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Evaluations of nanoparticle capture and transport methods in dielectric bowtie core capillaries

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Abstract

We propose a flexibly tunable and low-loss optical burette with an all-dielectric bowtie core capillary structure, where nanoparticle arrays can be transported bidirectionally with incident light from one end. Multiple hot spots, acting as optical traps, are periodically distributed at the center of the bowtie cores along the propagation direction because of the mode interference effect of guided lights. By adjusting the beam waist position, the hot spots continuously move across the entire capillary length; thus, trapped nanoparticles also transfer with the hot spots. The bidirectional transfer can be realized simply by changing the beam waist in the forward or backward direction. We confirmed that nanosized polystyrene spheres can be bidirectionally moved along a capillary length of ≈ 20 µm. Furthermore, the magnitude of the optical force can be adjusted using the incident angle and beam waist width, whereas the trapping period can be adjusted using the incident wavelength. These results were evaluated using the finite-difference time-domain method. We believe that this new approach can be extensively used in the field of biochemical and life sciences because of the properties of an all-dielectric structure, bidirectional transportation, and single incident light.

© 2023 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement

1. Introduction

Optical trapping and manipulation techniques [13] have piqued significant research interest in the fields of transport and positioning of nano and micro objects [4,5], as well as bioanalysis [6,7] and quantum information [8,9]. The conventional method is to use a far-field focus of single or multiple beams to trap and position particles along the optical axis [1012]. In recent years, near-filed optical devices have attracted attention as a means of handling smaller particles by overcoming the diffraction limit, thermal issues and transporting tiny particles in flexible trajectories [13]. As a result, waveguides, such as nanosized optical fibers, photonic crystal resonators, nanoapertures [14,15] slot waveguides [16,17], and V groove waveguides [18] have become research targets. Yang analyzed the optical transport and trapping of gold and polystyrene nanoparticles smaller than 100 nm in silicon slot waveguides [16]. After analyzing the relationship between trapping stability and the consequent transport speed as a function of particle size, particle refractive index, and slot waveguide shape, they achieved trapping and transport for objects as small as 10 or 20 nm in diameter.

In recent years, more precise control, such as positioning, of small particles has been required. To trap a nanoobject along the waveguide propagating direction, Tong created a potential well by locally narrowing the slot to create a slit in the center [19]. As a result, they could increase higher intensity spots at the slit and create a significant gradient force, which restrains particles. However, because of the predesigned structure, it could not position particles at arbitrarily assigned places.

For more precise positioning and fine adjustment of nanoparticles, the ability to transport particles backward against the light propagating direction is also required. Wang achieved a waveguide-coupled optical conveyor using graded silver nanorods [20]. By switching the incident wavelengths, particles can be transported bidirectionally following the hot spots produced by resonance. The position of the particle can be restricted on a subwavelength scale. Along with precise control, the use of metals significantly increases the intensity loss and restricts the effective working length. In Schmidt’s work [21], microparticles could be transported over long distances and precisely positioned in a low-loss air-filled hollow-core photonic crystal fiber utilizing a coherent superposition of two co-propagating spatial modes balanced by a backward-propagating fundamental mode. Conversely, the counter-propagating beam requires a light source on both ends of the device, which increases the total size of the system and restricts its application fields.

We have proposed a single-input optical conveyor belt that can transport elliptical particles bidirectionally by adjusting incident wavelengths based on the absorption of Si and the scattering effect of the particles [22]. However, this method is only effective on elliptical particles with a major axis longer than a specific threshold. Besides, the fact that the pulling force is obtained by absorption and scattering significantly restricts the effective working length.

Based on the above discussion on existent optical conveyor belts and to integrate multiple functions, we propose a new concept called “optical burettes” that consists of dielectric bowtie cores [23,24] that can interact with nonluminous space, such as an intracellular atmosphere, by transporting or extracting nanoparticles based on its properties of single-end-source and bidirectional transmission induced by multimode excitation and interference effects. By recurrently changing the position of the incident beam waist, which can be realized by moving an objective lens against the incident surface of the bowtie burette, the position of intensity hot spots, known as an optical trap, can be moved continuously along fiber cores, and more importantly, with the fringe shape of the intensity distribution unchanged. Thus, by continuously moving or discretely switching the beam waist appropriately, the target nanoparticles can be bidirectionally transported along the capillary or positioned at arbitrarily assigned places. The distance between each optical trap can be adjusted by switching incident wavelengths, whereas the magnitude of the trapping force can be modulated by switching the incident angle.

