Accurate wavelengths in O ii

K. B. S. Eriksson

doi:10.1364/JOSAB.4.001369

Journal of the Optical Society of America B
Vol. 4,
Issue 9,
pp. 1369-1371
(1987)
•https://doi.org/10.1364/JOSAB.4.001369

Accurate wavelengths in O ii

K. B. S. Eriksson

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K. B. S. Eriksson, "Accurate wavelengths in O ii," J. Opt. Soc. Am. B 4, 1369-1371 (1987)

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Abstract

The wavelengths of 71 strong O ii lines between 4676 and 525 Å have been measured, based on a high-frequency discharge. Improved energy levels have been derived. Smoothed wavelengths have been recalculated from these. The uncertainty is about 1 mÅ.

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${}^{\sqrt{2}}l og Int .$ ^a	λ_air (Å)			Designation

	New Obs.	Quoted^b	Calc.^c
19	4676.2350	.234B	.2339	3s⁴P_5/2–3p	⁴D_5/2
14	4673.7322	.738	.7331	⁴P_3/2–	⁴D_1/2
19	4661.6332	.633	.6322	⁴P_3/2–	⁴D_3/2
19	4650.8394	.841B	.8386	⁴P_1/2–	⁴D_1/2
23	4649.1348	.139B	.1358	⁴P_5/2–	⁴D_7/2
21	4641.8104	.811B	.8112	⁴P_3/2–	⁴D_5/2
19	4638.8550	.857	.8558	⁴P_1/2–	⁴D_3/2
9	4307.233	.245	.237	3d⁴P_1/2–4f	D(2)_3/2
13	4303.825	.836	.824	⁴P_5/2–	D(3)_7/2
8	4303.609	.623	.611	⁴D_7/2–	G(5)_9/2
12	4294.781	.792	.784	⁴P_3/2–	D(2)_5/2
10	4292.211	.219	.213	²F_5/2–	F(2)_5/2
10	4291.254	.259	.256	⁴P_5/2–	G(3)_7/2
9	4288.820	.819	.821	⁴P_1/2–	D(1)_1/2
12	4285.687	.689	.683	²F_5/2–	F(3)_7/2
10	4282.964	.954	.962	⁴D_3/2–	F(2)_5/2
10	4277.892	.901	.893	⁴D_7/2–	F(3)_7/2
10	4277.427	.439	.430	⁴D_1/2–	F(2)_3/2
12	4276.748	.750	.750	⁴D_5/2–	F(3)_7/2
14	4275.551	.556	.553	⁴D_7/2–	F(4)_9/2
10	4254.121	.126	.123	3d′ ²G_7/2–4f′	H(5)_9/2
11	4253.895	.895	.895	²G_9/2	H(5)_11/2
13	4153.2980	.302	.2985	3p⁴P_3/2–3d	⁴P_5/2
9	4146.076	.077		3p‴ ⁶P_7/2–3d‴	⁶D_9/2
11	4132.8004	.801	.8009	3p⁴P_1/2–3d	⁴P_3/2
10	4121.4619	.464	.4622	⁴P_1/2–	⁴P_1/2
10	4120.544	.544	.5463	⁴P_5/2–	⁴D_3/2
13	4120.280	.279	.2772	⁴P_5/2–	⁴D_5/2
17	4119.215	.216	.2165	⁴P_5/2–	⁴D_7/2
9	4110.7858	.786	.7868	⁴P_3/2–	⁴D_1/2
9	4107.091	.088	.090	3d⁴F_5/2–4f	D(3)_7/2
13	4104.993	.992	.9906	3p⁴P_3/2–3d	⁴D_3/2
11	4104.7231	.728	.7236	⁴P_3/2	⁴D_5/2
8	4103.001	2.998	.7236	⁴P_1/2	⁴D_1/2
11	4098.243	.245	2.9982	3d⁴F_3/2–	4f D(3)_5/2
15	4097.258	.260	.260	⁴F_7/2–	G(4)_9/2
9	4096.525	.530	.5281	3p⁴P_3/2–3d	⁴F_5/2
11	4095.644	.642	.643	3d⁴F_5/2–4f	G(3)_7/2
16	4092.9289	.930	.9282	3p⁴D_7/2–3d	⁴F_7/2
16	4089.288	.285	.287	3d⁴F_9/2–4f	G(5)_11/2
13	4087.152	.152	.154	⁴F_3/2–	G(3)_5/2
16	4085.1125	.114	.1136	3p⁴D_5/2–3d	⁴F_5/2
16	3982.7140	.715	.7141	3p²P_3/2–3p	²P_1/2
21	3973.2562	.260	.2560	²P_3/2–	²P_3/2
18	3954.3619	.366	.3617	²P_1/2–	²P_1/2
16	3945.0375	.040	.0376	²P_1/2–	²P_3/2

