Abstract

The infrared spectra of zinc formate dihydrate are presented for the region 1000 to 400 cm⁻¹ along with the laser-excited Raman spectra. With the use of the corresponding IR and Raman spectra for the deuterated and anhydrous samples and their temperature dependence (between 300 to 90 K), two sets of bands for the in-plane bending mode of formate ion and all the three librations of water have been identified corresponding to two types of formate and water in the unit cell. The large shift of the formate <i>v</i>₃ mode in going from the hydrate to the deuterate has been attributed to a dynamic interaction of this mode with the close-lying H₂O rocking mode.

Combination transitions due to stretching and librations of OH⁻ ions in LiNbO₃

László Kovács, Krisztián Lengyel, and Viktor Szalay
Opt. Lett. 36(18) 3714-3716 (2011)

Determination of deuteration level of K(H_1−xD_x)₂PO₄ crystal

Fafu Liu, Mingxia Xu, Baoan Liu, Xiping Chen, Lei Xie, Yuanhua Xia, Chengwei Wen, Lisong Zhang, Xin Ju, Guangai Sun, and Xun Sun
Opt. Mater. Express 6(7) 2221-2228 (2016)

Investigation of ablation efficiency during the pulsed laser ablation of a zinc metal target in a distilled water environment

Mohammad Rasoul Khodaverdi and Elnaz Irani
OSA Continuum 4(10) 2552-2564 (2021)

Relationship between defect formation by X-ray irradiation and thermally stimulated luminescence of binary zinc phosphate glasses

Hirokazu Masai, Go Okada, Noriaki Kawaguchi, and Takayuki Yanagida
Opt. Mater. Express 9(5) 2037-2045 (2019)

Structure, morphology, and nonlinear optical properties of orthorhombic α-Ca(HCOO)₂ single crystals

Shunli Wang, Pengfei Kong, Zijie Zhang, Hanlin Sun, Peigang Li, Ruipin Chen, Bing Gu, Goran Ungar, Xiaoping Wu, Lin Cheng, Xiaoyun Li, Daoyou Guo, and Weihua Tang
Opt. Mater. Express 8(8) 2238-2245 (2018)