The propagating modes in the bowtie fiber and their interference patterns along the bowtie center are introduced in the first part of this article. Then, we discuss and compare the effects of multiple parameters on the mode interference pattern, such as the position of the beam waist, input wavelength, beam waist width, and incident angle, and investigate how they affect the intensity peak distribution. The materials of bowtie cores and the effective working length are also discussed. The optical force and potential well are calculated to prove that the particles can be attracted into the capillary and transported bidirectionally.

2. Bowtie core capillary structure

The three-dimensional perspective and end face shape of the proposed bowtie core capillary are depicted in Fig. 1. x-polarized light has a high-intensity peak in the center of the core gap [23,24] due to the high-refractive-index contrast bowtie core structure. This structure is suitable for nanoparticle trapping because it produces a smaller, more intense light spot than the conventional rectangular core-slotted waveguide structure. In this study, we consider a structure, in which a bowtie core of Si3N4, which is typically used in photonic circuits, with a core diameter dcore and a gap distance dgap of 30 nm, is enclosed by a thin SiO2 capillary. The capillary is immersed in water (nb= 1.33). The target nanoparticles are supposed to be polystyrene spheres (np = 1.6) to preserve a strong resemblance with biological particles with a diameter dp of 20 nm dispersed in capillaries. A continuous, x-polarized beam with a Gaussian profile is launched into the fiber at z = 0 in our simulation. The width of the beam waist is denoted by w0. The depth distance between the beam waist and the capillary incidence plane is denoted by d. The angle between the z-axis and the incident light is denoted by θx on the xz plane and θy on the yz plane. The incident wavelength used in the simulation shifts from 0.3 µm to 1.3 µm, and is denoted by λ. The power of the incident light was 1 mW. The parameters and their symbols are listed in Table 1.

 figure: Fig. 1.

Fig. 1. Schematic of (a) a three-dimensional view of bowtie core capillary trapping nanoparticles at hot spots. (b) xy cross-section of bowtie cores with a particle at the core center. (c) xy view of bowtie cores in SiO2 capillary. (d) xz view of incident scheme with different depths d along z. (e) xz view of incident scheme with different waist widths w0. (f) xz (and yz) view of incident scheme with different incident angles to the z axis θx (and θy). At least one of θx and θy maintains 0. The components are not on an actual scale.

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Tables Icon

Table 1. Symbols and values of the parameters

3. Optical force

The total optical force applied on a particle is obtained by integrating the Maxwell stress tensor (MST) on an enclosed surface S surrounding it:

$${\mathbf{F}} = \oint {\mkern 1mu} {{\mkern 1mu} _S}{\mathbf{T}} \cdot {\mathbf{nd}}S$$
where n represents the surface normal, dS denotes the surface element of S, and T represents the MST given by
$${T_{ij}} = \varepsilon {E_i}{E_j} + \mu {B_i}{B_j} - \frac{1}{2}\left( {\varepsilon {E^2} + \mu {H^2}} \right){\delta _{ij}}$$
where E and H represent the electric and magnetic field components with coordinate indexes i and j, ε and μ denote the permittivity and permeability of the surrounding material, and δ represents the Kronecker delta function. The E and H fields are obtained using the three-dimensional finite-difference time-domain method through the commercial simulation tool RSoft FullWAVE [25].

4. Simulation and discussion of transportation and positioning of particles

The longitudinal and lateral distributions of guided modes in a bowtie core capillary with dcore= 0.5 µm and dgap = 0.03 µm at λ = 0.5 µm are illustrated in Fig. 2. The fundamental (LP01) mode demonstrates that light is constrained to the center of the core gap, where particle capture is expected. In contrast, the LP11 mode is weak and has little effect on particle capture at the core center. Both the fundamental and LP02 modes exhibit a comparable confinement effect at the gap center; however, the light phase at the wings is reversed. If the fundamental mode is excited only in the fiber, the |Ex|2 distribution along z remains stable, as depicted in Fig. 2(e). The scattering force plays the main role in pushing the particle in the + z direction. When the Gaussian beam with w0 = 0.5 µm is launched under d = 0 and θx = θy = 0, high-order modes are also excited with the LP01 mode. The mode interference forms a periodically distributed |Ex|2, as illustrated in Fig. 2(d) and (e), because each mode has a unique group velocity. Force Fz along the |Ex|2 gradient, shown in Fig. 2(f), is applied to particles trapped at the gap center, and a positive or negative |Ex|2 slope causes particle transport in the + z or −z direction, respectively. A continuous transport happens if the periodic |Ex|2 distribution shifts.

 figure: Fig. 2.

