Absolute transition probabilities in Ta i and W i

E. A. Den Hartog; D. W. Duquette; J. E. Lawler

doi:10.1364/JOSAB.4.000048

Journal of the Optical Society of America B
Vol. 4,
Issue 1,
pp. 48-63
(1987)
•https://doi.org/10.1364/JOSAB.4.000048

Absolute transition probabilities in Ta i and W i

E. A. Den Hartog, D. W. Duquette, and J. E. Lawler

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E. A. Den Hartog, D. W. Duquette, and J. E. Lawler, "Absolute transition probabilities in Ta i and W i," J. Opt. Soc. Am. B 4, 48-63 (1987)

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Abstract

Branching ratios are reported for 253 spectral lines in Ta i and 309 lines in W i. New radiative lifetime measurements of 39 W i levels are also reported. The branching ratios are combined with the newly measured W i and previously measured Ta i lifetimes to determine accurate absolute transition probabilities. An experimental determination of the strength of possible infrared branches indicates that no significant infrared branches have been omitted.

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Reference Transition	Lower Level (cm⁻¹)	Upper Level (cm⁻¹)	λ_lw in Air (nm)
a	0	25 513	391.85
b	3964	28 134	413.62
c	5621	31 601	384.81
d	6049	30 665	406.14
e	6069	30 665	406.46
f	9253	30 895	461.95

Designation of Upper Level	Upper Level (cm⁻¹)	λ_iu in Air (nm)	Reference Transition	f_lu/f_lw Calculated Using Emission Branching Ratios	f_lu/f_lw Measured Laser-Induced Fluorescence
z⁴D_1/2	18 505	540.25	a	1.05 (10)	1.13 (9)
z²D_3/2	20 772	481.28	a	1.48 (15)	1.41 (13)
z⁴D_5/2	21 168	581.11	b	0.62 (7)	0.70 (4)
z⁴F_3/2	21 855	457.43	a	1.36 (12)	1.30 (11)
z⁴F_5/2	23 363	578.07	e	0.26 (4)	0.32 (5)
z⁶D_3/2	24 739	535.47	e	0.26 (3)	0.30 (2)
y⁴D_1/2	25 513	513.65	d	0.55 (4)	0.55 (5)
y⁴D_3/2	26 364	492.60	e	0.59 (6)	0.60 (6)
z⁶F_7/2	26 586	576.79	f	0.156 (17)	0.160 (15)
z⁴P_3/2	26 590	576.66	f	0.089 (7)	0.100 (8)
J = 7/2	26 960	564.59	f	0.81 (7)	0.88 (5)
z⁶F_9/2	27 733	420.59	b	0.84 (12)	0.76 (7)
J = 11/2	27 783	451.10	c	2.5 (3)	2.7 (2)
y⁴D_5/2	28 134	453.09	e	1.18 (10)	1.11 (13)
J = 3/2	28 689	441.57	d	0.46 (3)	0.46 (3)
J = 5/2	28 862	438.61	e	0.47 (4)	0.49 (7)
J = 9/2	30 021	383.66	b	0.32 (4)	0.28 (3)
z⁶F_11/2	30 361	404.09	c	0.93 (13)	1.02 (10)

Reference Transition	Lower Level (cm⁻¹)	Upper Level (cm⁻¹)	λ_lw in Air (nm)
a	2951	27 890	400.88
b	4830	30 587	388.14

