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Stretchable optical diffraction grating from poly(acrylic acid)/polyethylene oxide stereocomplex

Abstract

Advances in optical materials, which were initially static elements, have enabled dynamically tunable optical diffraction gratings to be designed. One common tuning strategy relies on mechanical deformation of the grating pitch to modify the diffraction pattern. In the present work, we demonstrate an all-polymer tunable diffraction grating fabricated using a modified replica molding process. The poly(acrylic acid) (PAA)/polyethylene oxide (PEO) polymer stereocomplex films exhibit optical transmittance at or above 80% from 500 nm to 1400 nm and stretchability over 800% strain with reversibility under 70% strain. The imprinted gratings are characterized at 633 nm and 1064 nm under a range of strain conditions. The measured tunability agrees with finite element method modeling.

© 2021 Optical Society of America

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Supplementary Material (1)

NameDescription
Supplement 1       Experimental details and data

Data Availability

The data analysis code is freely available in Ref. [21]. Data underlying the results presented in this Letter are not publicly available at this time but may be obtained from the authors upon reasonable request.

21. A. M. Armani, "rgb-image-analysis," GitHub (2019) [accessed 19 July 2019], https://github.com/armanilab/rgb-image-analysis.

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