Laser bandwidth effects in resonance ionization spectroscopy of Nd

Gene A. Capelle; J. P. Young; D. L. Donohue; D. H. Smith

doi:10.1364/JOSAB.4.000445

Journal of the Optical Society of America B
Vol. 4,
Issue 4,
pp. 445-451
(1987)
•https://doi.org/10.1364/JOSAB.4.000445

Laser bandwidth effects in resonance ionization spectroscopy of Nd

Gene A. Capelle, J. P. Young, D. L. Donohue, and D. H. Smith

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Gene A. Capelle, J. P. Young, D. L. Donohue, and D. H. Smith, "Laser bandwidth effects in resonance ionization spectroscopy of Nd," J. Opt. Soc. Am. B 4, 445-451 (1987)

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Abstract

The resonance ionization spectrometry (RIS) signal from Nd was recorded between 5800 and 6000 Å using four different dye-laser line widths, ranging from 4–6 to <0.1 Å FWHM; a two-color experiment was also carried out. The RIS spectra obtained were analyzed to identify as many Nd transitions as possible. It was found that the number of processes available for Nd in a three-photon ionization process is a function of the line width of the laser.

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RIS Wavelength (Å) and Intensitya			Energy (cm⁻¹)

1–2-Å Bandwidth	0.4–0.7-Å Bandwidth	<0.1-Å Bandwidth	Experimental	Assigned	Transition
		5800.3 w
		5801.8 w
		5803.1 w
		5806.2 w
		5810.5 w
		5811.5 w
	5813.5 w	5812.6 m	17199	17200	${{}^{5}L}_{6}^{\circ} - {{}^{7}L}_{6}$
	5815 w	5813.7 m	17196
		5817.8 w
5821 w	5820 w	5819.6 m	17178	17176	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
		5824.3 w			–
		5825.8 w			–
5827 m	5827 s	5826.8 w	17157	17158	${{}^{5}I}_{7} - {()}_{6}^{\circ}$
		5820.0 m	17150
	5828.5 m	5828.5 m	17152
	5833 w	5832.4 w	17141
		5834.7 w
	5836.5 w	5836.7 s	17128	17127	${{}^{5}L}_{7}^{\circ} - {()}_{8}$
	5838.5	5838.6 s	17122	17122	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
	5839.5				${{}^{5}I}_{5} - {()}_{5}^{\circ}$
5840 m	5840.5	5840.2 s	17118	17121	${{}^{5}I}_{5} - {()}_{6}^{\circ}$
	5843.5 w	5843.5 m	17108	17110	⁵K₅–⁷L₆
		5844.4 w
		5851.8 m	17084
	5852.5 w	5852.5 w	17082	17084	${{}^{7}L}_{7} - {{}^{5}L}_{7}^{\circ}$
5859 m	5859.5 w	5858.9 s	17063	17062	${{}^{5}I}_{6} - {()}_{6}^{\circ}$
		5860.5 m	17058	17056	${{}^{7}L}_{8} - {()}_{7}^{\circ}$
5863 m	5863.5 m	5862.3 m	17053	17052	${{}^{5}K}_{7}^{\circ} - {()}_{6}$
		5868.7 s	17035
5869 s	5869.5 s	5869.2 s	17033	17032	${{}^{5}I}_{4} - {()}_{4}^{\circ}$
		5869.8 s	17031	17032	${{}^{5}F}_{2} - {()}_{3}^{\circ}$
	5874 w	5873.5 m	17021	17020	${{}^{7}M}_{8}^{\circ} - {()}_{7}$
5874 w	5875 m	5874.5 s	17018	17021	${{}^{5}I}_{7} - {()}_{6}^{\circ}$
5877 m	5877 m	5876.8 s	17011	17011	${{}^{5}L}_{6} - L_{7}^{\circ}$
	5878.5 m	5877.8 m	17008	17005	${{}^{5}I}_{5} - {{}^{3}G}_{5}^{\circ}$
	–	5879.4 w
	5880 w	5880.9 s	16999	17001	${{}^{7}L}_{5} - {()}_{4}^{\circ}$
5882 s	5882 s	5881.5 s	16997	16993	${{}^{5}I}_{8} - {()}_{7}^{\circ}$
5889 s	5889.5 s	5889.1 s	16976	16979	${{}^{5}I}_{4} - {()}_{3}^{\circ}$
	5891 m	5890.6 s	16971	16973	${{}^{7}L}_{5} - {()}_{4}^{\circ}$
	–	5900.6 m	16942		${{}^{5}I}_{5} - {()}_{5}^{\circ}$
5901 m	5901.5 m	5901.5 s	16940	16940	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
	5909.5 w	5909.3 m	16917	16915	${{}^{5}I}_{6} - {()}_{6}^{\circ}$
	–	5911.4 m	16911	16914	${{}^{7}L}_{6} - {()}_{5}^{\circ}$
	–	5913.7 m	16905	16905	${{}^{5}I}_{6} - {{}^{7}G}_{7}^{\circ}$
5914 m	5914 w	5914.2 w	16903	16902	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
5920 w	5920.5 w	5919.9 s	16887	16885	${{}^{7}L}_{8} - {{}^{7}L}_{7}^{\circ}$
		5922.2 m	16881	16879	${{}^{7}L}_{5} - {()}_{6}^{\circ}$
		5926.5 s	16868	16869	${{}^{7}K}_{4} - {()}_{4}^{\circ}$
		5928.1 w
		5933.6 s	16848	16848	${{}^{7}K}_{4} - {()}_{4}^{\circ}$
		5934.4 w
5933.5 m	5935 w	5935.5 s	16843	16845	${{}^{5}I}_{4} - {()}_{5}^{\circ}$
		5940.7 m	16828	16826	${{}^{7}L}_{5} - {()}_{6}^{\circ}$
		5944.7 w
		5945.6 w
		5946.5 w
		5963.6 m	16763
	5968.5 w	5968.0 s	16751	16751	${{}^{5}I}_{7} - {()}_{6}^{\circ}$
	5970 w	5969.5 s	16747	16749	${{}^{7}L}_{6} - {{}^{7}L}_{5}^{\circ}$
		5973 w
	5982 w	5989 w
		5992.6 w
		5993.9 w
	5996 w	5995.7 m	16674	16672	${{}^{7}L}_{7} - {{}^{7}L}_{7}^{\circ}$
		5997.0 w
5999 w	5999.5 w	5999.1 w	16664	16663	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
		6000.6 w	16660	16662	${{}^{5}I}_{5} - {()}_{4}^{\circ}$

