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Intracavity absorption detection of magnetic-dipole transitions in 18O2 and the determination of the b 1Σg+(v = 2) state rotational constants

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Abstract

Intracavity absorption spectroscopy was employed to obtain the b 1Σg+(υ = 2) ← X 3Σg(υ = 0), magnetic-dipole spectrum of the isotopic 18O2 molecule. Values for the rotational constants B2 and D2 (1.2067 ± 0.0005 cm−1 and 4.7 ± 0.5 × 10−6 cm−1, respectively) were deduced subsequently from 50 of the ΔN = −1 transitions.

© 1988 Optical Society of America

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