Designation of Upper Level	Upper Level (cm⁻¹)	λ_lu in Air (nm)	Reference Transition	f_lu/f_lw Calculated Using Emission Branching Ratios	f_lu/f_lw Measured Laser-Induced Fluorescence
z⁷D₂	23 965	522.47	b	0.45 (5)	0.48 (2)
z⁷F₄	24 763	501.53	b	0.30 (5)	0.35 (3)
z⁷D₃	26 189	430.21	a	0.196 (12)	0.206 (10)
z⁷P₂	26 230	429.46	a	0.48 (3)	0.47 (3)
J = 2	26 367	426.94	a	0.117 (8)	0.105 (11)
z⁷P₃	27 488	407.44	a	0.51 (4)	0.60 (4)
z⁵F₂	27 662	437.85	b	0.089 (9)	0.095 (5)
z⁷D₄	28 797	386.80	a	0.260 (18)	0.263 (27)
z⁵F₃	29 139	381.75	a	0.136 (9)	0.14 (3)
z⁵D₂	29 196	380.92	a	0.028 (3)	0.022 (3)
z⁵P₂	29 393	407.00	b	0.79 (8)	0.82 (3)

Reference Transition	Lower Level (cm⁻¹)	Upper Level (cm⁻¹)	λ_lw in Air (nm)
a	0	25 513	391.85
b	3964	28 134	413.62
c	5621	31 601	384.81
d	6049	30 665	406.14
e	6069	30 665	406.46
f	9253	30 895	461.95

