Abstract
We numerically present that suppressing the unwanted resonance mode in a metal-insulator-metal (MIM) structure can be achieved by using a fine-structured gold grating. In each period of the grating, a sub-grating consisting of multiple gold strips is used. Investigations on a high quality-factor (Q-factor) MIM structure with the grating and usual gratings are carried out. Comparisons show that the proposed grating supports different diffraction orders. Moreover, the unwanted mode which exists in the case of usual gratings can be significantly suppressed, and the desired mode can be kept almost unchanged. Thus, the MIM structure with our grating shows a single resonance at ~3.9 μm with a high Q-factor (~260) and an ultra-narrow linewidth (~10 cm−1) over a broad spectral region. This study provides a simple and effective approach to selective manipulating the resonance modes in MIM structures, which is useful for design of mid-infrared narrowband filters, emitters, and absorbers.
© 2019 Optical Society of America under the terms of the OSA Open Access Publishing Agreement
1. Introduction
Resonances in subwavelength periodic structures have been studied extensively over the past decade. The excited resonance modes can be either plasmonic or photonic, which affect transmission, reflection, and absorption features of a structure [1,2]. By manipulating the excited resonance modes, a large variety of useful devices have been achieved, such as filters [3–11], selective emitters [12–14], absorbers [15–18], and modulators [19,20].
Typically, there are multiple spectral peaks/dips in the transmission or reflection spectrum, because multiple resonance modes can be excited according to the wavevector matching condition. This has been shown in many broadband or multi-spectral materials [21] and components [22–25]. However, the existence of multiple peaks/dips could be very disadvantageous for many applications requiring narrow operating bandwidth. For example, in high-resolution spectroscopic sensing and filtering, the unwanted spectral peaks/dips will significantly increase the background complexity and decrease the accuracy.
Most of previous studies have tried their best to design a structure and obtain a spectral response peak/dip with desired linewidth. However, there is little research on how to selectively suppress the unwanted peaks/dips. For example, Zhong et al. proposed a dielectric grating structure with an ultra-narrow transmission dip in the mid-infrared region, but two weaker side dips were shown [26]. Zhang et al. presented a gold grating structure with a narrow main peak in the near-infrared region, but a weaker side peak was shown [27]. Wang et al. proposed a hybrid metal-dielectric structure with single reflection peak across the 1-5 μm wavelength range [28].
Our attention is focused on ultra-narrowband mid-infrared (mid-IR) notch filters, since they are very useful for many imaging or detection applications [26]. To achieve this, it is very convenient to employ MIM structures because they have been widely used to realize perfect absorption. However, MIM structures in the literature generally have low Q-factors (<100) owing to the intrinsic loss of metals. If they are used in the mid-IR, the low Q-factors could lead to a large operating bandwidth. This is disadvantageous for narrowband applications. Moreover, as mentioned above, the suppression of the unwanted stopband is of particular important, and is a challenge.
In this work, a geometric design for suppressing the unwanted resonance mode in a MIM structure is presented. We use a low-index and thick dielectric spacer to produce high Q-factor resonances. Since usual gratings lead to the unwanted resonance mode, we propose a fine-structured grating consisting of multiple gold strips in each unit cell. These gold strips are arranged into a sub-grating, which enables the proposed grating to be dual-periodic. In comparison with that of usual gratings, the use of our grating can significantly suppress the unwanted mode at ~2.65 μm and keep the desired mode at ~3.9 μm. Thus, the designed structure shows a single and high Q-factor spectral dip over a broad mid-infrared spectral region (2-5.5 μm). Although only numerical investigations were carried out, the device shows simple in structure and easy to fabricate.
2. Design and results
Figure 1 illustrates the investigated MIM structures and their performances. In Fig. 1(a), a MIM structure consisting of an Al2O3 layer between a usual gold grating and a bottom gold layer is shown. The period of the structure is . The width of the gold strip is . The thicknesses of the grating, the Al2O3 layer, and the bottom gold layer are respectively , , and . Figure 1(b) shows the MIM structure with our proposed grating, where two gold strips are periodically arranged in each unit cell. In other words, there is a sub-grating in each period of this MIM structure. The period of the sub-grating is . The other geometric parameters are exactly the same as those in Fig. 1(a) except . For discussion purposes, we use Eq. (1) to describe the two gratings:
Where is a positive integer, is the overall filling factor of the grating, is the filling factor of the sub-grating. Obviously, when and , the top grating is an usual grating as shown in Fig. 1(a). When and , the top grating will be a fine-structured grating as shown in Fig. 1(b).Reflection spectra were numerically studied by means of a finite-difference time-domain (FDTD) method. A two-dimensional (2D) computational region was considered, where periodic boundaries were used for the structure and perfectly matched layer (PML) absorbing boundaries were employed along the line of the incidence. Optical parameters of Au and Al2O3 were taken from [29].
