Obtaining the spectroscopic quality factor through the luminescent thermometry in 50Li2O · 45B2O3 · 5Al2O3 glasses doped with Nd3+ and fluorides

André S. Laia; André S. Laia; André S. Laia; José Felix N.; José Felix N.; Antonio C. Brandão-Silva; Antonio C. Brandão-Silva; José J. Rodrigues; José J. Rodrigues; Marcos A. C. dos Santos; Noelio O. Dantas; Anielle C. A. Silva; Márcio A. R. C. Alencar; Márcio A. R. C. Alencar

doi:10.1364/AO.476882

Applied Optics
Vol. 62,
Issue 8,
pp. C21-C29
(2023)
•https://doi.org/10.1364/AO.476882

Obtaining the spectroscopic quality factor through the luminescent thermometry in 50Li₂O · 45B₂O₃ · 5Al₂O₃ glasses doped with Nd³⁺ and fluorides

André S. Laia, José Felix N., Antonio C. Brandão-Silva, José J. Rodrigues, Marcos A. C. dos Santos, Noelio O. Dantas, Anielle C. A. Silva, and Márcio A. R. C. Alencar

Not Accessible

Your library or personal account may give you access

Get PDF
Email
Share
Get Citation
Copy Citation Text
André S. Laia, José Felix N., Antonio C. Brandão-Silva, José J. Rodrigues, Marcos A. C. dos Santos, Noelio O. Dantas, Anielle C. A. Silva, and Márcio A. R. C. Alencar, "Obtaining the spectroscopic quality factor through the luminescent thermometry in 50Li₂O · 45B₂O₃ · 5Al₂O₃ glasses doped with Nd³⁺ and fluorides," Appl. Opt. 62, C21-C29 (2023)

Export Citation
- BibTex
- Endnote (RIS)
- HTML
- Plain Text
Citation alert
Save article

Check for updates

Related Topics
Table of Contents Category
- Optical Devices, Sensors, and Detectors
Optics & Photonics Topics
?

The topics in this list come from the Optics and Photonics Topics applied to this article.

About this Article
History
- Original Manuscript: September 28, 2022
- Revised Manuscript: December 11, 2022
- Manuscript Accepted: December 15, 2022
- Published: January 17, 2023
Virtual Issues
Applied Optics Latin America Optics and Photonics 2022 (2022)

Abstract

Lithium-boron-aluminum (LBA) glasses doped with ${{\rm Nd}^{3 +}}$ and fluorides were produced. From the absorption spectra, their Judd–Ofelt intensity parameters, ${\Omega _{2,4,6}},$ and spectroscopic quality factors were calculated. Exploiting their near infrared temperature dependent luminescence, we investigated their potential for optical thermometry based on the luminescence intensity ratio (LIR) methodology. Three LIR schemes were proposed, and relative sensitivity values up to ${3.57}\;{\pm}\;{0.06}\;\% {{\rm K}^{- 1}}$ were obtained. From the temperature dependent luminescence, we alternatively calculated their corresponding spectroscopic quality factors. The results indicated that ${{\rm Nd}^{3 +}}$-doped LBA glasses are promising systems for optical thermometry and as gain mediums for solid-state lasers.

Full Article | PDF Article

More Like This

Upconversion luminescence properties and optical thermometry based on non-thermal coupling levels of Ho³⁺, Yb³⁺, and Tm³⁺ codoped 12CaO·7Al₂O₃ single crystals

Yunfei Qu and Rui Wang
Appl. Opt. 62(21) 5794-5800 (2023)

Luminescence intensity ratio thermometry based on combined ground and excited states absorptions of Tb³⁺ doped CaWO₄

Zhou Yuan, Peng Lixin, Tan Peng, and Zhang Zhiguo
Opt. Express 29(14) 22805-22812 (2021)

Effect of B₂O₃ and fluoride additions on the Yb³⁺ luminescence of an alumosilicate glass in the system Li₂O/MgO/Al₂O₃/SiO₂

Juliane Krey, Andreas Herrmann, Joachim Hein, Jörg Körner, Malte C. Kaluza, and Christian Rüssel
Opt. Mater. Express 6(8) 2662-2670 (2016)