RIS Wavelength (Å)

Measured Values		Predicted	Transition(cm⁻¹)

<0.1 Å	0.4–0.7-Å
5965.5	5965.8	5965.9	0–16 757
5934.3	5934.7	5934.8	0–16 845
5887.3	5887.7	5887.8	0–16 979
5869.4	5869.7	5869.5	0–17 032
5824.2	5824.2	5824.8	0–17 163
5878.3	5878.3	5878.8	1128–18 133
5999.5	5999.4	5999.9	1128–17 790
5999.2		5999.7	1128–17 791
5914.2	5914.4	5914.8	1128–18 030
5900.7	5901.2	5901.5	1128–18 068
5865.2	5865.3	5865.5	1128–18 172
	5839.2	5839.0	1128–18 249
5838.7	5838.7	5838.7	1128–18 250
5820.3	5819.7	5820.3	1128–18 304
		5955.8	2367–19 152
		5929.5	2367–19 226
		5913.8	2367–19 271
		5910.4	2367–19 281
5859.3	5858.9	5859.3	2367–19 428
		5883.6	3682–20 673
		5968.2	3682–20 432
		5914.6	3682–20 584
		5873.2	3682–20 703
5826.3		5826.7	3682–20 839
		5800.0	3682–20 918
5829.3	5829
5868.7
5889.1
5889.7
5920.5	5921.0

RIS Wavelength (Å) and Intensitya			Energy (cm⁻¹)

