Abstract

Color centers in wide bandgap semiconductors are attracting broad attention for use as platforms for quantum technologies relying on room-temperature single-photon emission (SPE), and for nanoscale metrology applications building on the centers’ response to electric and magnetic fields. Here, we demonstrate room-temperature SPE from defects in cubic boron nitride (cBN) nanocrystals, which we unambiguously assign to the cubic phase using spectrally resolved Raman imaging. These isolated spots show photoluminescence (PL) spectra with zero-phonon lines (ZPLs) within the visible region (496–700 nm) when subject to sub-bandgap laser excitation. Second-order autocorrelation of the emitted photons reveals antibunching with g2(0) ∼ 0.2, and a decay constant of 2.75 ns that is further confirmed through fluorescence lifetime measurements. The results presented herein prove the existence of optically addressable isolated quantum emitters originating from defects in cBN, making this material an interesting platform for opto-electronic devices and quantum applications.

© 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

With an atomic structure equivalent to that of diamond, refractive index close to 2.1, an optical bandgap exceeding 10 eV, and the possibility of n- and p-type doping, cubic boron nitride (cBN) is attracting interest as a host for atomic defects with optical features across a wide region of the electromagnetic spectrum [13]. A combination of photoluminescence (PL) and electron paramagnetic resonance (EPR) studies have shed light on the optical and electronic properties of a range of point defects, from vacancies to heavy-metals and rare-earth elements [13]. A combination of photoluminescence (PL) and electron paramagnetic resonance (EPR) studies have shed light on the optical and electronic properties of a range of point defects, from vacancies to heavy-metals and rare-earth elements [10–12]. Computational methods have also been used to study native and extrinsic defects in cBN, predicting the existence of an oxygen-related defect having isoelectronic properties to the well-known NV center in diamond [49. Computational methods have also been used to study native and extrinsic defects in cBN, predicting the existence of an oxygen-related defect having isoelectronic properties to the well-known NV center in diamond [1012]. In contrast, hexagonal boron nitride (hBN), which has recently found much interest in the context of single photon emission [13], has proven to host very limited spin activity at the single-defect level [14,15]. Thus far, however, experimental signatures from single atomic defects in cBN have proven elusive. Mainly, this has been due to its hardness along with its synthesis requirements, which pose limitations on defect engineering methods; as well as the energy separation between the defect levels within the bandgap, often large enough to make them inaccessible through optical excitation. Cathodoluminescence (CL), which provides the necessary energies to reach deep intra-band defect levels in cBN has been successfully used in this context. However, electron excitation usually results in synchronized emission from nearby defect centers that can be excited by the same incoming electron, posing difficulties for single-defect studies and antibunching measurements which are key to unambiguously identify individual defects [13,16].

Here, we report on room-temperature single-photon emission (SPE) originating from atomic defects in cBN, some of which show spectral features like those previously reported for color centers in single-crystal cBN [1,4]. We overcome some of the aforementioned limitations by using nanocrystalline cBN flakes, which have a high density of near-surface atomic defects accessible through optical laser excitation. By employing confocal Raman spectroscopy, we show that the optical regions of interest are indeed dominated by the cubic phase of BN, while small hexagonal boron nitride (hBN) quantities arising as a synthesis byproduct are found to phase-segregate in nm-sized regions.

cBN nanocrystals (dispersed in ethanol) obtained from PlasmaChem GmbH are drop-cast onto a Si/SiO2 substrate, kept at 60 °C under ambient conditions. The as-prepared samples show a variable distribution of cBN nanocrystal sizes (Fig. 1(a)) that strongly depends upon drop-cast parameters, such as solution concentration and dispersion. Individual nanocrystals range in size (80–450 nm) but are usually found to be around 160 nm. These high-quality cBN crystals can be obtained either by high-pressure/high-temperature (HPHT) synthesis from boron- and nitrogen-containing precursors, or by HPHT treatments of hBN in the presence of catalysts [17]. As a result, there are usually small fractions of hBN present in cBN samples, especially in polycrystalline, powder-like and cBN nanocrystals [17,18]. Thus, an important part of this study consists in characterizing possible phase-segregation of hBN within the nanocrystalline cBN, while ensuring that the optically probed domains correspond to cBN-dominated regions.

 figure: Fig. 1.