Fig. 2. Normalized Ex real part of (a) fundamental (LP01) mode, (b) LP11 mode, and (c) LP02 mode in the bowtie core capillary with λ = 0.5 µm, w0 = 0.5 µm, d = 0, θx(y) = 0, and dcore = 0.25 µm. (a), (b), and (c) share the same colormap. (d) Normalized |Ex|2 distribution on xz plane at y = 0. (e) Normalized |Ex|2 distribution along z at x = y = 0, the launch of Gaussian profile and LP01 mode. (f) z component of optical force along z at x = y = 0, the launch of Gaussian profile and LP01 mode.

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Because the beam waist can be treated as the first focal point of the mode interference, we start by thinking about changing the waist depth d of the beam to shift the distribution of |Ex|2. The distributions of |Ex|2 along the z-axis at λ = 0.75 and 0.5 µm are shown in Fig. 3(a) and (b). While the peak position is slightly altered, the period of interference fringes remains constant with respect to changes in d. Nevertheless, clear interference fringes are maintained at d within approximately 2 µm as |d| grows despite an increase in the optical coupling loss in the capillary. Figure 3(e) and (f) depict the Fz distributions on the particles produced by the |Ex|2 gradient at λ = 0.75 and 0.5 µm, respectively. Here we focus on two particular cases of particle movement through d change.

 figure: Fig. 3.

Fig. 3. (a), (b) Normalized |Ex|2 distribution at x = y = 0 along z axis with d = −5–5 µm at λ = 0.75 and 0.5 µm, respectively. (c) and (d) Normalized |Ex|2 distribution at x = y = 0 along z when d = −2, 0, and 2 µm at λ = 0.75 and 0.5 µm, respectively. (e) and (f) z component of optical force Fz at x = y = 0 along z when d = −2, 0, and 2 µm at λ = 0.75 and 0.5 µm, respectively. (g) and (h) Displacement of |Ex|2 peaks on z when d = −5–5 µm at λ = 0.75 and 0.5 µm, respectively. w0 = 0.5 µm, dcore = 0.5 µm, dgap = 0.03 µm, θx(y) = 0.

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We assume that a nanoparticle is trapped at the maximum |Ex|2 point at z ≈ 10 µm when d = 2 µm in Fig. 3(c) and (e). When d is shifted to 0, the maximum |Ex|2 point moves to z ≈ 10.5 µm in the + z direction, causing the particle to move under the + Fz in the same direction and be stuck at the peak position. Moreover, as d shifted to −2 µm, the fringe peak shifted to z ≈ 11 µm, and the particle was trapped there. The short-range nanoparticle transfer of 1 µm is now realized by shifting d from 2 to −2 µm. To transport the particle further along + z, we need to transmit the particle to the next adjacent peak in the + z direction. The next adjacent |Ex|2 peak occurs when d = 2 µm. However, when d is shifted back to 2 µm, the particle is on a negative |Ex|2 slope, and thus, −Fz pulls the particle backward to z ≈ 10.5 µm. Under λ = 0.75 µm and d = −2–2 µm, the particle will be constrained in one d period and will not be able to propagate through the entire capillary, as indicated by the arrows in Fig. 3(c). In Fig. 3(e), there exist + Fz bounce points (defined as the reversal point of force direction) at z ≈ 8.5, 11.25, and 13.75 µm, prohibiting the + z transmission of the particle. Likewise, the −z transmission is impeded by −Fz bounce points at z ≈ 9.75 and 12.5 µm.

Figure 3(d) and (f) show a successful example to transport a nanoparticle along the entire waveguide. We assume that a nanoparticle is trapped at z ≈ 7.2 µm for d = 2 µm at λ = 0.5 µm, w0 = 0.5 µm, θx(y) = 0, and dcore = 0.25 µm, dgap = 0.03 µm. The particle is subsequently transported to the |Ex|2 peak positions, where z ≈ 7.6 and 8.2 µm, by + Fz when d shifts to 0 and then to −2 µm. If d changes back to 2 µm because the particle is still on the positive |Ex|2 slope of the next adjacent peak, +Fz continues to propel the particle forward, beginning a new cycle, as indicated by the arrows in Fig. 3(d). In contrast, particle −z transmission can be realized by continuous −Fz when d shifts in the order of −2, 0, and 2 µm. In Fig. 3(g) and (f), when d changes within ±5 µm, the z positions of |Ex|2 peaks shift within −0.76–0.56 µm at λ = 0.75 µm and within −0.48–0.52 µm at λ = 0.5 µm, respectively. This property indicates that the nanoparticles are moved continuously and smoothly with a d shift and can be trapped at any z position.

