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Ultrafast Electron Dynamics in C6F6/Cu(111) after a Localized or Delocalized Excitation

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Abstract

Comparing optical and core-hole excitation, we study relaxation dynamics of excited electrons at C6F6/Cu(111) interfaces. The pronounced tenfold difference in relaxation times is attributed to electron transfer across the interface and intra-molecular electron delocalization, respectively.

© 2006 Optical Society of America

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