Upper-Level Energy Lifetime	Transition		Branching Ratio		gA (10⁸ sec⁻¹)
Upper-Level Energy Lifetime	Wave Number (cm⁻¹)	λ in Air (nm)	Ref. 13	This Study	gA (10⁸ sec⁻¹)
5d²6s²(a³F)6p z⁴D_1/2	12435.81	803.91	0.067	0.053 (9)	0.00185 (34)
18504.72 cm⁻¹	12455.30	802.65	0.330	0.189 (29)	0.0066 (11)
572 (29) nsec	18504.72	540.25	0.603	0.758 (37)	0.027 (2)
5d²6s²(a³P)6p z²D_3/2	14703.41	679.93	0.048	0.020 (5)	0.00119 (31)
20772.32 cm⁻¹	18762.22	532.84	0.222	0.158 (7)	0.0092 (8)
685 (55) nsec	20772.32	481.28	0.681	0.822 (9)	0.048 (4)
5d²6s²(a³F)6p z⁴D_5/2	11191.80	893.26		0.052 (2)	0.0034 (3)
21167.61 cm⁻¹	15098.70	662.13	0.244	0.275 (5)	0.0182 (15)
908 (73) nsec	17203.69	581.11	0.357	0.516 (9)	0.034 (3)
	19157.51	521.85	0.286	0.080 (3)	0.0053 (5)
	21167.61	472.29	0.113	0.077 (3)	0.0051 (4)
5d³6s(a⁵F)6p z⁴F_3/2	11879.26	841.57	0.012	0.024 (4)	0.0021 (4)
21855.07 cm⁻¹	12096.10	826.49	0.048	0.061 (61)	0.005 (5)
449 (22) nsec	15786.16	633.29	0.090	0.062 (8)	0.0055 (7)
	15805.65	632.51	0.133	0.151 (17)	0.0135 (16)
	19844.97	503.77	0.124	0.150 (9)	0.0133 (10)
	21855.07	457.43	0.593	0.552 (27)	0.049 (3)
5d³6s(a⁵F)6p z⁴F_5/2	12119.46	824.90	0.023	0.025 (5)	0.0039 (8)
23363.09 cm⁻¹	12412.87	805.39	0.013	0.008 (4)	0.0012 (6)
390 (20) nsec	13387.28	746.78	0.051	0.056 (8)	0.0086 (14)
	13657.71	731.98	0.031	0.030 (5)	0.0046 (8)
	14109.66	708.54	0.031	0.018 (3)	0.0028 (5)
	17294.18	578.07	0.109	0.130 (15)	0.020 (3)
	19399.17	515.34	0.084	0.068 (4)	0.0105 (9)
	21352.99	468.19	0.540	0.595 (26)	0.091 (6)
	23363.09	427.91	0.117	0.070 (4)	0.0108 (9)
5d³6s(a⁵F)6p z⁶D_3/2	13495.40	740.79	0.271	0.341 (6)	0.081 (4)
24739.03 cm⁻¹	13788.81	725.03	0.051	0.056 (2)	0.0131 (8)
170 (9) nsec	14763.22	677.17	0.110	0.095 (3)	0.023 (1)
	14980.06	667.37	0.151	0.155 (4)	0.036 (2)
	15485.60	645.58	0.029	0.025 (1)	0.0058 (4)
	18670.12	535.47	0.076	0.111 (5)	0.026 (2)
	18689.61	534.91	0.060	0.071 (3)	0.0168 (11)
	22728.93	439.85	0.151	0.078 (3)	0.0182 (12)
	24739.03	404.11	0.100	0.068 (3)	0.0160 (11)
5d³6s(a⁵F)6p y⁴D_1/2	13720.50	728.64	0.031	0.010 (3)	0.00179 (49)
25512.63 cm⁻¹	14562.41	686.51	0.049	0.016 (4)	0.0029 (7)
112 (6) nsec	15536.82	643.46		0.014 (3)	0.0026 (6)
	15753.66	634.60	0.095	0.042 (7)	0.0075 (13)
	19443.72	514.16	0.238	0.137 (4)	0.024 (1)
	19463.21	513.65	0.077	0.504 (12)	0.090 (5)
	25512.63	391.85	0.510	0.276 (12)	0.049 (3)
5d³6s(a⁵F)6p y⁴D_3/2	15120.06	661.20	0.208	0.240 (25)	0.075 (9)
26363.69 cm⁻¹	15413.47	648.61		0.016 (3)	0.0050 (9)
128 (6) nsec	16604.72	602.07	0.162	0.131 (13)	0.041 (4)
	17110.26	584.28		0.007 (2)	0.0022 (5)
