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Opto-thermoelectric trapping of fluorescent nanodiamonds on plasmonic nanostructures

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Abstract

Deterministic optical manipulation of fluorescent nanodiamonds (FNDs) in fluids has emerged as an experimental challenge in multimodal biological imaging. Designing and developing nano-optical trapping strategies to serve this purpose is an important task. In this Letter, we show how chemically prepared gold nanoparticles and silver nanowires can facilitate an opto-thermoelectric force to trap individual entities of FNDs using a long working distance lens, low power-density illumination (532-nm laser, 12 µW/µm2). Our trapping configuration combines the thermoplasmonic fields generated by individual plasmonic nanoparticles and the opto-thermoelectric effect facilitated by the surfactant to realize a nano-optical trap down to a single FND that is 120 nm in diameter. We use the same trapping excitation source to capture the spectral signatures of single FNDs and track their position. By tracking the FND, we observe the differences in the dynamics of the FND around different plasmonic structures. We envisage that our drop-casting platform can be extrapolated to perform targeted, low-power trapping, manipulation, and multimodal imaging of FNDs inside biological systems such as cells.

© 2023 Optica Publishing Group

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Supplementary Material (5)

NameDescription
Supplement 1       Supplementary information
Visualization 1       Visualization 1. Individual FND diffuses towards the anchored 150 nm Au np, which is at the center of the screen. The FND is readily trapped as shown. The video is recorded at 20 mM concentration of CTAC and 4 mW laser power.
Visualization 2       Visualization 2. Trapping and dark field ability. The FND is readily trapped as shown. The video is recorded at 20 mM concentration of CTAC and 4 mW laser power.
Visualization 3       Visualization 3. FND is repeatedly trapped and released using 400 nm Au np as the anchor particle. The video is recorded at 14 mM CTAC concentration and 1.2 mW laser power.
Visualization 4       Visualization 4. FND is trapped and released using (350 nm edge-to-edge thickness) AgNW. The video is recorded at 14 mM CTAC concentration and 3 mW laser power.

Data availability

Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

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Equations (1)

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