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3s23p2–3s3p3, 3s23p2–3s23p3d, and 3s23p2–3s23p4s transitions in the silicon sequence for elements potassium through titanium

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Abstract

The HXR self-consistent-field method of Cowan [ R. D. Cowan, The Theory of Atomic Structure and Spectra ( U. California Press, Berkeley, Calif., 1981)] including some relativistic effects was used to calculate a detailed set of weighted oscillator strengths for 3s23p2–3s3p3, 3s23p2–3s23p3d, and 3s23p2–3s23p4s transitions of the silicon sequence for the elements potassium through titanium. Ab initio HXR values of Slater parameters were adjusted by means of a least-squares optimization process in order to fit calculated eigenvalues of the Hamiltonian matrix with the experimental energy levels. The predicted location of the 3s3p3S52 level along the sequence is discussed.

© 1986 Optical Society of America

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