	20294.78	492.60	0.154	0.195 (14)	0.061 (5)
	20314.27	492.13	0.138	0.150 (11)	0.047 (4)
	24353.59	410.50	0.185	0.144 (10)	0.045 (4)
	26363.69	379.21	0.154	0.116 (10)	0.036 (4)
5d³6s(a⁵F)6p z⁶F_1/2	14351.17	696.61	0.305	0.317 (17)	0.097 (7)
26585.93 cm⁻¹	15342.30	651.61	0.166	0.326 (14)	0.100 (7)
261 (13) nsec	15895.61	628.93	0.060	0.048 (3)	0.0147 (12)
	16880.55	592.23		0.005 (1)	0.00153 (38)
	17332.50	576.79	0.045	0.067 (4)	0.021 (2)
	22622.01	441.93		0.019 (3)	0.0058 (10)
	24575.83	406.79	0.424	0.218 (26)	0.067 (9)
5d²6s²(a³P)6p z⁴P_3/2	14797.90	675.59	0.032	0.024 (2)	0.0055 (6)
26590.03 cm⁻¹	15346.40	651.44	0.247	0.377 (16)	0.086 (6)
176 (9) nsec	15639.81	639.22	0.054	0.037 (3)	0.0084 (7)
	16831.06	593.98	0.276	0.280 (12)	0.064 (4)
	17336.60	576.66	0.054	0.053 (3)	0.0120 (9)
	20521.12	487.17	0.041	0.041 (6)	0.0093 (14)
	n 20540.61	486.71		0.006 (2)	0.00136 (39)
	24579.93	406.72	0.207	0.117 (15)	0.027 (4)
	26590.03	375.98	0.088	0.065 (9)	0.0148 (22)
5d³6s(a⁵F)6p z⁶D_5/2	14560.00	686.62	0.250	0.292 (13)	0.155 (10)
26794.76 cm⁻¹	15551.13	642.86	0.068	0.068 (3)	0.036 (2)
113 (6) nsec	15844.54	630.96	0.161	0.207 (7)	0.110 (7)
	16818.95	594.40	0.241	0.241 (8)	0.128 (8)
	17089.38	585.00		0.020 (2)	0.0108 (10)
	17541.33	569.92	0.036	0.046 (3)	0.025 (2)
	22830.84	437.88	0.102	0.054 (8)	0.029 (5)
	24784.66	403.36	0.016	0.010 (2)	0.0053 (12)
	26794.76	373.10	0.127	0.061 (10)	0.032 (5)
Unassigned J = 7/2	14094.49	709.30	0.048	0.036 (5)	0.0101 (15)
26960.46 cm⁻¹	14725.70	678.90	0.079	0.061 (4)	0.0171 (14)
285 (14) nsec	15716.83	636.08	0.123	0.133 (5)	0.037 (2)
	16270.14	614.46	0.115	0.069 (3)	0.0194 (12)
	17707.03	564.59	0.260	0.405 (20)	0.114 (8)
	21339.42	468.49	0.071	0.078 (7)	0.022 (2)
	24950.36	400.68	0.303	0.218 (17)	0.061 (6)
5d³6s(a⁵F)6p z⁶F_9/2	14381.98	695.13	0.117	0.098 (7)	0.037 (3)
27733.43 cm⁻¹	15498.67	645.04	0.345	0.575 (25)	0.22 (1)
265 (13) nsec	17043.11	586.59		0.019 (2)	0.0072 (8)
	n 18028.05	554.54		<0.010 (10)	<0.004 (4)
	22112.39	452.11	0.091	0.062 (7)	0.023 (3)
	23769.51	420.59	0.447	0.236 (26)	0.089 (11)
5d³6s(a⁵F)6p z⁶D_1/2	12389.61	806.90	0.024	0.024 (4)	0.0161 (25)
27780.62 cm⁻¹	14429.17	692.85	0.194	0.203 (10)	0.135 (9)
120 (6) nsec	14914.65	670.30		0.008 (1)	0.0054 (9)
	15545.86	643.08	0.328	0.341 (8)	0.23 (1)
	16536.99	604.54	0.305	0.308 (8)	0.21 (1)
	17090.30	584.97	0.015	0.033 (2)	0.022 (2)
	n 18075.24	553.09		0.007 (1)	0.0047 (9)
	18527.19	539.60	0.042	0.030 (5)	0.020 (4)
	22159.58	451.15	0.091	0.043 (7)	0.029 (5)
	n 25770.52	387.93		0.002 (1)	0.0013 (9)