Fig. 1. Confocal Raman spectroscopy of cBN nanocrystals. (a) Laser reflection imaging reveals large area coverage and conglomeration of cBN nanoflakes. (b) Raman spectrum collected by averaging over the squared region in (a) shows cBN LO and TO phonon modes strongly dominate over the E2g mode of hBN. (c-e) Confocal Raman spectroscopy for select phonon energies (shaded areas in (b)) show that the cubic phase of BN is dominant and uniform across the sample, while hBN regions seem to be localized possibly due to phase segregation. Scale bar denotes 2 µm.

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Raman studies on BN show that cBN and hBN have spectrally separated vibrational signatures that can be used to identify and differentiate the two phases [1921]. Specifically, both cBN and hBN have an optical phonon mode centered at Γ point which, due to ionic contributions, splits into longitudinal and transverse optical phonon modes (LO and TO) only in the case of cBN. These cBN modes are usually centered around 1254 and 1055 cm−1, respectively, while the E2g-symmetric phonon mode of hBN is centered around 1365 cm−1 [1921]. Performing both optical and Raman confocal spectroscopy thus allows us to establish that the collected fluorescence originates from defects in cBN nanocrystals.

We perform Raman spectroscopy via a confocal Raman microscope (alpha300 R; WITec GmbH), equipped with a 100x (1.0NA) microscope objective and an SHG Nd:YAG laser (532 nm). Collected photons are sent to a spectrometer with a CCD-camera (1024 × 128 pixel, Peltier cooled to -65°C) rejecting reflected and elastically scattered photons by using an edge filter. The nominal spectral resolution is found to be ∼5 cm−1 per CCD pixel. Due to low scattering cross sections, Raman signatures from both BN phases tend to be close to the noise level, especially when dealing with nanocrystalline samples. A well-resolved Raman spectrum from the different BN phases is thus obtained by averaging over specific scanned areas (dashed square in Fig. 1(a)) while integrating for 0.5 s and illuminating at ∼12.0 mW laser power (Fig. 1(b)). The main Raman spectral features extracted from this and several other locations include two dominant peaks centered at ∼1055 and ∼1254 cm−1, which arise from TO and LO modes in cBN, respectively, and a third, lower intensity peak centered at ∼1360 cm−1 arising from the E2g phonon mode in hBN. For confocal Raman imaging, the 50 µm core of a multimode fiber serves as the pinhole, which leads to a focal depth of ∼1 µm, while the diffraction-limited spot results in a lateral resolution of ∼1–2 µm. Scanning over the same region while only collecting one of the specific phonon energies in Fig. 1(b) reveals an almost uniform distribution for both TO and LO cBN modes (Fig. 1(c, d) respectively), while showing a non-uniform distribution for the E2g hBN mode (Fig. 1. (e)). The small amount of residual hBN is thus observed to be localized at specific spots, mainly resulting from phase segregation. Further, the ratio, I(E2g)/I(TO + LO) = 0.0615 ± 0.0053 averaged over multiple regions, confirms that these are indeed cBN-dominated nanocrystalline domains. We observe variable linewidths and small energy shifts in all the BN phonon modes throughout different sample locations, possibly due to size effects, local strain and relaxation of both phases to nanocrystalline states [19,21]. However, all Raman measurements demonstrate that the cubic phase of BN dominates across the sample, while small hBN quantities are found to segregate within nm-sized regions.

To elucidate the optoelectronic properties of defect-related color centers in cBN nanocrystals, room-temperature confocal spectroscopy is performed via a home-built confocal microscope, equipped with a 50x (0.83 NA) objective and a 460 nm continuous-wave (CW) laser (L462P1400MM, ThorLabs). The collected fluorescence is filtered from the excitation source by using a 500 nm long-pass filter (LPF) and sent through a fiber beam splitter allowing for real-time spectral analysis and time-resolved measurements. The excitation source, with spot-size of about ∼ 1 µm, is kept at an average power below 200 µW to avoid/suppress blinking and bleaching of single emitters. Despite the inhomogeneity in the spatial distribution of flakes owing to the drop-casting technique, a collection of isolated bright spots across large sample areas is systematically observed upon sub-bandgap excitation (Fig. 2(a)), indicating the presence of defect centers within the cBN nanoflakes independent of the sample preparation process. Most of the isolated bright spots inside the cBN nanoflakes usually give broad fluorescence features. Usually, two main cases are observed: (1) real-time spectral analysis shows substantial blinking of different zero-phonon lines (ZPLs) associated with different centers inside the same diffraction-limited spot (defect ensembles); (2) individual ZPLs arise on top of a broadband background, which is present in the nearby nanoflake regions. The majority of the ZPLs arising from single defects, however, are found to share similar spectral response, as can be observed by comparing Fig. 2(b) and Fig. 2(c), some of which resemble features previously reported from color centers in cBN, e.g., under UV-excitation [4]. Other ZPLs tend to resemble those observed in hBN defects (Fig. 2(d)), e.g., with phonon replicas matching the E2g phonon mode energy (∼165 meV). Thus, it is noted that both cBN and hBN defects are found across the sample. However, the majority of the observed emitters are unlikely to originate from hBN defects due to: (1) their uniform distribution across the sample and the high extent of hBN localization (Fig. 1); (2) mismatch between the obtained spectral features and those reported for hBN defects; (3) the similarities between most of the observed emitters and those previously reported in cBN.

