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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 27,
  • Issue 5,
  • pp. 394-394
  • (1973)

The Charge Transfer to Solvent (CTTS) Spectrum of Br In Molten Tetrabutylphosphonium Tetrabromometalates

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Abstract

Recently we reported that some of the charge-transfer bands of CoBr<sub>4</sub><sup>=</sup> which are ordinarily obscured by the absorption of Br<sup>−</sup> can be resolved in thin films of (Bu<sub>4</sub>P<sup>+</sup>)<sub>2</sub>CoBr<sub>4</sub><sup>=</sup>.<sup>1</sup> Apparently the concentration of free Br<sup>−</sup> is so small under these conditions that it permits the detection of CoBr<sub>4</sub><sup>=</sup> bands in the same region. Here we note that it is also possible to observe at least the first component of the absorption band of Br<sup>−</sup> by the same technique.

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