We establish a new function, namely, the transfer capacity Tc(d), as the |Ex|2 peak shift range within ± d over the|Ex|2 peak period to numerically evaluate the transfer continuity. The following condition is required to accomplish continuous transfer: Tc(d) > 0.5. In the successful example, Tc(2) ≈ 0.67, with a shift range of 1 µm and a peak period of 1.5 µm. In comparison, in the unsuccessful case, Tc(2) ≈ 0.4, with a shift range of 1 µm and a peak period of 2.5 µm. However, for the unsuccessful example, if |d| is increased to 5 µm, Tc(5) ≈ 0.528, which meets the continuous transfer condition. Thus, while designing an optical burette, one can increase |d| to obtain a continuous transfer; however, this must be balanced with Fz, because longer |d| contributes to a higher Tc(d) while decreasing Fz.

Modifying the incident wavelength λ is another way to shift |Ex|2 distribution. The normalized |Ex|2 distribution dependent on λ is shown in Fig. 4(a), with λ = 0.3–1.3 µm, d = 0, w0 = 0.6 µm, and θx(y) = 0. The |Ex|2 distribution is mainly divided into three bands. The first band is a “single-mode band” with λ ≈ 1.1–1.3 µm. In this single-mode band, w0 is large compared with the bowtie core diameter, resulting in only the fundamental mode being coupled from the incident beam. The particles are mainly pushed in the + z direction by the scattering force. The second band is a “few-mode band” with λ ≈ 0.65–1.1 µm. In this band, w0 becomes smaller than bowtie cores, exciting the high-order modes, LP11 and LP02 modes. The |Ex|2 distribution appears periodic and unambiguous with longer λ producing a longer period. The particles will be trapped at the maximal |Ex|2 points. The third band is a “multimode band” with λ ≈ 0.3–0.65 µm. In this band, w0 is small compared with bowtie cores. As more high-order modes are excited in this band, the interference pattern becomes chaotic and erratic.

 figure: Fig. 4.

Fig. 4. (a) Normalized |Ex|2 field distribution at x = y = 0 along the z-axis at λ = 0.3–1.3 µm, at w0 = 0.6 µm, θx(y) = 0, d = 0, in the bowtie core capillary with dcore = 0.5 µm, dgap = 0.03 µm. (b), (c) Normalized |Ex|2 distribution and Fz distribution at x = y = 0 along z at λ = 0.5, 0.8, and 1.2 µm, respectively. (d) Fz distribution at x = y = 0 along z at λ = 0.7, 0.85 and 1 µm, respectively.

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To compare the transmission force in detail, we choose three typical wavelengths, λ = 0.5, 0.8, and 1.2 µm, as representations for the three bands. The distributions of |Ex|2 and Fz along z at x = y = 0 are shown in Fig. 4(b) and (c). The distribution of |Ex|2 is relatively smooth at λ = 1.2 µm because the fundamental mode dominates the intensity. The |Ex|2 gradient-induced Fz has a smooth but low magnitude of approximately 0.01 pN/W. For λ = 0.8 µm in the “few-mode band,” the periodically changed |Ex|2 field becomes more obvious, indicating that almost the same amount of LP02 mode was excited, along with the LP01 mode. The high contrast of |Ex|2 also makes a higher optical force. For λ = 0.5 µm in the “multimode band,” the |Ex|2 distribution has an irregular shape, making Fz unpredictable.

To transport particles along the entire capillary, continuous force pointing in one direction is required. However, Fig. 4(c) shows that there exist bounce points along the z-axis for both positive and negative Fz, which means that the continuous force cannot be formed by switching wavelengths between λ = 0.5, 0.8, and 1.2 µm.

Because the |Ex|2 distribution in the “few-mode band” is reasonably regular and has high contrast, we choose λ = 0.7, 8.5, and 1 µm to investigate the transporting ability and illustrate the Fz distribution in Fig. 4(d). Although several bounce points still appear along z, preventing continuous transfer through the entire capillary, a short-range continuous transfer of −5.5 µm is realized.

The above analysis helps us choose the appropriate λ for different applications. For instance, a longer wavelength should be chosen for moving particles along the waveguide by the even-distributed intensity of the fundamental mode, and “few-mode band” wavelengths should be chosen for trapping and transporting particles in a short range. In addition, the trapping period can be adjusted by choosing different λ.