 figure: Fig. 2.

Fig. 2. Steady-state confocal spectroscopy of cBN nanoflakes. (a) Confocal imaging of a representative cBN region reveals an array of isolated bright spots. White circles denote spots that showed sharp and spectrally separated ZPLs. (b-d) Representative optical spectra for different bright spots identified with (orange, green and blue) arrows in (a). While (b, c) show spectral features comparable to those reported for defects in cBN (black arrows), (d) reveals a phonon replica matching the E2g phonon energy in hBN demonstrating that both cBN and hBN defects are present across the sample. Scale bar denotes 2 µm.

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To further study the dynamics and photon correlation of defects in cBN nanoflakes, we turn to room-temperature time-resolved and correlation spectroscopy. CW photon correlation measurements are performed via Hanbury-Brown-Twiss (HBT) interferometry (Picoquant, Picoharp 300) using two avalanche photodiode detectors (APD) and 460 nm laser excitation. Lifetime measurements are performed using the 488 nm line of an 80 MHz, 500-fs pulsed tunable laser (Toptica FemtoFiber TVIS). Results from these studies are summarized in Fig. 3. The obtained spectrum from a single defect center in cBN is shown in Fig. 3(a), with features indicated by arrows matching the shape and distribution of those previously reported [4]. In our study, however, these features appeared much more separated (∼130 meV), while preserving the separation from the main peak. Given the similarities between these shifts and the phonon energies for cBN (∼130 and ∼160 meV), these are likely to be phonon replicas. The fluorescence time-trace of this single defect center under continuous excitation showed substantial blinking (Fig. 3(b)), a signature characteristic of isolated quantum emitters, likely due to different charge-states of the excited defect. Photon correlation of the collected fluorescence through the second-order autocorrelation function, g2(τ), gives rise to a clear dip at zero-time delay (Fig. 3(c)), with g2(0) = 0.229 proving the quantum nature of the emitter. A slight bunching component with time constant of ∼30 ns is observed, which points at a possible metastable and/or charge state that may correlate to the blinking behavior observed during fluorescence time traces [5,13,22]. Finally, lifetime measurements reveal an exponential decay (Fig. 3(d)) from which a radiative time constant of 2.753 ns is obtained. This exponential decay is further confirmed directly from CW g2(τ) measurements and falls well within the range of fluorescence lifetimes previously reported from point defects in cBN [1,5]. Exposure to external magnetic fields of up to 0.1 T and/or circularly polarized excitation yield no discernible change in the fluorescence, hence suggesting magneto-optically-active defects — including the ONVB center, predicted to have a response similar to that of the NV in diamond — may not be widespread. We warn, however, most emitters tend to fade upon prolonged exposure to the laser beam, hence requiring additional work — e.g., exploiting time-modulated magnetic fields — will be required to expose weak magneto-optical contrast.

 figure: Fig. 3.

Fig. 3. Time-resolved fluorescence spectroscopy of a single defect center in cBN. (a) Optical spectrum of an isolated color center under 460 nm continuous-wave (CW) excitation. Blue arrows indicate features that match those previously observed for the GB-1 color center under UV-excitation. Inset shows a zoomed-in confocal scan of this emitter (dotted circle). (b) Time-trace of the collected fluorescence showing fast transitions to a dark-state, characteristic of most of single-emitters. (c) Second-order autocorrelation function, showing photon antibunching at zero-time delay with g2(0) = 0.258. (d) Fluorescence lifetime under 488 nm pulsed excitation. Solid line represents a biexponential decay fit to the experimental data (orange circles). Scale bar denotes 1 µm.