Unassigned J = 11/2	14431.55	692.74	0.317	0.383 (37)	0.121 (13)
27783.00 cm⁻¹	17092.68	584.89		0.025 (3)	0.0079 (11)
379 (19) nsec	22161.96	451.10	0.683	0.592 (39)	0.187 (15)
5d³6s(a⁵F)6p y⁴D_5/2	15899.12	628.79	0.061	0.047 (6)	0.0180 (24)
28133.88 cm⁻¹	18158.07	550.57	0.028	0.029 (4)	0.0113 (16)
157 (8) nsec	18880.45	529.50	0.117	0.120 (6)	0.045 (3)
	22064.97	453.09	0.291	0.382 (13)	0.145 (9)
	24169.96	413.62	0.317	0.288 (10)	0.109 (7)
	26123.78	382.69	0.108	0.080 (11)	0.031 (5)
	28133.88	355.34	0.078	0.053 (4)	0.020 (2)
Unassigned J = 3/2	16897.18	591.65	0.081	0.068 (10)	0.0197 (31)
28689.31 cm⁻¹	17445.68	573.05		0.013 (3)	0.0038 (8)
138 (7) nsec	17739.09	563.57	0.048	0.050 (7)	0.0145 (23)
	18713.50	534.22	0.057	0.066 (4)	0.0191 (15)
	18930.34	528.10	0.040	0.041 (3)	0.0119 (10)
	19435.88	514.37	0.217	0.231 (9)	0.067 (4)
	22620.40	441.96	0.118	0.068 (3)	0.0197 (13)
	22639.89	441.57	0.328	0.347 (10)	0.101 (6)
	28689.31	348.46	0.112	0.116 (8)	0.034 (3)
5d³6s(a⁵F)6p z⁶D_9/2	13652.51	732.27	0.026	0.018 (2)	0.0130 (17)
28766.65 cm⁻¹	15415.20	648.54	0.755	0.807 (9)	0.58 (3)
138 (7) nsec	16531.89	604.73	0.191	0.124 (4)	0.090 (5)
	19061.27	524.48	0.029	0.012 (3)	0.0087 (21)
	n 23145.61	431.93		0.007 (2)	0.0051 (15)
	24802.73	403.07		0.032 (6)	0.023 (4)
Unassigned J = 5/2	15996.04	624.98	0.088	0.063 (10)	0.021 (3)
28862.01 cm⁻¹	16627.25	601.26		0.014 (3)	0.0047 (10)
180 (9) nsec	17911.79	558.14		0.010 (2)	0.0034 (8)
	18886.20	529.34		0.021 (2)	0.0070 (8)
	19156.63	521.87		0.146 (9)	0.049 (4)
	19608.58	509.84		0.020 (2)	0.0067 (7)
	22793.10	438.61	0.325	0.185 (9)	0.062 (4)
	24898.09	401.53		0.039 (3)	0.0130 (11)
	26851.91	372.31	0.088	0.030 (3)	0.0101 (10)
	28862.01	346.38	0.500	0.472 (21)	0.157 (10)
Unassigned J = 5/2	18393.24	543.53	0.082	0.104 (16)	0.064 (10)
29343.46 cm⁻¹	19367.65	516.18	0.093	0.062 (5)	0.038 (4)
97.5 (4.9) nsec	19638.08	509.07	0.108	0.093 (7)	0.057 (5)
	20090.03	497.62	0.029	0.024 (3)	0.0151 (18)
	27333.36	365.75	0.076	0.042 (4)	0.026 (3)
	29343.46	340.69	0.612	0.674 (22)	0.41 (2)
Unassigned J = 7/2	16371.50	610.65		0.006 (2)	0.0037 (12)
29722.95 cm⁻¹	16856.98	593.06	0.014	0.014 (3)	0.0087 (18)
129 (6) nsec	17488.19	571.65	0.007	0.013 (3)	0.0081 (18)
	n 20017.57	499.42		0.004 (1)	0.0025 (8)
	20469.52	488.40	0.067	0.143 (7)	0.089 (6)
	24101.91	414.79	0.189	0.230 (10)	0.143 (9)
	27712.85	360.74	0.723	0.590 (19)	0.37 (2)
Unassigned J = 9/2	14630.19	683.33		0.013 (2)	0.0055 (8)
30021.20 cm⁻¹	14907.06	670.65	0.049	0.031 (3)	0.0130 (14)
238 (12) nsec	16669.75	599.72	0.534	0.575 (21)	0.24 (1)
	17786.44	562.07	0.102	0.142 (7)	0.060 (4)