In order to obtain a desired spectral dip at ~3.9 μm, we first investigate the structure shown in Fig. 1(a). Figure 1(c) shows the calculated reflection with the following parameters: = 3.7 μm, = 430 nm, = 110 nm, = 1.74 μm, and = 100 nm. According to Eq. (1), there are , and . A high-extinction resonance mode at 3.913 μm with a full-width at half-maximum (FWHM) linewidth of ~17 nm or ~11 cm−1 is clearly observed. This mode exhibits a Q-factor of ~230, which is much higher than most of MIM structures in the literature. The ultra-narrow linewidth is advantageous for narrowband filtering. However, a notable but unwanted mode at ~2.65 μm also exists, which is disadvantages for narrowband filtering. To study if this unwanted mode can be eliminated, a parametric sweep of , , and has been made (not shown). However, the results indicate that it is always significant.
Figure 1(d) shows the calculated reflection associated with Fig. 1(b). The geometric parameters are: = 2, = 925 nm, = 352 nm. In this case, there are and according to Eq. (1). The other parameters are identical with those above. There is only a single stopband at ~3.933 μm with a FWHM linewidth of ~15 nm or ~9.7 cm−1, corresponding to a Q-factor of ~262. Thus, the MIM structure with our proposed grating shows a single reflection dip at the desired wavelength and a high background reflection (>90%) over an ultra-broad spectral region (2-5.5 μm). The narrow stopband and remarkable decrease in sideband complexity would be very useful for narrowband filtering. The results suggest that the desired mode can be well kept and the unwanted mode can be significantly suppressed by using the proposed grating. Although the spectral location of the desired mode exhibits a slight redshift in comparison with that of Fig. 2(c), the Q-factor gets even higher. The redshift effect will be explained in Section 4.
3. Physical mechanism
At first, in order to understand the high Q-factor, the and field distributions at and associated with Figs. 1(c) and 1(d) are represented in Fig. 2. It is observed that a large portion of resonant energy is confined in the Al2O3 layer. The reason is that the Al2O3 layer has a relatively low refractive index (~1.7) and large thickness (1.74 μm). Moreover, the optical loss of Al2O3 is small in the investigated wavelength range. These lead to a relatively low loss of the resonance mode [30]. Thus, the investigated MIM structures show a high Q-factor.
It should be noted that the use of a thinner Al2O3 layer seems to show an almost the same linewidth as our structure, as presented in [30]. However, we would find that the Q-factor of our structure is nearly an order of magnitude larger that in [30]. In fact, using a thinner Al2O3 layer in our structure can also realize the desired spectral dip at ~3.9 μm. If doing so, the Q-factor will decrease significantly.
Then, we show that how the MIM structure with our grating (see Fig. 1(b)) can suppress the unwanted mode at ~2.65 μm and keep the desired mode at ~3.9 μm. Figure 3 shows the main diffracted rays in the investigated MIM structures based on geometric optics. For the MIM structure with an usual grating (see Fig. 1(a)), the TM-polarized incidence is diffracted into 5 different orders (−2, −1, 0, + 1, + 2) after passing through the top grating, as illustrated in Fig. 3(a). The in-plane wavevectors of these diffracted orders can be written as (except the 0th order):
where and are the wavevector and angle of the incidence, respectively. Resonances occur when the diffracted orders couple to the planar plasmonic modes. These processes should satisfy the wavevector matching condition: where is the in-plane wavevector of the plasmonic mode excited by certain diffraction order. According to Eqs. (2-5), there are and at normal incidence ().For the MIM structure with our proposed grating (see Fig. 1(b)), the incident beam is diffracted into 3 different orders (−1, 0, + 1) after passing through the grating, as illustrated in Fig. 3(b). Only Eqs. (2) and (4) should be considered in this case. At normal incidence, the resonance wavelength is simply determined by .
