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Photochemistry of a retinal protonated Schiff-base analogue mimicking the opsin shift of bacteriorhodopsin

Oshrat Bismuth, Noga Friedman, Mudi Sheves, and Sanford Ruhman

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Abstract

Photochemistry of retinal protonated Schiff-base analogue mimicking opsin shift of bacteriorhodopsin is studied. Results rule out correlations between BR’s absorption red shifting and internal conversion catalysis. Indications for the involvement of multiple excited states uncovered.

© 2006 Optical Society of America

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