	19330.88	517.16	0.049	0.042 (6)	0.0176 (27)
	20315.82	492.09		0.050 (7)	0.021 (3)
	24400.16	409.72	0.102	0.051 (16)	0.021 (7)
	26057.28	383.66	0.165	0.096 (12)	0.040 (5)
5d³6s(a⁵F)6p z⁶F_11/2	17009.77	587.74	0.625	0.720 (31)	0.28 (2)
30361.22 cm⁻¹	19670.90	508.23	0.075	0.057 (7)	0.023 (3)
304 (15) nsec	24740.18	404.09	0.300	0.223 (25)	0.088 (11)
Unassigned J = 7/2	13207.83	756.92	0.013	0.010 (3)	0.0058 (16)
30590.95 cm⁻¹	15199.94	657.71		0.015 (3)	0.0086 (18)
139 (7) nsec	17724.98	564.02	0.057	0.068 (10)	0.039 (6)
	18356.19	544.62		0.014 (3)	0.0084 (18)
	20885.57	478.66	0.032	0.033 (3)	0.0188 (18)
	21337.52	468.53	0.054	0.048 (4)	0.027 (2)
	24969.91	400.37	0.093	0.044 (3)	0.025 (2)
	26627.03	375.45	0.163	0.091 (6)	0.052 (4)
	28580.85	349.79	0.589	0.676 (21)	0.39 (2)
5d³6s(a⁵P)6p y⁶D_3/2	19421.03	514.76	0.075	0.052 (3)	0.036 (3)
30664.66 cm⁻¹	20688.85	483.22	0.059	0.099 (5)	0.068 (5)
57.9 (2.9) nsec	20905.69	478.21		0.009 (1)	0.0062 (10)
	21411.23	466.91	0.138	0.165 (6)	0.114 (7)
	24595.75	406.46	0.213	0.222 (5)	0.153 (9)
	24615.24	406.14	0.443	0.378 (8)	0.26 (1)
	28654.56	348.88		0.042 (4)	0.029 (3)
	30664.66	326.02	0.072	0.033 (5)	0.023 (3)
5d³6s(a⁵P)6p z⁴S_3/2	18028.70	554.52	0.016	<0.018 (18)	<0.010 (10)
30894.67 cm⁻¹	19102.54	523.34		0.021 (2)	0.0111 (11)
75.4 (3.8) nsec	19651.04	508.74	0.094	0.114 (4)	0.060 (4)
	19944.45	501.25	0.110	0.141 (4)	0.075 (4)
	n 20918.86	477.91		0.020 (1)	0.0106 (9)
	21641.24	461.95	0.482	0.396 (8)	0.21 (1)
	24825.76	402.69	0.298	0.272 (8)	0.144 (8)
	30894.67	323.59		0.018 (3)	0.0095 (15)
5d³6s(a⁵P)6p z⁶P_3/2	19822.71	504.33	0.111	0.147 (5)	0.109 (7)
31066.34 cm⁻¹	20116.12	496.97	0.055	0.053 (3)	0.040 (3)
54.0 (2.7) nsec	21090.53	474.02	0.207	0.273 (6)	0.20 (1)
	21307.37	469.19	0.179	0.220 (5)	0.163 (9)
	21812.91	458.32	0.028	0.021 (1)	0.0157 (14)
	24997.43	399.93	0.139	0.099 (5)	0.073 (5)
	25016.92	399.62	0.282	0.181 (8)	0.134 (9)
	n 29056.24	344.07		0.005 (1)	0.0037 (11)
Unassigned J = 9/2	18178.57	549.94	0.043	0.074 (11)	0.061 (10)
31530.02 cm⁻¹	21824.64	458.07	0.027	0.025 (2)	0.021 (2)
122 (6) nsec	25908.98	385.86		0.031 (3)	0.025 (3)
	27566.10	362.66	0.930	0.870 (12)	0.71 (4)
Unassigned J = 3/2	18687.92	534.96	0.191	0.209 (9)	0.086 (6)
31553.89 cm⁻¹	n 19761.76	505.89		0.007 (1)	0.0029 (5)
97.1 (4.9) nsec	20603.67	485.22	0.130	0.160 (6)	0.066 (4)
	21578.08	463.31	0.167	0.119 (4)	0.049 (3)
	n 22300.46	448.30		0.010 (1)	0.0042 (6)
	25484.98	392.28	0.512	0.385 (11)	0.159 (9)
	29543.79	338.39		0.052 (5)	0.021 (2)
	n 31553.89	316.83		0.058 (7)	0.024 (3)