The existence of only 3 different orders (−1, 0, + 1) can be attributed to the dual-periodic structure of our grating. Compared with an usual grating, it supports different diffraction orders [31]. There are slits with different widths in our grating, from which the diffracted rays can destructively interfere with each other. To validate this, we calculated spectral responses of the structures shown in Figs. 1(a) and 1(b) after removing the bottom gold layers. The results are shown in Fig. 4. We see that there are abrupt changes in the transmission and reflection spectra. The abrupt changes are associated with the diffraction effect of the grating. Compared with those in Fig. 4(a), a reduced number of abrupt changes in Fig. 4(b) suggests that our proposed grating supports fewer diffraction orders.
Furthermore, a detailed comparison between Figs. 4(a), 4(b) and Figs. 1(c), 1(d) was carried out. It is indicated that the abrupt changes marked by the red and blue rectangles in Fig. 4 are associated with the desired and unwanted modes, respectively. The abrupt change marked by the blue rectangle in Fig. 4(a), which is associated with the unwanted mode, disappears in Fig. 4(b). This implies that the unwanted mode is suppressed by using our grating. The spectral location of the abrupt change marked by the red rectangle in Fig. 4(a), which is associated with the desired mode, shows an almost unchanged property in Fig. 4(b). This implies that the desired mode can be kept by using our grating. The other abrupt changes in Fig. 4 are associated with the tiny reflection dips in Fig. 1(c) and 1(d). The blue shifts of these abrupt changes are due to the removal of the bottom gold layers.
The analysis above is consistent with the field distributions at the resonance wavelengths shown in Fig. 2, which confirms the suppression of the unwanted resonance mode based on our grating.
4. Discussion
The suppression can also be realized by using more gold strips in the sub-grating. To show this, we further increase the value in Eq. (1), and then optimize the grating parameters. In the case of each value, we just need to optimize and . The other structure parameters are the same as those above: = 3.7 μm, = 110 nm, = 1.74 μm, and = 100 nm. Figure 5 shows the calculated reflection spectra, where the results in Figs. 1(c) and 1(d) are also plotted for comparison. Table 1 lists the optimized grating parameters, where those associated with and are also shown. Note that simulations of the reflection for were not carried out, because in those cases the gaps between the gold strips would be too narrow to fabricate.
Compared with the case of (i.e. an usual grating), the unwanted mode is observed to be significantly suppressed provided that , as shown in Fig. 5. In addition, the FWHM or Q-factor of the desired mode is almost unchanged in the cases of various values. This is because the thickness of the Al2O3 layer is kept unchanged in these calculations. However, the spectral location of the desired mode exhibits a slight redshift as increases. The redshift can be understood as follows.
According to Eqs. (2) and (4), there is:
where is effective refractive index of the desired mode. is mainly determined by the arrangement of the gold strips because all the other parameters do not change in these calculations. The arrangement of the gold strips in each unit cell is governed by Eq. (1), based on which we obtain:where denotes the ratio of gold in each period of the grating. In Table 1, it is clearly shown that increases as increases. However, we should note that the grating layer is relatively thin in comparison the investigated MIM structure. This increase in could only lead to a small increase in , which results in the slight redshift according to Eq. (6).Then, based on the MIM structure shown in Fig. 1(b), we studied the reflection features by independently varying the structure parameters. It must be noted that some parameters are correlated. The calculated results are shown in Fig. 6.
In Fig. 6(a), it is seen that the overall filling factor significantly affects the suppression of the unwanted resonance mode at ~2.65 μm. However, the other geometric parameters presented in Figs. 6(b)-6(e) show relatively weaker effects. In order to understand these results, we first determine the widths of the gold slits in our grating according to Eq. (1), they are:
where and are respectively the widths of the wider and narrower slits. Based on the data in Table 1, we know that is comparable to and is much smaller than 2.65 μm. When , these slits result in a destructive interference of the diffracted rays. However, as increases or decreases, increases or decreases more quickly than . The interference effect will be affected in the case of larger or smaller , which enables the diffracted rays to coupe to the plasmonic mode and the unwanted spectral dip to be notable.This effect is not so significant when adjusting the other parameters, because there are only small (Fig. 6(b) and 6(e)) or even no (Figs. 6(c) and 6(d)) changes in the widths of gold slits. However, the thickness of the Al2O3 layer has a distinct effect on the plasmonic modes. The change in Al2O3 layer thickness could enable the coupling between the plasmonic modes and the diffracted rays at other wavelengths, as shown in Fig. 6(d).
