Abstract
Resonance Raman spectra have recently been reported for a variety of biological materials including hemoglobin and cytochrome <i>c</i>. The resonance phenomenon leads to enhancement of intensity when molecules are excited by radiation of wavelength within that of an absorption band, and the effect provides a structural probe at low solution concentrations. We now report a resonance Raman study of cyanocobalamin (vitamin B<sub>12</sub>) in both solid and solution states together with a study of dicyanocobalamin and cyanoaquocobin-amide.
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