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Dual chirped-pulse electro-optical frequency comb method for simultaneous molecular spectroscopy and dynamics studies: formic acid in the terahertz region

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Abstract

An electro-optic dual-comb system based on chirped-pulse waveforms is used to simultaneously acquire temporally magnified rapid passage signals and normal spectral line shapes from the back-transformation to the time domain. Multi-heterodyne terahertz (THz) wave generation and detection is performed with the difference frequency mixing of two free-running lasers. The method is used to obtain THz spectra of formic acid in the 10 cm-1 to 20 cm-1 (300 GHz–600 GHz) region over a range of pressures. The method is widely applicable across other spectral regions for investigations of the transient dynamics and spectroscopy of molecular systems.

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Supplementary Material (1)

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Supplement 1       Supplemental Document

Data availability

Data underlying the results presented in this paper are available in Ref. [12].

12. D. F. Plusquellic, “Dual chirped-pulse electro-optical frequency comb method for simultaneous molecular spectroscopy and dynamics studies: Formic acid in the THz region,” NIST Public Data Repository (2022) https://doi.org/10.18434/mds2-2684.

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