Energy Flow from Highly Excited CH Overtones in Benzene and Alkanes

E. L. Sibert; J. S. Hutchinson; J. T. Hynes; W. P. Reinhardt

doi:10.1364/UP.1984.ThA1

Topical Meeting on Ultrafast Phenomena
Technical Digest Series (Optica Publishing Group, 1984),
paper ThA1
•https://doi.org/10.1364/UP.1984.ThA1

Energy Flow from Highly Excited CH Overtones in Benzene and Alkanes

E. L. Sibert, J. S. Hutchinson, J. T. Hynes, and W. P. Reinhardt

International Conference on Ultrafast Phenomena 1984

Monterey, California United States
12–15 June 1984
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Chemistry II (ThA)

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E. L. Sibert, J. S. Hutchinson, J. T. Hynes, and W. P. Reinhardt, "Energy Flow from Highly Excited CH Overtones in Benzene and Alkanes," in Topical Meeting on Ultrafast Phenomena, Technical Digest Series (Optica Publishing Group, 1984), paper ThA1.

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Abstract

Simple classical and quantal models of the ultrarapid ( 50 to 250 fs) flow of energy from CH (CD) overtones in benzene (perdeuterobenzene) and in terminal alkyl methyl groups are shown to account for experimental variation in linewidths, including isotopic effects.

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