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Conferences > PSHB > 1991 > ThD > ThD5

Spectral Holes Under Pressure: Proteins and Glasses

J. Zollfrank and J. Friedrich

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Abstract

Pressure tuning of spectral holes /1/ provides, in a way, a link between gas–phase and solid state spectroscopy. Generally speaking, the shift of a spectral hole under isotropic pressure conditions, allows for a determination of three system parameters. These are: the vacuum frequency νvac of the molecular probe, the solvent shift νs which the probe experiences when embedded into a lattice and the compressibility κ of the host material.

© 1991 Optical Society of America

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