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Surface-enhanced Raman scattering from silver particles on polymer-replica substrates

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Abstract

Evaporation of silver onto polymer microstructures produces a particle system for which optical characterization (e.g., absorbance) is possible. Measurements of surface-enhanced Raman scattering from these surfaces are compared with the particle-plasmon resonance model, including radiation-damping effects. The results provide evidence for the correlation between the Raman-excitation resonance and the optical properties of the silver system, supporting the electromagnetic model of surface Raman enhancement.

© 1982 Optical Society of America

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