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Mapping of molecular docking of organic cations on negatively charged polymers by picosecond time resolved fluorescence spectroscopy.

Ehud Pines, Dina Pines, Y. Zhao, Jacob Cohen, Vitally Khutorsky, and Zvi Priel

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Abstract

Picosecond time resolved spectroscopy is used to probe the binding between positively charged diaminostilbene derivatives and negatively charged polyions. Several binding modes of roughly equal stability but of different polarity and environment were found; implying a compensation mechanism between the hydrophobic and electrostatic interactions.

© 2000 Optical Society of America

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