1–2-Å Bandwidth	0.4–0.7-Å Bandwidth	<0.1-Å Bandwidth	Experimental	Assigned	Transition
		5800.3 w
		5801.8 w
		5803.1 w
		5806.2 w
		5810.5 w
		5811.5 w
	5813.5 w	5812.6 m	17199	17200	${{}^{5}L}_{6}^{\circ} - {{}^{7}L}_{6}$
	5815 w	5813.7 m	17196
		5817.8 w
5821 w	5820 w	5819.6 m	17178	17176	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
		5824.3 w			–
		5825.8 w			–
5827 m	5827 s	5826.8 w	17157	17158	${{}^{5}I}_{7} - {()}_{6}^{\circ}$
		5820.0 m	17150
	5828.5 m	5828.5 m	17152
	5833 w	5832.4 w	17141
		5834.7 w
	5836.5 w	5836.7 s	17128	17127	${{}^{5}L}_{7}^{\circ} - {()}_{8}$
	5838.5	5838.6 s	17122	17122	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
	5839.5				${{}^{5}I}_{5} - {()}_{5}^{\circ}$
5840 m	5840.5	5840.2 s	17118	17121	${{}^{5}I}_{5} - {()}_{6}^{\circ}$
	5843.5 w	5843.5 m	17108	17110	⁵K₅–⁷L₆
		5844.4 w
		5851.8 m	17084
	5852.5 w	5852.5 w	17082	17084	${{}^{7}L}_{7} - {{}^{5}L}_{7}^{\circ}$
5859 m	5859.5 w	5858.9 s	17063	17062	${{}^{5}I}_{6} - {()}_{6}^{\circ}$
		5860.5 m	17058	17056	${{}^{7}L}_{8} - {()}_{7}^{\circ}$
5863 m	5863.5 m	5862.3 m	17053	17052	${{}^{5}K}_{7}^{\circ} - {()}_{6}$
		5868.7 s	17035
5869 s	5869.5 s	5869.2 s	17033	17032	${{}^{5}I}_{4} - {()}_{4}^{\circ}$
		5869.8 s	17031	17032	${{}^{5}F}_{2} - {()}_{3}^{\circ}$
	5874 w	5873.5 m	17021	17020	${{}^{7}M}_{8}^{\circ} - {()}_{7}$
5874 w	5875 m	5874.5 s	17018	17021	${{}^{5}I}_{7} - {()}_{6}^{\circ}$
5877 m	5877 m	5876.8 s	17011	17011	${{}^{5}L}_{6} - L_{7}^{\circ}$
	5878.5 m	5877.8 m	17008	17005	${{}^{5}I}_{5} - {{}^{3}G}_{5}^{\circ}$
	–	5879.4 w
	5880 w	5880.9 s	16999	17001	${{}^{7}L}_{5} - {()}_{4}^{\circ}$
5882 s	5882 s	5881.5 s	16997	16993	${{}^{5}I}_{8} - {()}_{7}^{\circ}$
5889 s	5889.5 s	5889.1 s	16976	16979	${{}^{5}I}_{4} - {()}_{3}^{\circ}$
	5891 m	5890.6 s	16971	16973	${{}^{7}L}_{5} - {()}_{4}^{\circ}$
	–	5900.6 m	16942		${{}^{5}I}_{5} - {()}_{5}^{\circ}$
5901 m	5901.5 m	5901.5 s	16940	16940	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
	5909.5 w	5909.3 m	16917	16915	${{}^{5}I}_{6} - {()}_{6}^{\circ}$
	–	5911.4 m	16911	16914	${{}^{7}L}_{6} - {()}_{5}^{\circ}$
	–	5913.7 m	16905	16905	${{}^{5}I}_{6} - {{}^{7}G}_{7}^{\circ}$
5914 m	5914 w	5914.2 w	16903	16902	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
5920 w	5920.5 w	5919.9 s	16887	16885	${{}^{7}L}_{8} - {{}^{7}L}_{7}^{\circ}$
		5922.2 m	16881	16879	${{}^{7}L}_{5} - {()}_{6}^{\circ}$
		5926.5 s	16868	16869	${{}^{7}K}_{4} - {()}_{4}^{\circ}$
		5928.1 w
		5933.6 s	16848	16848	${{}^{7}K}_{4} - {()}_{4}^{\circ}$
		5934.4 w
5933.5 m	5935 w	5935.5 s	16843	16845	${{}^{5}I}_{4} - {()}_{5}^{\circ}$
		5940.7 m	16828	16826	${{}^{7}L}_{5} - {()}_{6}^{\circ}$
		5944.7 w
		5945.6 w
		5946.5 w
		5963.6 m	16763
	5968.5 w	5968.0 s	16751	16751	${{}^{5}I}_{7} - {()}_{6}^{\circ}$
	5970 w	5969.5 s	16747	16749	${{}^{7}L}_{6} - {{}^{7}L}_{5}^{\circ}$
		5973 w
	5982 w	5989 w
		5992.6 w
		5993.9 w
	5996 w	5995.7 m	16674	16672	${{}^{7}L}_{7} - {{}^{7}L}_{7}^{\circ}$
		5997.0 w
5999 w	5999.5 w	5999.1 w	16664	16663	${{}^{5}I}_{5} - {()}_{5}^{\circ}$
		6000.6 w	16660	16662	${{}^{5}I}_{5} - {()}_{4}^{\circ}$

RIS Wavelength (Å)

Measured Values		Predicted	Transition(cm⁻¹)

<0.1 Å	0.4–0.7-Å
5965.5	5965.8	5965.9	0–16 757
5934.3	5934.7	5934.8	0–16 845
5887.3	5887.7	5887.8	0–16 979
5869.4	5869.7	5869.5	0–17 032
5824.2	5824.2	5824.8	0–17 163
5878.3	5878.3	5878.8	1128–18 133
5999.5	5999.4	5999.9	1128–17 790
5999.2		5999.7	1128–17 791
5914.2	5914.4	5914.8	1128–18 030
5900.7	5901.2	5901.5	1128–18 068
5865.2	5865.3	5865.5	1128–18 172
	5839.2	5839.0	1128–18 249
5838.7	5838.7	5838.7	1128–18 250
5820.3	5819.7	5820.3	1128–18 304
		5955.8	2367–19 152
		5929.5	2367–19 226
		5913.8	2367–19 271
		5910.4	2367–19 281
5859.3	5858.9	5859.3	2367–19 428
		5883.6	3682–20 673
		5968.2	3682–20 432
		5914.6	3682–20 584
		5873.2	3682–20 703
5826.3		5826.7	3682–20 839
		5800.0	3682–20 918
5829.3	5829
5868.7
5889.1
5889.7
5920.5	5921.0

Abstract

References

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Figures (3)

Tables (2)

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