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In summary, we have demonstrated room-temperature SPE from defects in cBN nanoflakes. Confocal images show isolated bright spots across the nanoflakes, while Raman spectroscopy confirms that these are indeed cBN-dominated nanocrystalline domains with the ratio, I(E2g)/I(TO + LO) ∼ 0.06. The amount of residual hBN is localized at different spots (phase segregation) and further confirms the cBN-origin of the observed color centers. Fluorescence spectroscopy reveals numerous ZPLs in the visible region, mainly covering 496–700 nm. Interestingly, the optical signatures of some of the studied defects resemble those previously reported [4] for color centers in cBN, with a clear shift (∼130 meV) on the separation between the main peak and its low-intensity features. These features hint at an electronic structure unique to these color centers, while suggesting electron-phonon coupling similar to that of defects in cBN, e.g., the GB-1 centers [1,4]. These results open interesting possibilities in defect engineering based on cBN, combining properties similar to its hexagonal counterpart while providing a wider bandgap, ease of being ion-bombarded and a new group of diverse defect-related color centers.

Funding

National Science Foundation (1726573, 1906096, HRD-1547830); Research Corporation (FRED Award).

Acknowledgements

V.M.M. and C.A.M. acknowledge support from the National Science Foundation through grants NSF-1906096 and NSF-1726573. C.A.M. also acknowledges support from Research Corporation for Science Advancement through a FRED Award; all authors acknowledge partial funding and access to the facilities of the NSF CREST IDEALS, grant number NSF-HRD-1547830. VM acknowledges useful discussions with Prof. Igor Aharonovich.

Disclosures

The authors declare no conflicts of interest.

References

1. A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018). [CrossRef]  

2. L. Vel, G. Demazeau, and J. Etourneau, “Cubic boron nitride: synthesis, physicochemical properties and applications,” Mater. Sci. Eng., B 10(2), 149–164 (1991). [CrossRef]  

3. G. Cappellini and G. Satta, “Optical properties of BN in cubic and layered hexagonal phases,” Phys. Rev. B 64(3), 035104 (2001). [CrossRef]  

4. E. M. Shishonok, “Luminescence centers in cubic boron nitride,” J. Appl. Spectrosc. 74(2), 272–277 (2007). [CrossRef]  

5. R. Buividas, I. Aharonovich, G. Seniutinas, X. W. Wang, L. Rapp, A. V. Rode, T. Taniguchi, and S. Juodkazis, “Photoluminescence from voids created by femtosecond-laser pulses inside cubic-BN,” Opt. Lett. 40(24), 5711 (2015). [CrossRef]  

6. E. M. Shishonok, S. V. Leonchik, and J. W. Steeds, “Luminescence from europium, europium–chromium, erbium, samarium and terbium-activated powder, ceramic and polycrystalline cubic boron nitride,” Phys. Status Solidi B 244(6), 2172–2179 (2007). [CrossRef]  

7. E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007). [CrossRef]  

8. S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000). [CrossRef]  

9. S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010). [CrossRef]  

10. W. Orellana and H. Chacham, “Stability of native defects in hexagonal and cubic boron nitride,” Phys. Rev. B 63(12), 125205 (2001). [CrossRef]  

11. P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997). [CrossRef]  

12. T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014). [CrossRef]  

13. T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016). [CrossRef]  

14. A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019). [CrossRef]  

15. N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

16. S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015). [CrossRef]  

17. S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006). [CrossRef]  

18. Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006). [CrossRef]  

19. S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005). [CrossRef]  

20. T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997). [CrossRef]  

21. O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010). [CrossRef]  

22. Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016). [CrossRef]  

References

  • View by:

