Abstract
The real-time dynamics of the dissociative ionization of CF3I has been studied by femtosecond photoelectron-photoion coincidence imaging. With coincidence imaging, correlated three dimensional scattering data of the recoiling electrons and the parent ion, CF3+ and I+ photofragment are obtained. With the photoelectron spectra of CF3I+ and the correlated images of the fragments, the different multi-photon dissociation pathways producing I+ are unravelled. Furthermore, molecular frame angular correlations are extracted for the CF3+ and I+ photofragments. These molecular frame angular correlations provide details on the photodissociation and ionization dynamics.
© 2002 Optical Society of America
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