The |Ex|2 distribution can also be changed by modifying the beam waist width w0. We change w0 from 0.25 to 1 µm at λ = 0.5 µm, θx(y) = 0, d = 0 with bowtie core parameters dcore = 0.25 µm and dgap = 0.03 µm. The |Ex|2 shown in Fig. 5(a) appears as a stable periodic distribution without a noticeable shift along z. Nevertheless, the maximal and minimal |Ex|2 positions are inverse on each side of a transitional band of w0 = 0.65–0.75 µm, which means that the peak position is discretely shifted by half period. To find a continuous |Ex|2 shift, we magnify the |Ex|2 distribution at w0 = 0.65–0.75 µm to Fig. 5(b) and mark the boundary of the high-intensity area by solid lines at |Ex|2 = 0.5. The |Ex|2 peak shifts quickly around the threshold w0 = 0.68 µm without a clear continuous shifting band. We then choose w0 = 0.5, 0.68, and 1 µm as representatives from the three bands and show their |Ex|2 and Fz distributions in Fig. 5(c) and (d). An antidirectional, regularly distributed Fz is produced by the high contrast, phase-opposite |Ex|2 distribution at w0 = 0.5 and 1 µm. This property can be used to switch the force direction without moving the optical trap. The |Ex|2 distribution exhibits stability for w0 = 0.68 µm, resulting in Fz with an amplitude of 0.005 pN/W, which is a comparatively modest value compared to Fz caused by other w0. The one-directional Fz is always interrupted by Fz = 0, preventing continuous particle transport between |Ex|2 peaks. Although the Fz created by w0 = 0.68 µm can correct the continuity of the Fz produced by w0 = 0.5 and 1 µm, it is not reasonable to believe that the low magnitude can aid in particle movement. In conclusion, changing w0 alone is not an effective way to transport particles, but it still has value in force magnitude and direction adjustments when combined with other transport mechanisms.

 figure: Fig. 5.

Fig. 5. (a), (b) Normalized |Ex|2 field distribution at x = y = 0 along the z-axis with w0 = 0.25–1 µm (from 0.5λ to 2λ) at λ = 0.5 µm, θ = 0, d = 0, in bowtie capillary with dcore = 0.25 µm, dgap = 0.03 µm. The solid lines indicate the normalized |Ex|2 = 0.5. (c), (d) Normalized |Ex|2 field distribution and Fz distribution at x = y = 0 along z at d = 0.5, 0.68, and 1 µm, respectively.

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Finally, we attempt to alter the distribution of |Ex|2 by incident angle θx and θy. θx and θy are changed from 0° to 60° individually at λ = 0.5 µm, w0 = 0.5 µm, dcore = 0.25 µm, and dgap = 0.03 µm, and the corresponding normalized |Ex|2 is displayed in Fig. 6(a) and (b) for θx and θy, respectively. The fringe form is unaffected by the incident angle in either of the figures, meaning that a change in the incident angle does not affect the interference pattern. The amplitude of |Ex|2 reduces while θx(y) increases due to the growing coupling loss. The incident light is completely reflected at the incidence plane when θx(y) > 46°, causing the intensity of the bowtie core gap to disappear suddenly. The |Ex|2 and Fz distribution at θx = 0, 25, and 43° are depicted in Fig. 6(c) and (d). Because of the approximately constant period and the peak position of the |Ex|2 at the three angles, the direction of Fz along z is steady. Notably, |Ex|2 at θx = 25° has a higher contrast between its maximal and minimal value, resulting in a greater optical force. Hence, altering the incident angle θ is an excellent way to change the magnitude of the force and contrast but not for particle transport.

 figure: Fig. 6.

Fig. 6. (a), (b) Normalized |Ex|2 distribution at x = y = 0 along the z-axis at θx(y) = 0°–60°. (c), (d) Normalized |Ex|2 distribution and Fz distribution at x = y = 0 along z at θx = 0, 25 and 43°. λ = 0.5 µm, w0 = 0.5 µm, d = 0, θy = 0.

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In this section, we realized continuous nanoparticle transport by changing the depth of the incident beam waist. Modifying the incident wavelength can also transport nanoparticle in a short range and adjust the period of optical traps. Modifying the beam waist width and incident angle can effectively adjust the magnitude of the optical force.

5. Method of particle capture in the direction of the core center

The next issue is determining how to load particles into the bowtie gap. We considered the case where particles were trapped along the y direction. Figure 7(a–c) present the |Ex|2 distribution on xy cross-sections at z = 2.85, 2.46, and 2.13 µm, which are the z positions of |Ex|2 peak, half, and bottom values, respectively. The |Ex|2 value at x = 0 was extracted from Fig. 7(d). It is obvious that |Ex|2 near y = 0 is significantly higher than the surrounding area, which produces a gradient force near the bowtie center pointing to y = 0, acting as a trapping force, as depicted in Fig. 7(e). Although the amplitude of the trapping force Fy changes with different positions, the trapping center formed by the force remains unchanged, meaning that particles can be trapped in the bowtie center at any z position. For a simpler method, the fundamental mode can be used to form uniformly distributed intensity along z, attracting particles at any z position near the bowtie center with constant Fy. The fundamental mode can be produced by adjusting w0 to a value greater than the bowtie size.

 figure: Fig. 7.