Previous Article Next Article

Supplementary Material (1)

Name	Description
Supplement 1	Emission spectra and temperature uncertainties

Data availability

Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Figures (3)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Tables (4)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

Equations (14)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access Optica Member Subscription

	LBA2Nd		LBA2Nd10LiF		${L B A 2 N d 10 B a F}_{2}$		${L B A 2 N d 10 C a F}_{2}$		${L B A 2 N d 10 A l F}_{3}$		${L B A 2 N d 10 Z r F}_{4}$
Energy Level	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$
$^{4} F_{3 / 2}$	1.00	0.95	0.79	0.86	0.83	0.85	0.73	1.03	0.97	1.17	0.91	0.88
$^{4} F_{5 / 2} +^{2} H^{9 / 2}$	2.62	2.94	2.79	3.02	2.85	2.99	2.82	2.77	3.08	3.22	3.00	3.21
$^{4} F_{7 / 2} +^{4} S_{3 / 2}$	2.60	3.02	2.80	3.27	2.95	3.23	2.84	2.62	3.20	3.11	2.93	3.52
$^{4} F_{9 / 2}$	0.30	0.24	0.35	0.25	0.39	0.25	0.27	0.21	0.39	0.25	0.34	0.27
$^{4} G_{5 / 2} +^{2} G_{7 / 2}$	5.94	6.14	6.32	6.40	6.64	6.84	6.50	6.79	7.58	7.51	6.79	7.08
$^{2} K_{13 / 2} +^{4} G_{7 / 2} +^{4} G_{9 / 2}$	2.51	2.20	2.50	2.15	2.66	2.16	2.55	2.27	2.99	2.59	2.99	2.26
$^{2} K_{15 / 2} +^{2} G_{9 / 2} +^{2} D_{3 / 2} +^{2} G_{11 / 2}$	0.83	0.52	0.84	0.51	0.89	0.50	0.80	0.52	0.86	0.61	1.03	0.53
$^{2} P_{1 / 2} +^{2} D_{5 / 2}$	0.48	0.26	0.27	0.23	0.29	0.22	0.26	0.29	0.33	0.33	0.32	0.23
$^{4} D_{3 / 2} +^{4} D_{5 / 2} +^{2} I_{11 / 2} +^{4} D_{1 / 2}$	3.48	4.68	3.13	4.14	3.12	4.09	3.45	5.23	3.94	5.91	2.95	4.15
n	$1.52 \pm 0.02$		$1.43 \pm 0.03$		$1.38 \pm 0.03$		$1.45 \pm 0.01$		$1.34 \pm 0.01$		$1.47 \pm 0.02$
$Ω_{2}$	$1.16 \pm 0.09$		$1.51 \pm 0.11$		$1.78 \pm 0.14$		$1.34 \pm 0.12$		$1.56 \pm 0.12$		$1.75 \pm 0.16$
$Ω_{4}$	$1.93 \pm 0.15$		$1.78 \pm 0.12$		$1.82 \pm 0.15$		$2.33 \pm 0.16$		$2.83 \pm 0.20$		$1.71 \pm 0.15$
$Ω_{6}$	$2.18 \pm 0.17$		$2.55 \pm 0.11$		$2.61 \pm 0.21$		$1.95 \pm 0.18$		$2.51 \pm 0.20$		$2.68 \pm 0.24$
$Ω_{4} / Ω_{6}$	$0.89 \pm 0.10$		$0.70 \pm 0.08$		$0.70 \pm 0.08$		$1.19 \pm 0.14$		$1.13 \pm 0.12$		$0.64 \pm 0.08$

