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Real-time monitoring of toxic CS2 with high concentrations using a suitable terahertz photonic crystal fiber

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Abstract

Detection of toxic carbon disulfide (${{\rm CS}_2}$) at high concentration, arising due to heavy industrial utilities, is an essential requirement for a sustainable ecosystem and healthcare. However, research and development of appropriate sensor devices to monitor a very high concentration of ${{\rm CS}_2}$ are lacking. We design a polyethylene (PE) photonic crystal fiber (PCF) consisting of two interpenetrating periodic hexagonal lattices of teflon inclusions and air holes in the cladding, which can monitor ambient ${{\rm CS}_2}$ with extremely high precision in a wide concentration range. Here, we measure the time delay difference (TDD) associated with the difference between group velocities of the two supported modes due to changes in ${{\rm CS}_2}$ concentration in the prescribed holes. For a 10 cm long variant of the designed PCF operating at 0.75 THz frequency, we observe a linearly increasing TDD variation from ${\sim}{2}$ to 13 ps due to change in ${{\rm CS}_2}$ concentration from 17 to 50%. However, when the ${{\rm CS}_2}$ concentration exceeds the 50% range, we observe decreasing TDD characteristics. In this high concentration regime (${\gt}{50}\%$), we monitor ${{\rm CS}_2}$ by analyzing second mode loss (SML) variation due to concentration change (at 0.98 THz frequency), where SML increases up to ${\sim}{30}\;{\rm dB}$ for ${\sim}{100}\%$ ambient ${{\rm CS}_2}$ concentration. Here, we achieve a high concentration sensitivity where a variation of 1.6 dB SML is observed with a unit concentration change of ${{\rm CS}_2}$. The proposed scheme has an immense potential to boost the technologies for high-precision gas monitoring devices.

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Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

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