Fig. 7. Normalized |Ex|2 distribution on the xy cross section at (a) |Ex|2 peak (z = 2.85 µm), (b) |Ex|2 half (z = 2.46 µm), and (c) |Ex|2 bottom (z = 2.13 µm) at λ = 0.5 µm, w0 = 0.5 µm, and d = 0, θx(y) = 0. (d) Normalized |Ex|2 and (e) Fy along y axis at x = 0.

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6. Bowtie core material, loss effects and potential well

To explore the wider applicability of bowtie core capillaries, we simulated a high-refractive index (n = 3.03 at λ = 0.75 µm) semiconductor material AlAs, which is also extensively used in optical waveguides [26], to replace Si3N4 (n = 2.04 and 2.01 at λ = 0.5 and 0.75 µm, respectively) bowtie cores. The normalized |Ex|2 in the bowtie center and Fz along z are depicted in Fig. 8(a) and (b), at λ = 0.75 µm, w0 = 0.5 µm, θx(y) = 0, and d = −1, 0, and 1 µm, in the waveguide with dcore = 0.25 µm and dgap = 0.03 µm. The Fz produced by the |Ex|2 gradient always remains in the + z direction when d is shifted in the order 1, 0, and −1 µm recurrently. In contrast, continuous −Fz can be realized by changing d in the order −1, 0, and 1 µm. The simulation result indicates that continuous bidirectional transport can be achieved with shorter d in bowtie core capillaries with higher-refractive index materials.

 figure: Fig. 8.

Fig. 8. (a) Normalized |Ex|2 distribution at x = y = 0 along z when d = −1, 0, and 1 µm at λ = 0.75 µm. (b) z component of optical force Fz at x = y = 0 along z when d = −1, 0, and 1 µm at λ = 0.75 µm, w0 = 0.5 µm, dcore = 0.25 µm, dgap = 0.03 µm, and θ = 0. (c) Normalized |Ex|2 distribution at x = y = 0 along z with Si3N4 and AlAs bowtie cores. The parameters of incident light and shape of Si3N4 bowtie cores are the same as in Fig. 2(b) at d = 0.

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The propagation loss of bowtie cores is also considered, which decides the effective working length of the optical burette. We compare the normalized |Ex|2 distribution at x = y = 0 along z of Si3N4 and AlAs bowtie cores with a capillary length of 100 µm, as shown in Fig. 8(c). The dashed lines indicate the peak values. According to Fig. 8(c), neither material exhibits significant intensity attenuation after being transported 100 µm, and the duration of the |Ex|2 fringe remains constant, indicating that the optical force also maintains the same distribution. Therefore, it is reasonable to expect that the effective working length of the burette is significantly greater than 100 µm due to the negligible propagation loss of Si3N4 and AlAs bowtie cores.

In our proposal, the thermal effect is believed to be negligible. The optical trapping force is produced by the near-field enhancement which has a higher efficiency than using a focusing lens and reduces the energy aggregation and heat generation. Besides, the bowtie core is assigned as all dielectric materials without any metal or plasmonic effect in use, making the heat production by plasmonic absorption negligible [13,19]. In addition, the high thermal conductivity of Si3N4 [27] and AlAs [28], hundred times higher than water, also contributes to heat dissipation.

The capture stability of nanoparticles is represented by the potential well U [16,29]. The potential well corresponds to the amount of work necessary to move a particle from a specific position to infinity, which is calculated by integrating the force along the particle escaping direction. A particle can be stably trapped when |U| > 1 kBT, where kB is the Boltzmann constant (1.3805 × 10−23 J/K), and T is the absolute temperature in Kelvin scale (T = 293.15 K). When |U| < 1 kBT, the particle can easily hop away due to the Brownian motion. The potential well of trapping and transporting a nanoparticle with dp = 20 nm by Si3N4 bowtie core capillary is shown in Fig. 9, which shows stable trapping ability in z and y direction. The weakest Uz locates at z ≈ 8.1 µm when d shifts from −2 to 2 µm as circled by dot line in Fig. 9(a). To satisfy the trapping condition |Uz| > 1 kBT, the power threshold of the incident light can be extrapolated as Pin = 136 mW.

 figure: Fig. 9.

Fig. 9. Potential well of trapping a 20 nm particle by Si3N4 bowtie cores. (a) The potential well along z at x = y = 0 when d = −2, 0, and 2 µm. (b) The potential well along y at x = 0 and z positions of different |Ex|2 magnitude. The other situations are the same as in Fig. 3(d).