	I3/I2		I2/I1		I3/I1
	$C$	$α$	$C$	$α$	$C$	$α$
LBA2Nd	$0.1 \pm 0.1$	$1280 \pm 40$	$2.04 \pm 0.05$	$1740 \pm 10$	$2.0 \pm 0.1$	$2970 \pm 50$
LBA2Nd10LiF	$0.3 \pm 0.1$	$1350 \pm 20$	$2.07 \pm 0.07$	$1730 \pm 20$	$2.2 \pm 0.1$	$3020 \pm 50$
${L B A 2 N d 10 B a F}_{2}$	$0.5 \pm 0.1$	$1430 \pm 20$	$2.04 \pm 0.07$	$1730 \pm 20$	$2.4 \pm 0.1$	$3090 \pm 40$
${L B A 2 N d 10 C a F}_{2}$	$1.0 \pm 0.2$	$1250 \pm 30$	$2.06 \pm 0.06$	$1720 \pm 20$	$1.8 \pm 0.3$	$2860 \pm 90$
${L B A 2 N d 10 A l F}_{3}$	$0.01 \pm 0.08$	$1260 \pm 30$	$1.91 \pm 0.07$	$1700 \pm 20$	$1.8 \pm 0.1$	$2920 \pm 40$
${L B A 2 N d 10 Z r F}_{4}$	$0.1 \pm 0.1$	$1250 \pm 20$	$2.23 \pm 0.04$	$1800 \pm 10$	$2.3 \pm 0.1$	$3060 \pm 20$

Material	$λ$ (nm)	LIR	$Δ T$ (K)	$α$ (K)	Sr ( $% . K^{- 1}$ )	Reference
${N a Y F}_{4}$	830	I1/I1	273–423	86	0.10	[52]
${L a F}_{3}$	808	I1/I1	283–333	86	0.10	[9]
$Y_{2} O_{3}$	800	I1/I1	303–333	312	0.34	[53]
${G d}_{2} O_{3}$	580	I2/I1	288–323	1452	1.68	[3]
${Y V O}_{4}$	532	I2/I1	123–873	1460	1.59	[54]
${S r F}_{2}$	532	I2/I1	298–573	1511	1.69	[20]
${B i V O}_{4}$	750	I2/I1	310–573	1467	1.7	[55]
$Y_{2} {S i O}_{5}$	532	I3/I1	298–673	1899	2.89	[15]
${N a Y F}_{4}$	574.8	I3/I1	323–673	2.805	2.69	[2]
${L i B a P O}_{4}$	532	I3/I1	294–423	3223	2.54	[11]
${C a W O}_{4} : L i$	980	I3/I1	303–773	2377	2.58	[56]
(oxyfluoride) GC	980	I3/I1	323–573	2642	1.05	[57]
(oxyfluoride) GC	980	I3/I1	303–623	3010	0.42	[58]
(SBN) GC	532	I2/I1	300–700	1372	1.52	[59]
Fluorotellurite glass	514	I3/I1	300–700	2922	3.25	[17]
Fluoroindogallate glass	577	I3/I1	288–323	2601	3.14	[60]
P–K–Ba–Al glass	532	I2/I1	300–850	1630	1.80	[61]
LBA2Nd	532	I3/I1	294–373	$2970 \pm 50$	$3.4 \pm 0.1$	This work
LBA2Nd10LiF	532	I3/I1	294–373	$3020 \pm 50$	$3.5 \pm 0.1$	This work
${L B A 2 N d 10 B a F}_{2}$	532	I3/I1	294–373	$3090 \pm 40$	$3.58 \pm 0.04$	This work
${L B A 2 N d 10 C a F}_{2}$	532	I3/I1	294–373	$2860 \pm 90$	$3.3 \pm 0.1$	This work
${L B A 2 N d 10 A l F}_{3}$	532	I3/I1	294–373	$2920 \pm 40$	$3.4 \pm 0.1$	This work
${L B A 2 N d 10 Z r F}_{4}$	532	I3/I1	294–373	$3060 \pm 20$	$3.54 \pm 0.02$	This work

Material	$Ω_{4} / Ω_{6}$	M
LBA2Nd	$1.0 \pm 0.1$	$0.86 \pm 0.03$
LBA2Nd10LiF	$0.8 \pm 0.1$	$0.80 \pm 0.02$
${L B A 2 N d 10 B a F}_{2}$	$0.8 \pm 0.1$	$0.75 \pm 0.02$
${L B A 2 N d 10 C a F}_{2}$	$1.1 \pm 0.2$	$0.9 \pm 0.1$
${L B A 2 N d 10 A l F}_{3}$	$1.1 \pm 0.2$	$0.93 \pm 0.04$
${L B A 2 N d 10 Z r F}_{4}$	$0.8 \pm 0.1$	$0.76 \pm 0.02$
YAG [50]	0.54	0.54

