 (10)
$3 d^{4} 4 p$	$t {}^{4}D^{0}$	0.5	37 757.30	0.0	264.849	354	5.3 (0.4)
		3.5	38 115.69	323.46	264.604	353	5.6 (0.4)
	$u {}^{4}F^{0}$	1.5	39 266.68	0.0	254.668	424	8.7 (0.6)
		2.5	39 300.56	137.38	255.341	424	9.4 (0.7)
		3.5	39 341.79	323.46	256.289	423	9.5 (0.7)
		4.5	39 391.08	323.46	255.966	423	9.6 (0.7)
$3 d^{3} 4 s 4 p$	$r {}^{4}D^{0}$	0.5	41 928.48	0.0	238.501	309	7.3 (0.5)
V $II$
$3 d^{3} 4 p$	$z {}^{3}G^{0}$	4	39 403.74	208.89	255.135	327	4.7 (0.3)	7.4^a 4.8^b
		5	39 612.96	339.21	254.622	328	4.7 (0.3)	6.9^a 4.7^b
	$y {}^{5}D^{0}$	1	46 690.42	36.05	214.342	301	5.5 (0.4)
		2	47 101.89	36.05	212.468	298	5.0 (0.4)	6.5^a
		3	47 181.21	106.63	212.428	299	4.6 (0.3)	5.5^a
		4	47 420.25	208.89	211.813	297	4.7 (0.3)
	$z {}^{3}P^{0}$	2	46 739.99	106.63	214.438	301	6.0 (0.5)	9.9^a
		1	47 107.99	106.63	212.759	298	5.1 (0.4)
	$z {}^{5}P^{0}$	1	46 754.59	0.0	213.882	302	2.9 (0.3)
		2	46 879.98	36.05	213.474	302	2.7 (0.3)	5.2^a
		3	47 051.86	106.63	213.014	300	2.7 (0.3)

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Journal of the Optical Society of America B