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When transport particles forward by changing the waist depth, the depth should be shifted in the order of −|d|, 0, |d| and then back to −|d|. We also investigated the suitable switching time from −|d| to |d| to demonstrate the technical feasibility. We assume that d is shifted by moving the objective lens forward or backward at a constant velocity vl in the z direction. Due to the ultrasmall size of the particle, the fluid viscosity resistance Fdrag and Brownian force FBr are considered, which can be calculated as [29]:

$${F_{drag}} = 3\pi {d_p}\eta {v_p}$$
$${F_{Br}} = R\sqrt {\frac{{6\pi {k_B}T{d_p}\eta }}{{{{\Delta }}t}}}$$
where η is the dynamic viscosity of water (1 × 10−3 Pa·s), R is a Gaussian random number with a mean value of 0 and a unit standard deviation, and Δt is the time interval.

Here, we use the example when transport a particle forward as described in Fig. 3(d) and (f). We assume that the particle has already been trapped at z = 8.2 µm at d = −2 µm. To transmit the particle forward, the objective lens should be moved 4 µm backward to shift d from −2 to 2 µm. The instantaneous particle position shift Δzp is shown in Fig. 10(a). When d shifts in a relatively large velocity vl = −1000 µm/s, the particle shifts slightly in z direction with Δzp = −0.04 µm. In this case, the particle can be captured by the next forward |Ex|2 envelope. The speed threshold is obtained as vl = −375 µm/s. The speed |vl| lower than 375 µm/s causes the particle to be pulled back to the previous |Ex|2 envelope, preventing the forward transmission. Thus, the faster |vl| is, the more possible that the continuous transmission can be achieved. The vl threshold at different Pin is shown as the dash line in Fig. 10(b). The slowest vl allowing continuous forward transmission is 2.79 mm/s at Pin = 1 W, which is reasonably easy to achieve.

 figure: Fig. 10.

Fig. 10. (a) The instantaneous particle position shift Δzp during d shifts from −2 to 2 µm with incident power Pin = 136 mW and objective lens moving speed vl = −150, −375 and −1000 µm/s. (b) The particle position shift Δzp at the moment when d shifts to 2 µm with a dependency on vl and input power Pin. The initial status is assumed as that the particle is trapped at z = 8.2 µm at d = −2 µm. The other situations are the same as in Fig. 3(d).

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7. Conclusion

We proposed a tunable bowtie core optical burette capable of bidirectionally transporting nanoparticles with incident light from a single end. Because of the intensity of hot spots created by mode interference, nanoparticles are trapped and transported. Polystyrene spheres with diameters of 20 nm can be transported continuously along the + z direction at λ = 0.5 µm by recurrently switching the beam waist depth d in the order of 2, 0 and −2 µm. d shift from −2 back to 2 µm can be realized by moving objective lens backward with a velocity within mm/s level. Similarly, the −z transmission is achieved by switching d in the order of −2, 0 and 2 µm. The particles can be loaded into the fiber center from the y direction. The transporting distance is expected to be greater than hundreds of microns due to the low-loss material of bowtie cores. The transporting and positioning properties such as the magnitude of optical force, direction of particle transfer, and period of optical traps can be controlled by the incident angle θx(y), the beam waist width w0, and incident wavelength λ.

Acknowledgments

The authors acknowledge the support of JSPS Grant Number JP20K04627. The authors would like to thank Qin Xu, Xuecheng Li, and Chenlin Zhao for their contributions to the development of the simulation environment.

Disclosures

The authors declare no conflicts of interest related to this article.

Data availability

Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

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Data availability

Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

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Figures (10)

