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VUV and UV luminescence spectra of rare earth activated ions in LiYF4 and LiLuF4 single crystals

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Abstract

The allowed radiative interconfigurational d-f transitions of the rare earth ions in the wide band gap dielectric crystals offers the possibility that these materials can be used for generating coherent VUV and UV radiation when they are pumped with F2 molecular lasers at 157 nm. Therefore the search for new rare earth activated wide band gap dielectric crystals for potential VUV and UV laser sources is of great importance. We report here on the laser induced fluorescence spectroscopic features of the rare earth trivalent ions of Nd, Ho, Tm, Tb, Pr, Er in LiYF4, and LiLuF4 host dielectric crystals in the VUV and UV region of the spectrum under laser pumping of these crystals with the F2 molecular laser at 157 nm.

© 1992 Optical Society of America

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