Additions and revisions to the levels of magnesiumlike Cu xviii and Zn xix

Jack Sugar; Victor Kaufman

doi:10.1364/JOSAB.4.002010

Journal of the Optical Society of America B
Vol. 4,
Issue 12,
pp. 2010-2011
(1987)
•https://doi.org/10.1364/JOSAB.4.002010

Additions and revisions to the levels of magnesiumlike Cu xviii and Zn xix

Jack Sugar and Victor Kaufman

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Jack Sugar and Victor Kaufman, "Additions and revisions to the levels of magnesiumlike Cu xviii and Zn xix," J. Opt. Soc. Am. B 4, 2010-2011 (1987)

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Abstract

Energy-level values are given for the 3p^{2 1}S₀ and 3p3d¹F₃ and ¹P₁ states of Cu xviii and Zn xix. Corrections to the published wavelengths for these spectra found from new observations are reported.

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	Cu xviii		Zn xix

Transition	λ(Å)	Intensity	λ(Å)	Intensity
3p^{2 1}D₂–3p3d¹F₃	165.349	10	156.239	100
3p^{2 3}P₂–3p3d¹F₃	175.785	5	167.194	2
3p^{2 1}S₀–3p3d¹P₁	202.086	30	191.782	50
3s3d¹D₂–3p3d¹P₁	261.820	3	246.145	2
3s3p¹P₁–3p^{2 1}S₀	265.145	10	248.797	2
3s3d¹D₂–3p3d¹F₃	272.120	30	225.754	100

		Level (cm⁻¹)

Designation	J	Cu xviii	Zn xix
3s^{2 1}S	0	0	0
3s3p³P	0	279 808	295 209
	1	289 388	306 319
	2	314 751	336 648
3s3p¹P	1	426 987	453 371
3p^{2 3}P	0	664 964	702 238
	1	684 681	726 463
	2	715 618	763 322
³p^{2 1}D	2	679 714	721 444
3p^{2 1}S	0	804 139	855 305
3s3d³D	1	818 619	866 698
	2	820 693	869 234
	3	823 970	873 293
3s3d¹D	2	917 010	970 488
3p3d³F	2	1118 018	1183 363
	3	1 135 5&1	1 204 050
	4	1 156 841	1 229 359
3p3d¹D	2	1 149 332	1 218 642
3p3d³D	1	1 183 239	1 251 892
	2	1 187 903	1 258 915
	3	1 205 535	1 278 893
3p3d³P	0	1 208 022	1 281 812
	1	1 208 323	1 282 177
	2	1 209 102	1 283 200
3p3d¹F	3	1 284 495	1 361 489
3p3d¹P	1	1 298 965	1 376 741

	Cu xviii	Fitted/HF^a	Zn xix	Fitted/HF^a
3s3p
E_av	341 960(170)	1.017	363 360(100)	1.019
G¹(sp)	214 000(600)	0.975	223 590(400)	0.976
ζ₃_p	23 420(170)	1.072	27 770(100)	1.072
3p²
E_av	713 030(200)	0.994	758 020(300)	0.996
F²(pp)	139 200(1700)	0.810	147 900(2400)	0.822
ζ₃_p	23 287(10)	1.067	27 613(17)	1.067
3s3d
E_av	835 020(100)	0.999	884 320(170)	1.001
G²(sd)	131 900(1100)	0.925	136 700(1600)	0.924
ζ₃_d	2 142(8)	0.878	2 640(14)	0.887
3p3d
E_av	1188 200(70)	0.999	1 260 130(50)	1.000
F²(pd)	150 950(800)	0.878	159 790(600)	0.887
G¹(pd)	171 550(300)	0.910	179 380(200)	0.914
G³(pd)	101 770(900)	0.814	107 470(700)	0.823
ζ₃_p	23 280(200)	1.069	27 390(160)	1.061
ζ₃_d	2 310(120)	0.950	2 810(100)	0.948
3s²–3p²
R¹(ss, pp)	194 700(6000)	0.879	198 200(9700)	0.856
R¹(pp, sd)	171 800(700)	0.867	180 500(1000)	0.875
3s3p–3p3d
R¹(sp, pd)	208 200^b		216 000^b
R¹(sp, dp)	157 400(1200)	1.048	163 100(900)	1.031

	Cu xviii		Zn xix

Transition	λ(Å)	Intensity	λ(Å)	Intensity
3p^{2 1}D₂–3p3d¹F₃	165.349	10	156.239	100
3p^{2 3}P₂–3p3d¹F₃	175.785	5	167.194	2
3p^{2 1}S₀–3p3d¹P₁	202.086	30	191.782	50
3s3d¹D₂–3p3d¹P₁	261.820	3	246.145	2
3s3p¹P₁–3p^{2 1}S₀	265.145	10	248.797	2
3s3d¹D₂–3p3d¹F₃	272.120	30	225.754	100

		Level (cm⁻¹)

Designation	J	Cu xviii	Zn xix
3s^{2 1}S	0	0	0
3s3p³P	0	279 808	295 209
	1	289 388	306 319
	2	314 751	336 648
3s3p¹P	1	426 987	453 371
3p^{2 3}P	0	664 964	702 238
	1	684 681	726 463
	2	715 618	763 322
³p^{2 1}D	2	679 714	721 444
3p^{2 1}S	0	804 139	855 305
3s3d³D	1	818 619	866 698
	2	820 693	869 234
	3	823 970	873 293
3s3d¹D	2	917 010	970 488
3p3d³F	2	1118 018	1183 363
	3	1 135 5&1	1 204 050
	4	1 156 841	1 229 359
3p3d¹D	2	1 149 332	1 218 642
3p3d³D	1	1 183 239	1 251 892
	2	1 187 903	1 258 915
	3	1 205 535	1 278 893
3p3d³P	0	1 208 022	1 281 812
	1	1 208 323	1 282 177
	2	1 209 102	1 283 200
3p3d¹F	3	1 284 495	1 361 489
3p3d¹P	1	1 298 965	1 376 741

Abstract

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Tables (3)

Journal of the Optical Society of America B