Unassigned J = 111	14217.83	703.15	0.028	0.023 (4)	0.0173 (29)
31600.95 cm⁻¹	14376.48	695.39	0.097	0.087 (11)	0.066 (9)
106 (5) nsec	16209.94	616.73		0.007 (2)	0.0053 (13)
	n 18249.50	547.81		0.007 (2)	0.0053 (15)
	18734.98	533.61	0.053	0.058 (3)	0.044 (3)
	n 20357.32	491.09		0.009 (3)	0.0068 (23)
	20910.63	478.09	0.152	0.229 (5)	0.173 (10)
	21895.57	456.59	0.325	0.269 (6)	0.20 (1)
	22347.52	447.35	0.176	0.144 (4)	0.109 (6)
	25979.91	384.81	0.168	0.138 (5)	0.104 (7)
	27637.03	361.73		0.022 (2)	0.0166 (18)
	29590.85	337.85		0.008 (2)	0.0060 (12)
5d³6s(a⁵P)6p z⁶P_5/2	19095.45	523.54	0.054	0.038 (2)	0.028 (2)
31961.42 cm⁻¹	19726.66	506.79	0.171	0.238 (8)	0.175 (10)
81.7 (4.1) nsec	20717.79	482.54	0.163	0.214 (7)	0.158 (9)
	21011.20	475.80	0.079	0.061 (3)	0.045 (3)
	21985.61	454.72	0.058	0.044 (2)	0.032 (2)
	n 22256.04	449.19		0.020 (3)	0.0146 (23)
	22707.99	440.25	0.349	0.186 (5)	0.137 (8)
	25892.51	386.11		0.024 (2)	0.0176 (17)
	27997.50	357.08		0.020 (2)	0.0146 (20)
	29951.32	333.78	0.126	0.108 (10)	0.079 (8)
	n 31961.42	312.79		0.047 (8)	0.034 (6)
5d³6s(a⁵P)6p y⁶D_5/2	19620.78	509.53	0.056	0.030 (2)	0.030 (2)
32486.75 cm⁻¹	20251.99	493.64	0.222	0.269 (9)	0.27 (2)
60.5 (3.0) nsec	21243.12	470.61	0.105	0.085 (3)	0.084 (5)
	22510.94	444.10	0.099	0.045 (2)	0.045 (3)
	23233.32	430.30	0.267	0.126 (5)	0.125 (8)
	26417.84	378.43	0.028	0.266 (10)	0.26 (2)
	28522.83	350.50	0.222	0.164 (9)	0.163 (12)
	30476.65	328.03		0.015 (3)	0.0149 (26)
Unassigned J = 11/2	17679.27	565.48		0.008 (2)	0.0054 (13)
33070.28 cm⁻¹	n 17956.14	556.76		0.006 (2)	0.0040 (11)
175 (9) nsec	19718.83	506.99		0.030 (3)	0.020 (2)
	27449.24	364.21	1.000	0.957 (7)	0.66 (3)
5d³6s(a⁵P)6p z⁶P_7/2	15973.28	625.87		0.021 (4)	0.026 (6)
33197.75 cm⁻¹	19846.30	503.74	0.239	0.280 (9)	0.35 (2)
63.4 (3.2) nsec	n 20331.78	491.71		0.015 (1)	0.0189 (21)
	20962.99	476.90	0.153	0.175 (5)	0.22 (1)
	21954.12	455.37	0.067	0.060 (3)	0.076 (5)
	22507.43	444.17	0.105	0.057 (2)	0.072 (5)
	23944.32	417.52	0.267	0.171 (6)	0.22 (1)
	27576.71	362.52	0.074	0.065 (4)	0.082 (7)
	29233.83	341.97	0.095	0.121 (9)	0.153 (14)
	31187.65	320.55		0.036 (8)	0.045 (10)
Unassigned J = 9/2	14344.32	696.95		0.016 (4)	0.029 (7)
35497.65 cm⁻¹	18114.53	551.89	1.000	0.208 (31)	0.38 (6)
54.3 (2.7) nsec	20106.40	497.21		0.039 (20)	0.07 (4)
	20383.51	490.46		0.106 (11)	0.195 (23)
	n 22146.20	451.42		0.017 (3)	0.031 (5)
	24807.33	402.99		0.149 (16)	0.28 (3)
	31533.73	317.03		0.465 (43)	0.85 (9)

Abstract

Cited By

Figures (4)

Tables (6)

Equations (2)

Journal of the Optical Society of America B