  1. A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
    [Crossref]
  2. L. Vel, G. Demazeau, and J. Etourneau, “Cubic boron nitride: synthesis, physicochemical properties and applications,” Mater. Sci. Eng., B 10(2), 149–164 (1991).
    [Crossref]
  3. G. Cappellini and G. Satta, “Optical properties of BN in cubic and layered hexagonal phases,” Phys. Rev. B 64(3), 035104 (2001).
    [Crossref]
  4. E. M. Shishonok, “Luminescence centers in cubic boron nitride,” J. Appl. Spectrosc. 74(2), 272–277 (2007).
    [Crossref]
  5. R. Buividas, I. Aharonovich, G. Seniutinas, X. W. Wang, L. Rapp, A. V. Rode, T. Taniguchi, and S. Juodkazis, “Photoluminescence from voids created by femtosecond-laser pulses inside cubic-BN,” Opt. Lett. 40(24), 5711 (2015).
    [Crossref]
  6. E. M. Shishonok, S. V. Leonchik, and J. W. Steeds, “Luminescence from europium, europium–chromium, erbium, samarium and terbium-activated powder, ceramic and polycrystalline cubic boron nitride,” Phys. Status Solidi B 244(6), 2172–2179 (2007).
    [Crossref]
  7. E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007).
    [Crossref]
  8. S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000).
    [Crossref]
  9. S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010).
    [Crossref]
  10. W. Orellana and H. Chacham, “Stability of native defects in hexagonal and cubic boron nitride,” Phys. Rev. B 63(12), 125205 (2001).
    [Crossref]
  11. P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997).
    [Crossref]
  12. T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
    [Crossref]
  13. T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
    [Crossref]
  14. A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
    [Crossref]
  15. N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).
  16. S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
    [Crossref]
  17. S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
    [Crossref]
  18. Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
    [Crossref]
  19. S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
    [Crossref]
  20. T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997).
    [Crossref]
  21. O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
    [Crossref]
  22. Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
    [Crossref]

2019 (1)

A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
[Crossref]

2018 (1)

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

2016 (2)

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

2015 (2)

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

R. Buividas, I. Aharonovich, G. Seniutinas, X. W. Wang, L. Rapp, A. V. Rode, T. Taniguchi, and S. Juodkazis, “Photoluminescence from voids created by femtosecond-laser pulses inside cubic-BN,” Opt. Lett. 40(24), 5711 (2015).
[Crossref]

2014 (1)

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

2010 (2)

S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010).
[Crossref]

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

2007 (3)

E. M. Shishonok, S. V. Leonchik, and J. W. Steeds, “Luminescence from europium, europium–chromium, erbium, samarium and terbium-activated powder, ceramic and polycrystalline cubic boron nitride,” Phys. Status Solidi B 244(6), 2172–2179 (2007).
[Crossref]

E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007).
[Crossref]

E. M. Shishonok, “Luminescence centers in cubic boron nitride,” J. Appl. Spectrosc. 74(2), 272–277 (2007).
[Crossref]

2006 (2)

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

2005 (1)

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

2001 (2)

W. Orellana and H. Chacham, “Stability of native defects in hexagonal and cubic boron nitride,” Phys. Rev. B 63(12), 125205 (2001).
[Crossref]

G. Cappellini and G. Satta, “Optical properties of BN in cubic and layered hexagonal phases,” Phys. Rev. B 64(3), 035104 (2001).
[Crossref]

2000 (1)

S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000).
[Crossref]

1997 (2)

P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997).
[Crossref]

T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997).
[Crossref]

1991 (1)

L. Vel, G. Demazeau, and J. Etourneau, “Cubic boron nitride: synthesis, physicochemical properties and applications,” Mater. Sci. Eng., B 10(2), 149–164 (1991).
[Crossref]

Abtew, T. A.

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

Aharonovich, I.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

R. Buividas, I. Aharonovich, G. Seniutinas, X. W. Wang, L. Rapp, A. V. Rode, T. Taniguchi, and S. Juodkazis, “Photoluminescence from voids created by femtosecond-laser pulses inside cubic-BN,” Opt. Lett. 40(24), 5711 (2015).
[Crossref]

Alkauskas, A.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Arenal, R.

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

Bassett, L. C.

A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
[Crossref]

Bello, I.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

Berhane, A. M.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Bourrellier, R.

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Bray, K.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Buividas, R.

Cappellini, G.

G. Cappellini and G. Satta, “Optical properties of BN in cubic and layered hexagonal phases,” Phys. Rev. B 64(3), 035104 (2001).
[Crossref]

Cazimajou, T.

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Chacham, H.

W. Orellana and H. Chacham, “Stability of native defects in hexagonal and cubic boron nitride,” Phys. Rev. B 63(12), 125205 (2001).
[Crossref]

Chan, C.

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Chang, H. C.

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Chejanovsky, N.

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Chong, Y.

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Chong, Y. M.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Considine, C. R.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Da-Peng, Y.

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Dasari, D. B. R.

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Demazeau, G.

L. Vel, G. Demazeau, and J. Etourneau, “Cubic boron nitride: synthesis, physicochemical properties and applications,” Mater. Sci. Eng., B 10(2), 149–164 (1991).
[Crossref]

Denisenko, A.

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

di Sabatino, S.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

Dinca, G.

S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000).
[Crossref]

Doherty, M. W.

A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
[Crossref]

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Etourneau, J.

