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Luminescent Properties of Lamellar Solids Derived from Hydrogen Uranyl Phosphate and Cr(III) Werner Complexes

Michael M. Olken, Carla M. Verschoor, and Arthur B. Ellis

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Abstract

The emissive layered solid HUO2PO4·4H2O (HUP) readily undergoes intercalative ion exchange reactions with a variety of cationic species, leading, in many cases, to substituted lamellar materials which retain the luminescence characteristic of UO22+.1 We have recently carried out such substitution reactions using the following Cr(III) Werner complexes: Cr(NH3)63+; Cr(NH3)5(H2O)3+; Cr(ethylenediamine)33+ (Cr(en)33+); Cr(2,2′-bipyridine)33+(Cr(bpy)33+); and Cr(urea)63+.

© 1984 Optical Society of America

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