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Kinetics of gradual degradation in semiconductor lasers

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Abstract

Gradual degradation in semiconductor lasers is caused by the creation and migration of point defects which require jumping of atoms from their initial position to disordered ones (with activation energy Ea of a few electron volts). The injection of a nonequilibrium electron-hole plasma may increase the probability of structural changes and reduce their activation energy by δEFcFv through nonradiative recombination1 (Fc and Fv are the quasi-Fermi levels). Such enhancement is possible only if the recombination is synchronized with the atom jump event, and the released energy δE is localized around this atom. In the present model, such synchronization is inherent: the fluctuating atom forms a transient point defect which behaves as a nonradiative recombination center of lifetime δτ ≃ 10−13 − 10−12s. Free carriers are trapped at these centers leading to synchronous release of localized energy δE. This model is based on the kinetic many-body theory of short-lived large energy fluctuations of atoms.2,3 The laser degradation rate K is given by K = Ko exp[−(EaδE)/kT] with Ko and δE expressed in terms of the laser parameters (carrier concentration, energy gap, defect concentration, etc.) Calculated laser lifetimes are in good agreement with experimental data.

© 1988 Optical Society of America

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