${}^{\sqrt{2}}l og Int .$ ^a	λ_air (Å)			Designation

	New Obs.	Quoted^b	Calc.^c
31	834.4655	.467		2p^{3 4}S_3/2–2p⁴	⁴P_5/2
30	833.3294	.332		⁴S_3/2–	⁴P_3/2
28	832.7572	.756B		⁴S_3/2–	⁴P_1/2
22^d	796.682^d	.665B	.6796	2p^{3 2}P_3/2–2p⁴	²D_5/2
19	796.644	.665B	.6424	²P_1/2–	²D_3/2
23	718.5663	.569B	.5666	2p^{3 2}D_3/2–2p⁴	²D_3/2
25	718.5036	.495B	.5036	²D_5/2–	²D_5/2
17	673.768	.768E	.7662	2p^{3 2}P–3s	²P_1/2
19	672.946	.948E	.9457	²P–	²P_3/2
21	644.157	.159B	.1554	2p^{3 2}P–2p⁴	²S_1/2
22	617.0632	.060	.0635	2p^{3 2}D_3/2–3s	²P_1/2
18	616.378	.363E	.3790	²D_3/2–	²P_3/2
24	616.3029	.304	.3028	²D_5/2–	²P_3/2
20	600.586	.585	.5874	2p^{3 2}P–3s′	²D
20	580.9707	.974	.9704	2p^{3 2}P–2p⁴	²P_3/2
18	580.4058	.409B	.4062	²P–	²P_1/2
20	555.117	.121E	.1175	2p^{3 2}D_3/2–3s′	²D_3/2
22	555.060	.056E	.0588	²D_5/2–	²D_5/2
23	539.8544	.853E	.8542	2p^{3 4}S_3/2–3s	⁴P_1/2
25	539.5489	.547E	.5475	⁴S_3/2–	⁴P_3/2
26	539.0855	.086E	.0864	⁴S_3/2–	⁴P_5/2
18^e	538.318^e	.318E	.3199	2p^{3 2}D_3/2–2p⁴	²P_3/2
24	538.2636	.256E	.2618	²D_5/2–	²P_3/2
22	537.8319	.830E	.8322	²D_3/2–	²P_1/2
15	525.9267		.9254	2p^{3 2}P–3s″	²S_1/2