	LBA2Nd		LBA2Nd10LiF		${L B A 2 N d 10 B a F}_{2}$		${L B A 2 N d 10 C a F}_{2}$		${L B A 2 N d 10 A l F}_{3}$		${L B A 2 N d 10 Z r F}_{4}$
Energy Level	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$	$f^{\exp}$	$f^{c a l}$
$^{4} F_{3 / 2}$	1.00	0.95	0.79	0.86	0.83	0.85	0.73	1.03	0.97	1.17	0.91	0.88
$^{4} F_{5 / 2} +^{2} H^{9 / 2}$	2.62	2.94	2.79	3.02	2.85	2.99	2.82	2.77	3.08	3.22	3.00	3.21
$^{4} F_{7 / 2} +^{4} S_{3 / 2}$	2.60	3.02	2.80	3.27	2.95	3.23	2.84	2.62	3.20	3.11	2.93	3.52
$^{4} F_{9 / 2}$	0.30	0.24	0.35	0.25	0.39	0.25	0.27	0.21	0.39	0.25	0.34	0.27
$^{4} G_{5 / 2} +^{2} G_{7 / 2}$	5.94	6.14	6.32	6.40	6.64	6.84	6.50	6.79	7.58	7.51	6.79	7.08
$^{2} K_{13 / 2} +^{4} G_{7 / 2} +^{4} G_{9 / 2}$	2.51	2.20	2.50	2.15	2.66	2.16	2.55	2.27	2.99	2.59	2.99	2.26
$^{2} K_{15 / 2} +^{2} G_{9 / 2} +^{2} D_{3 / 2} +^{2} G_{11 / 2}$	0.83	0.52	0.84	0.51	0.89	0.50	0.80	0.52	0.86	0.61	1.03	0.53
$^{2} P_{1 / 2} +^{2} D_{5 / 2}$	0.48	0.26	0.27	0.23	0.29	0.22	0.26	0.29	0.33	0.33	0.32	0.23
$^{4} D_{3 / 2} +^{4} D_{5 / 2} +^{2} I_{11 / 2} +^{4} D_{1 / 2}$	3.48	4.68	3.13	4.14	3.12	4.09	3.45	5.23	3.94	5.91	2.95	4.15
n	$1.52 \pm 0.02$		$1.43 \pm 0.03$		$1.38 \pm 0.03$		$1.45 \pm 0.01$		$1.34 \pm 0.01$		$1.47 \pm 0.02$
$Ω_{2}$	$1.16 \pm 0.09$		$1.51 \pm 0.11$		$1.78 \pm 0.14$		$1.34 \pm 0.12$		$1.56 \pm 0.12$		$1.75 \pm 0.16$
$Ω_{4}$	$1.93 \pm 0.15$		$1.78 \pm 0.12$		$1.82 \pm 0.15$		$2.33 \pm 0.16$		$2.83 \pm 0.20$		$1.71 \pm 0.15$
$Ω_{6}$	$2.18 \pm 0.17$		$2.55 \pm 0.11$		$2.61 \pm 0.21$		$1.95 \pm 0.18$		$2.51 \pm 0.20$		$2.68 \pm 0.24$
$Ω_{4} / Ω_{6}$	$0.89 \pm 0.10$		$0.70 \pm 0.08$		$0.70 \pm 0.08$		$1.19 \pm 0.14$		$1.13 \pm 0.12$		$0.64 \pm 0.08$

Anielle C. A. Silva	https://orcid.org/0000-0003-1959-2870
Márcio A. R. C. Alencar	https://orcid.org/0000-0003-1436-9901

Abstract

Supplementary Material (1)

Data availability

Cited By

Figures (3)

Tables (4)

Equations (14)

Applied Optics