L. Vel, G. Demazeau, and J. Etourneau, “Cubic boron nitride: synthesis, physicochemical properties and applications,” Mater. Sci. Eng., B 10(2), 149–164 (1991).
[Crossref]

Exarhos, A. L.

A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
[Crossref]

Fazzio, A.

P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997).
[Crossref]

Fedder, H.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Ferrari, A. C.

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

Finkler, A.

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Gao, W.

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

Gao, X.

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

Garashchenko, V.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Gatti, M.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

Ghica, D.

S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010).
[Crossref]

Gontar, A. G.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Goovaerts, E.

S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010).
[Crossref]

Hahn, J.

T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997).
[Crossref]

Hopper, D. A.

A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
[Crossref]

Jayakumar, H.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Juodkazis, S.

Kim, Y.

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Kociak, M.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Kutsay, O.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Lee, S.

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Lee, S. T.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Leonchik, S. V.

E. M. Shishonok, S. V. Leonchik, and J. W. Steeds, “Luminescence from europium, europium–chromium, erbium, samarium and terbium-activated powder, ceramic and polycrystalline cubic boron nitride,” Phys. Status Solidi B 244(6), 2172–2179 (2007).
[Crossref]

E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007).
[Crossref]

Leung, K.

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Li, L. H.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Li, Y. K.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Loiseau, A.

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

Ma, K.

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Mackoit, M.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Menon, V. M.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Meriles, C. A.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Meuret, S.

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Mota, R.

P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997).
[Crossref]

Mukherjee, A.

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Nistor, S. V.

S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010).
[Crossref]

S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000).
[Crossref]

Novikov, N. V.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Orellana, W.

W. Orellana and H. Chacham, “Stability of native defects in hexagonal and cubic boron nitride,” Phys. Rev. B 63(12), 125205 (2001).
[Crossref]

Patel, R. N.

A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
[Crossref]

Piquini, P.

P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997).
[Crossref]

Rapp, L.

Reich, S.

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

Reining, L.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

Richter, F.

T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997).
[Crossref]

Robertson, J.

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

Rode, A. V.

Sandstrom, R. G.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Satta, G.

G. Cappellini and G. Satta, “Optical properties of BN in cubic and layered hexagonal phases,” Phys. Rev. B 64(3), 035104 (2001).
[Crossref]

Schmidt, T. M.

P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997).
[Crossref]

Schoemaker, D.

S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000).
[Crossref]

Seniutinas, G.

Shishonok, E. M.

E. M. Shishonok, “Luminescence centers in cubic boron nitride,” J. Appl. Spectrosc. 74(2), 272–277 (2007).
[Crossref]

E. M. Shishonok, S. V. Leonchik, and J. W. Steeds, “Luminescence from europium, europium–chromium, erbium, samarium and terbium-activated powder, ceramic and polycrystalline cubic boron nitride,” Phys. Status Solidi B 244(6), 2172–2179 (2007).
[Crossref]

E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007).
[Crossref]

Shotan, Z.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Smet, J. H.

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Steeds, J. W.

E. M. Shishonok, S. V. Leonchik, and J. W. Steeds, “Luminescence from europium, europium–chromium, erbium, samarium and terbium-activated powder, ceramic and polycrystalline cubic boron nitride,” Phys. Status Solidi B 244(6), 2172–2179 (2007).
[Crossref]

E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007).
[Crossref]

Stefan, M.

S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010).
[Crossref]

Stefana, M.

S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000).
[Crossref]

Sun, Y. Y.

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

Taniguchi, T.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

R. Buividas, I. Aharonovich, G. Seniutinas, X. W. Wang, L. Rapp, A. V. Rode, T. Taniguchi, and S. Juodkazis, “Photoluminescence from voids created by femtosecond-laser pulses inside cubic-BN,” Opt. Lett. 40(24), 5711 (2015).
[Crossref]

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Tararan, A.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

Tie-Chen, Z.

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Tizei, L. H. G.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Toth, M.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Tran, T. T.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Treussart, F.

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Vel, L.

L. Vel, G. Demazeau, and J. Etourneau, “Cubic boron nitride: synthesis, physicochemical properties and applications,” Mater. Sci. Eng., B 10(2), 149–164 (1991).
[Crossref]

Wang, X. W.

Watanabe, K.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Werninghaus, T.

T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997).
[Crossref]

Wolverson, D.

E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007).
[Crossref]

Wrachtrup, J.

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

Xiao-Rui, J.