Fig. 1.
Fig. 1. Schematic of (a) a three-dimensional view of bowtie core capillary trapping nanoparticles at hot spots. (b) xy cross-section of bowtie cores with a particle at the core center. (c) xy view of bowtie cores in SiO2 capillary. (d) xz view of incident scheme with different depths d along z. (e) xz view of incident scheme with different waist widths w0. (f) xz (and yz) view of incident scheme with different incident angles to the z axis θx (and θy). At least one of θx and θy maintains 0. The components are not on an actual scale.
Fig. 2.
Fig. 2. Normalized Ex real part of (a) fundamental (LP01) mode, (b) LP11 mode, and (c) LP02 mode in the bowtie core capillary with λ = 0.5 µm, w0 = 0.5 µm, d = 0, θx(y) = 0, and dcore = 0.25 µm. (a), (b), and (c) share the same colormap. (d) Normalized |Ex|2 distribution on xz plane at y = 0. (e) Normalized |Ex|2 distribution along z at x = y = 0, the launch of Gaussian profile and LP01 mode. (f) z component of optical force along z at x = y = 0, the launch of Gaussian profile and LP01 mode.
Fig. 3.
Fig. 3. (a), (b) Normalized |Ex|2 distribution at x = y = 0 along z axis with d = −5–5 µm at λ = 0.75 and 0.5 µm, respectively. (c) and (d) Normalized |Ex|2 distribution at x = y = 0 along z when d = −2, 0, and 2 µm at λ = 0.75 and 0.5 µm, respectively. (e) and (f) z component of optical force Fz at x = y = 0 along z when d = −2, 0, and 2 µm at λ = 0.75 and 0.5 µm, respectively. (g) and (h) Displacement of |Ex|2 peaks on z when d = −5–5 µm at λ = 0.75 and 0.5 µm, respectively. w0 = 0.5 µm, dcore = 0.5 µm, dgap = 0.03 µm, θx(y) = 0.
Fig. 4.
Fig. 4. (a) Normalized |Ex|2 field distribution at x = y = 0 along the z-axis at λ = 0.3–1.3 µm, at w0 = 0.6 µm, θx(y) = 0, d = 0, in the bowtie core capillary with dcore = 0.5 µm, dgap = 0.03 µm. (b), (c) Normalized |Ex|2 distribution and Fz distribution at x = y = 0 along z at λ = 0.5, 0.8, and 1.2 µm, respectively. (d) Fz distribution at x = y = 0 along z at λ = 0.7, 0.85 and 1 µm, respectively.
Fig. 5.
Fig. 5. (a), (b) Normalized |Ex|2 field distribution at x = y = 0 along the z-axis with w0 = 0.25–1 µm (from 0.5λ to 2λ) at λ = 0.5 µm, θ = 0, d = 0, in bowtie capillary with dcore = 0.25 µm, dgap = 0.03 µm. The solid lines indicate the normalized |Ex|2 = 0.5. (c), (d) Normalized |Ex|2 field distribution and Fz distribution at x = y = 0 along z at d = 0.5, 0.68, and 1 µm, respectively.
Fig. 6.
Fig. 6. (a), (b) Normalized |Ex|2 distribution at x = y = 0 along the z-axis at θx(y) = 0°–60°. (c), (d) Normalized |Ex|2 distribution and Fz distribution at x = y = 0 along z at θx = 0, 25 and 43°. λ = 0.5 µm, w0 = 0.5 µm, d = 0, θy = 0.
Fig. 7.
Fig. 7. Normalized |Ex|2 distribution on the xy cross section at (a) |Ex|2 peak (z = 2.85 µm), (b) |Ex|2 half (z = 2.46 µm), and (c) |Ex|2 bottom (z = 2.13 µm) at λ = 0.5 µm, w0 = 0.5 µm, and d = 0, θx(y) = 0. (d) Normalized |Ex|2 and (e) Fy along y axis at x = 0.
Fig. 8.
Fig. 8. (a) Normalized |Ex|2 distribution at x = y = 0 along z when d = −1, 0, and 1 µm at λ = 0.75 µm. (b) z component of optical force Fz at x = y = 0 along z when d = −1, 0, and 1 µm at λ = 0.75 µm, w0 = 0.5 µm, dcore = 0.25 µm, dgap = 0.03 µm, and θ = 0. (c) Normalized |Ex|2 distribution at x = y = 0 along z with Si3N4 and AlAs bowtie cores. The parameters of incident light and shape of Si3N4 bowtie cores are the same as in Fig. 2(b) at d = 0.
Fig. 9.
Fig. 9. Potential well of trapping a 20 nm particle by Si3N4 bowtie cores. (a) The potential well along z at x = y = 0 when d = −2, 0, and 2 µm. (b) The potential well along y at x = 0 and z positions of different |Ex|2 magnitude. The other situations are the same as in Fig. 3(d).
Fig. 10.
Fig. 10. (a) The instantaneous particle position shift Δzp during d shifts from −2 to 2 µm with incident power Pin = 136 mW and objective lens moving speed vl = −150, −375 and −1000 µm/s. (b) The particle position shift Δzp at the moment when d shifts to 2 µm with a dependency on vl and input power Pin. The initial status is assumed as that the particle is trapped at z = 8.2 µm at d = −2 µm. The other situations are the same as in Fig. 3(d).

Tables (1)

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Table 1. Symbols and values of the parameters

Equations (4)

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F = S T n d S
T i j = ε E i E j + μ B i B j 1 2 ( ε E 2 + μ H 2 ) δ i j
F d r a g = 3 π d p η v p
F B r = R 6 π k B T d p η Δ t
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