As for the desired mode, slight redshifts are observed in Figs. (a-c) when increasing , , . According to Eq. (7), independently increasing or indicates that the ratio of gold in each period of the grating increase. As a result, the effective refractive index in Eq. (6) increase, leading to the slight redshift of the desired mode. It is similar when increasing . However, the redshifts are notable when increasing the Al2O3 layer thickness or the structure period , as shown in Figs. 6(d) and 6(e). According to Eq. (6), this is easy to understand.
The FWHM or Q-factor is seen to increase or decrease dramatically with the increase of in Fig. 6(b), whereas it is not in Fig. 6(a) or Figs. 6(c)-6(e). Based on the field distributions at-resonance shown in Fig. 2(c), we would explain that the gap between the two gold strips will decrease quickly as increases. Owing to the loss at the gold ridges, a narrower gold slits can significantly increase the loss of the desired mode. However, the increase in the other parameters would not narrow the gold slits so quickly and increase the loss of the desired mode so significantly.
In comparison with , , and (Figs. 6(a), 6(c) and 6(e)), it is shown that the intensity extinction is more sensitive to and (Figs. 6(b) and 6(d)). In fact, the change in each of these parameters affects the intensity extinction of the desired mode, because the desired spectral dip results from the coupling between the ( ± 1) diffraction orders and the plasmonic mode. The intensity extinction is mainly determined by the coupling strength between them. The results indicate that the filling factor of the sub-grating and the thickness of the Al2O3 layer thickness should be optimized carefully in order to obtain a high extinction at the desired wavelength.
In addition, we calculated the reflection spectra of our MIM structure shown in Fig. 1(b) at different angles of incidence. The results are shown in Fig. 7. Obviously, the desired spectral dip splits under oblique incidence. This can be attributed to the guided-mode resonance effect according to Eqs. (2) and (4). At oblique incidence, i.e., , the wavevector norms of and are different, resulting in two different resonance wavelengths and . The phenomenon has also been shown in dielectric grating based guided-mode resonance filters [26]. Despite this, the splitting effect could be useful. The reflection features can be tuned by rotating the MIM structure with respect to the incidence. From this point of view, the results in Fig. 7 indicate that a tuning range of ~400 nm can be achieved by a 5° rotation.
5. Conclusion
In summary, we have presented that suppression of the unwanted resonance mode in a MIM structure can be achieved by designing the grating layer. The investigated MIM structure uses a low-index and relatively thick dielectric layer to realize high Q-factor resonances. Since the unwanted spectral dip at ~2.65 μm exists when using usual gratings in the MIM structure, we propose a fine-structured grating and use it to suppress the unwanted resonance mode. The proposed grating consists of multiple gold strips in each unit cell, which are arranged to form a sub-grating. Thus the grating shows a dual-period feature, which enables it to support different diffraction orders. Compared with the case of usual gratings, our FDTD simulations reveal that using the proposed grating can significantly suppress the unwanted resonance mode and keep the desired resonance mode at ~3.9 μm. By varying the various structure parameters, we carried out investigations on their influences. For suppressing the unwanted mode, it is suggested that the overall filling factor should be controlled first. For keeping the desired mode, we also need to design the filling factor of the sub-grating and the thickness of the dielectric layer carefully. Based on the design, the MIM structure shows only a single reflection dip at ~3.9 μm with ~10 cm−1 linewidth and >90% background reflection across the 2-5.5 μm wavelength range. Although the MIM structure is sensitive to the angle of incidence, the design will be useful for many mid-IR applications such as narrowband filtering, selective emitting, and narrowband perfect absorption.
Funding
National Natural Science Foundation of China (NSFC) (60907003, 61671455, 61805278); Program for New Century Excellent Talents in University (NCET) (NCET-12-0142); Natural Science Foundation of Hunan Province of China (13JJ3001); China Postdoctoral Science Foundation (2018M633704).
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