Designation	E (cm⁻¹)	Interval
2p^{3 4}S_3/2	0.00(0)
²D_5/2	26810.52(9)	−20.05(6)^a
²D_3/2	26830.57(9)	−20.05(6)^a
²P_3/2	40467.69(13)	−2.00(3)^a
²P_1/2	40469.69(13)	−2.00(3)^a
3s⁴P_1/2	185235.193	105.295
⁴P_3/2	185340.488	158.538
⁴P_5/2	185499.026	158.538
²P_1/2	188888.456	179.971
²P_3/2	189068.427	179.971
2p^{4 2}S_1/2	195710.40
3p⁴D_1/2	206730.673	55.525
⁴D_3/2	206786.198	91.574
⁴D_5/2	206877.772	124.607
⁴D_7/2	207002.379	124.607
3s′ ²D_5/2	206971.61	−1.00
²D_3/2	206972.61	−1.00
3p⁴P_1/2	208346.018	46.164
⁴P_3/2	208392.182	91.937
⁴P_5/2	208484.119	91.937
2p^{4 2}P_3/2	212593.73	−168.42
²P_1/2	212762.15	−168.42
3p²P_1/2	214169.833	59.751
²P_3/2	214229.584	59.751
3p′ ²D_5/2	229947.00
3s″ ²S_1/2	230609.378
2p^{4 4}P_5/2	119837.19(11)	−163.38
⁴P_3/2	120000.57(11)	−82.45
⁴P_1/2	120083.02(11)	−82.45
²D_5/2	165988.66(18)	−7.86
²D_3/2	165996.52(16)	−7.86
3d⁴F_3/2	231296.040	53.947
⁴F_5/2	231349.987	77.883
⁴F_7/2	231427.870	102.279
⁴F_9/2	231530.149	102.279
⁴P_5/2	232462.643	−73.217
⁴P_3/2	232535.860	−66.548
⁴P_1/2	232602.408	−66.548
⁴D_1/2	232711.563
⁴D_3/2	232745.901	34.338
⁴D_5/2	232747.485	1.584
⁴D_7/2	232753.733	6.248
²F_5/2	232796.209	6.248
4s²P_3/2	240517.237
3d′ ²G_9/2	252608.20	−1.11
²G_7/2	252609.31	−1.11
4f D(3)_7/2	255691.26
D(2)_3/2	255812.62
G(4)_9/2	255827.54
G(5)_9/2	255983.50
F(2)_3/2	256083.51
F(3)_7/2	256123.15
4f′ H(5)_11/2	276109.45

${}^{\sqrt{2}}l og Int .$ ^a	λ_air (Å)			Designation

	New Obs.	Quoted^b	Calc.^c
19	4676.2350	.234B	.2339	3s⁴P_5/2–3p	⁴D_5/2
14	4673.7322	.738	.7331	⁴P_3/2–	⁴D_1/2
19	4661.6332	.633	.6322	⁴P_3/2–	⁴D_3/2
19	4650.8394	.841B	.8386	⁴P_1/2–	⁴D_1/2
23	4649.1348	.139B	.1358	⁴P_5/2–	⁴D_7/2
21	4641.8104	.811B	.8112	⁴P_3/2–	⁴D_5/2
19	4638.8550	.857	.8558	⁴P_1/2–	⁴D_3/2
9	4307.233	.245	.237	3d⁴P_1/2–4f	D(2)_3/2
13	4303.825	.836	.824	⁴P_5/2–	D(3)_7/2
8	4303.609	.623	.611	⁴D_7/2–	G(5)_9/2
12	4294.781	.792	.784	⁴P_3/2–	D(2)_5/2
10	4292.211	.219	.213	²F_5/2–	F(2)_5/2
10	4291.254	.259	.256	⁴P_5/2–	G(3)_7/2
9	4288.820	.819	.821	⁴P_1/2–	D(1)_1/2
12	4285.687	.689	.683	²F_5/2–	F(3)_7/2
10	4282.964	.954	.962	⁴D_3/2–	F(2)_5/2
10	4277.892	.901	.893	⁴D_7/2–	F(3)_7/2
10	4277.427	.439	.430	⁴D_1/2–	F(2)_3/2
12	4276.748	.750	.750	⁴D_5/2–	F(3)_7/2
14	4275.551	.556	.553	⁴D_7/2–	F(4)_9/2
10	4254.121	.126	.123	3d′ ²G_7/2–4f′	H(5)_9/2
11	4253.895	.895	.895	²G_9/2	H(5)_11/2
13	4153.2980	.302	.2985	3p⁴P_3/2–3d	⁴P_5/2
9	4146.076	.077		3p‴ ⁶P_7/2–3d‴	⁶D_9/2
11	4132.8004	.801	.8009	3p⁴P_1/2–3d	⁴P_3/2
10	4121.4619	.464	.4622	⁴P_1/2–	⁴P_1/2
10	4120.544	.544	.5463	⁴P_5/2–	⁴D_3/2
13	4120.280	.279	.2772	⁴P_5/2–	⁴D_5/2
17	4119.215	.216	.2165	⁴P_5/2–	⁴D_7/2
9	4110.7858	.786	.7868	⁴P_3/2–	⁴D_1/2
9	4107.091	.088	.090	3d⁴F_5/2–4f	D(3)_7/2
13	4104.993	.992	.9906	3p⁴P_3/2–3d	⁴D_3/2
11	4104.7231	.728	.7236	⁴P_3/2	⁴D_5/2
8	4103.001	2.998	.7236	⁴P_1/2	⁴D_1/2
11	4098.243	.245	2.9982	3d⁴F_3/2–	4f D(3)_5/2
15	4097.258	.260	.260	⁴F_7/2–	G(4)_9/2
9	4096.525	.530	.5281	3p⁴P_3/2–3d	⁴F_5/2
11	4095.644	.642	.643	3d⁴F_5/2–4f	G(3)_7/2
16	4092.9289	.930	.9282	3p⁴D_7/2–3d	⁴F_7/2
16	4089.288	.285	.287	3d⁴F_9/2–4f	G(5)_11/2
13	4087.152	.152	.154	⁴F_3/2–	G(3)_5/2
16	4085.1125	.114	.1136	3p⁴D_5/2–3d	⁴F_5/2
16	3982.7140	.715	.7141	3p²P_3/2–3p	²P_1/2
21	3973.2562	.260	.2560	²P_3/2–	²P_3/2
18	3954.3619	.366	.3617	²P_1/2–	²P_1/2
16	3945.0375	.040	.0376	²P_1/2–	²P_3/2