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Xi-Liang, G.

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Xu-Xin, Y.

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Yan, C.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Ye, Q.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Yong-Hui, D.

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Zachreson, C.

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Zahn, D. R. T.

T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997).
[Crossref]

Zapien, J. A.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Zhang, P.

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

Zhang, S. B.

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

Zhang, W.

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Zhang, W. J.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Zhou, Z. F.

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

Zobelli, A.

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

Zuo-Peng, S.

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

ACS Photonics (1)

Z. Shotan, H. Jayakumar, C. R. Considine, M. Mackoit, H. Fedder, J. Wrachtrup, A. Alkauskas, M. W. Doherty, V. M. Menon, and C. A. Meriles, “Photoinduced Modification of Single-Photon Emitters in Hexagonal Boron Nitride,” ACS Photonics 3(12), 2490–2496 (2016).
[Crossref]

Appl. Magn. Reson. (1)

S. V. Nistor, M. Stefan, D. Ghica, and E. Goovaerts, “Multifrequency ESR Characterization of Paramagnetic Point Defects in Semiconducting Cubic BN Crystals,” Appl. Magn. Reson. 39(1-2), 87–101 (2010).
[Crossref]

Appl. Phys. Lett. (1)

T. Werninghaus, J. Hahn, F. Richter, and D. R. T. Zahn, “Raman spectroscopy investigation of size effects in cubic boron nitride,” Appl. Phys. Lett. 70(8), 958–960 (1997).
[Crossref]

Chem. Vap. Deposition (1)

Y. Chong, K. Ma, K. Leung, C. Chan, Q. Ye, I. Bello, W. Zhang, and S. Lee, “Synthesis and Mechanical Properties of Cubic Boron Nitride/Nanodiamond Composite Films,” Chem. Vap. Deposition 12(1), 33–38 (2006).
[Crossref]

Chin. Phys. Lett. (1)

S. Zuo-Peng, D. Yong-Hui, J. Xiao-Rui, Y. Da-Peng, Y. Xu-Xin, G. Xi-Liang, and Z. Tie-Chen, “Synthesis of Cubic Boron Nitride by the Reaction of Li3N and B2O3,” Chin. Phys. Lett. 23(8), 2285–2287 (2006).
[Crossref]

Diamond Relat. Mater. (2)

E. M. Shishonok, S. V. Leonchik, J. W. Steeds, and D. Wolverson, “Strong ultraviolet luminescence from cerium- and gadolinium-doped cubic boron nitride,” Diamond Relat. Mater. 16(8), 1602–1607 (2007).
[Crossref]

O. Kutsay, C. Yan, Y. M. Chong, Q. Ye, I. Bello, W. J. Zhang, J. A. Zapien, Z. F. Zhou, Y. K. Li, V. Garashchenko, A. G. Gontar, N. V. Novikov, and S. T. Lee, “Studying cubic boron nitride by Raman and infrared spectroscopies,” Diamond Relat. Mater. 19(7-9), 968–971 (2010).
[Crossref]

J. Appl. Spectrosc. (1)

E. M. Shishonok, “Luminescence centers in cubic boron nitride,” J. Appl. Spectrosc. 74(2), 272–277 (2007).
[Crossref]

Mater. Sci. Eng., B (1)

L. Vel, G. Demazeau, and J. Etourneau, “Cubic boron nitride: synthesis, physicochemical properties and applications,” Mater. Sci. Eng., B 10(2), 149–164 (1991).
[Crossref]

Nat. Commun. (1)

A. L. Exarhos, D. A. Hopper, R. N. Patel, M. W. Doherty, and L. C. Bassett, “Magnetic-field-dependent quantum emission in hexagonal boron nitride at room temperature,” Nat. Commun. 10(1), 222 (2019).
[Crossref]

Opt. Lett. (1)

Phys. Rev. Appl. (1)

T. T. Tran, C. Zachreson, A. M. Berhane, K. Bray, R. G. Sandstrom, L. H. Li, T. Taniguchi, K. Watanabe, I. Aharonovich, and M. Toth, “Quantum Emission from Defects in Single-Crystalline Hexagonal Boron Nitride,” Phys. Rev. Appl. 5(3), 034005 (2016).
[Crossref]

Phys. Rev. B (5)

A. Tararan, S. di Sabatino, M. Gatti, T. Taniguchi, K. Watanabe, L. Reining, L. H. G. Tizei, M. Kociak, and A. Zobelli, “Optical gap and optically active intragap defects in cubic BN,” Phys. Rev. B 98(9), 094106 (2018).
[Crossref]

