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Gold Rush in Dynamics? Time-resolved Ion Spectroscopy Reveals Ultrafast Processes in Isomorphic, Ligated Ag/Au Coinage Metal Dimers

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Ultrafast electronic dynamics and UV absorption of phosphine–ligated (L) coinage metal complexes [Ag2(L)2]2, [AgAu(L)2]2+ and [Au2(L)2]2+ reveal the influence of intermetallic interaction on electronic states. Isomorphic exchange by AuI presumably accelerates ISC rate.

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