${}^{\sqrt{2}}l og Int .$ ^a	λ_air (Å)			Designation

	New Obs.	Quoted^b	Calc.^c
31	834.4655	.467		2p^{3 4}S_3/2–2p⁴	⁴P_5/2
30	833.3294	.332		⁴S_3/2–	⁴P_3/2
28	832.7572	.756B		⁴S_3/2–	⁴P_1/2
22^d	796.682^d	.665B	.6796	2p^{3 2}P_3/2–2p⁴	²D_5/2
19	796.644	.665B	.6424	²P_1/2–	²D_3/2
23	718.5663	.569B	.5666	2p^{3 2}D_3/2–2p⁴	²D_3/2
25	718.5036	.495B	.5036	²D_5/2–	²D_5/2
17	673.768	.768E	.7662	2p^{3 2}P–3s	²P_1/2
19	672.946	.948E	.9457	²P–	²P_3/2
21	644.157	.159B	.1554	2p^{3 2}P–2p⁴	²S_1/2
22	617.0632	.060	.0635	2p^{3 2}D_3/2–3s	²P_1/2
18	616.378	.363E	.3790	²D_3/2–	²P_3/2
24	616.3029	.304	.3028	²D_5/2–	²P_3/2
20	600.586	.585	.5874	2p^{3 2}P–3s′	²D
20	580.9707	.974	.9704	2p^{3 2}P–2p⁴	²P_3/2
18	580.4058	.409B	.4062	²P–	²P_1/2
20	555.117	.121E	.1175	2p^{3 2}D_3/2–3s′	²D_3/2
22	555.060	.056E	.0588	²D_5/2–	²D_5/2
23	539.8544	.853E	.8542	2p^{3 4}S_3/2–3s	⁴P_1/2
25	539.5489	.547E	.5475	⁴S_3/2–	⁴P_3/2
26	539.0855	.086E	.0864	⁴S_3/2–	⁴P_5/2
18^e	538.318^e	.318E	.3199	2p^{3 2}D_3/2–2p⁴	²P_3/2
24	538.2636	.256E	.2618	²D_5/2–	²P_3/2
22	537.8319	.830E	.8322	²D_3/2–	²P_1/2
15	525.9267		.9254	2p^{3 2}P–3s″	²S_1/2

Abstract

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Tables (3)

Journal of the Optical Society of America B