G. Cappellini and G. Satta, “Optical properties of BN in cubic and layered hexagonal phases,” Phys. Rev. B 64(3), 035104 (2001).
[Crossref]

W. Orellana and H. Chacham, “Stability of native defects in hexagonal and cubic boron nitride,” Phys. Rev. B 63(12), 125205 (2001).
[Crossref]

P. Piquini, R. Mota, T. M. Schmidt, and A. Fazzio, “Theoretical studies of native defects in cubic boron nitride,” Phys. Rev. B 56(7), 3556–3559 (1997).
[Crossref]

S. Reich, A. C. Ferrari, R. Arenal, A. Loiseau, I. Bello, and J. Robertson, “Resonant Raman scattering in cubic and hexagonal boron nitride,” Phys. Rev. B 71(20), 205201 (2005).
[Crossref]

Phys. Rev. Lett. (2)

T. A. Abtew, W. Gao, X. Gao, Y. Y. Sun, S. B. Zhang, and P. Zhang, “Theory of Oxygen-Boron Vacancy Defect in Cubic Boron Nitride: A Diamond NV− Isoelectronic Center,” Phys. Rev. Lett. 113(13), 136401 (2014).
[Crossref]

S. Meuret, L. H. G. Tizei, T. Cazimajou, R. Bourrellier, H. C. Chang, F. Treussart, and M. Kociak, “Photon Bunching in Cathodoluminescence,” Phys. Rev. Lett. 114(19), 197401 (2015).
[Crossref]

Phys. Status Solidi B (1)

E. M. Shishonok, S. V. Leonchik, and J. W. Steeds, “Luminescence from europium, europium–chromium, erbium, samarium and terbium-activated powder, ceramic and polycrystalline cubic boron nitride,” Phys. Status Solidi B 244(6), 2172–2179 (2007).
[Crossref]

Solid State Commun. (1)

S. V. Nistor, M. Stefana, D. Schoemaker, and G. Dinca, “EPR observation of first point defects in cubic boron nitride crystalline powders,” Solid State Commun. 115(1), 39–44 (2000).
[Crossref]

Other (1)

N. Chejanovsky, A. Mukherjee, Y. Kim, A. Denisenko, A. Finkler, T. Taniguchi, K. Watanabe, D. B. R. Dasari, J. H. Smet, and J. Wrachtrup, “Single spin resonance in a van der Waals embedded paramagnetic defect,” arXiv:1906.05903 (2019).

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Figures (3)

Fig. 1.
Fig. 1. Confocal Raman spectroscopy of cBN nanocrystals. (a) Laser reflection imaging reveals large area coverage and conglomeration of cBN nanoflakes. (b) Raman spectrum collected by averaging over the squared region in (a) shows cBN LO and TO phonon modes strongly dominate over the E2g mode of hBN. (c-e) Confocal Raman spectroscopy for select phonon energies (shaded areas in (b)) show that the cubic phase of BN is dominant and uniform across the sample, while hBN regions seem to be localized possibly due to phase segregation. Scale bar denotes 2 µm.
Fig. 2.
Fig. 2. Steady-state confocal spectroscopy of cBN nanoflakes. (a) Confocal imaging of a representative cBN region reveals an array of isolated bright spots. White circles denote spots that showed sharp and spectrally separated ZPLs. (b-d) Representative optical spectra for different bright spots identified with (orange, green and blue) arrows in (a). While (b, c) show spectral features comparable to those reported for defects in cBN (black arrows), (d) reveals a phonon replica matching the E2g phonon energy in hBN demonstrating that both cBN and hBN defects are present across the sample. Scale bar denotes 2 µm.
Fig. 3.
Fig. 3. Time-resolved fluorescence spectroscopy of a single defect center in cBN. (a) Optical spectrum of an isolated color center under 460 nm continuous-wave (CW) excitation. Blue arrows indicate features that match those previously observed for the GB-1 color center under UV-excitation. Inset shows a zoomed-in confocal scan of this emitter (dotted circle). (b) Time-trace of the collected fluorescence showing fast transitions to a dark-state, characteristic of most of single-emitters. (c) Second-order autocorrelation function, showing photon antibunching at zero-time delay with g2(0) = 0.258. (d) Fluorescence lifetime under 488 nm pulsed excitation. Solid line represents a biexponential decay fit to the experimental data (orange circles). Scale bar denotes 1 µm.

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