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Optica Publishing Group
  • Journal of Lightwave Technology
  • Vol. 39,
  • Issue 22,
  • pp. 7303-7306
  • (2021)

Optical Detection of Ammonia in Water Using Integrated Up-Conversion Fluorescence in a Fiberized Microsphere

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Abstract

A novel optical sensor for ammonia concentration in water is demonstrated using up-conversion (UC) fluorescence intensity ratio (FIR). The sensor element consists of (i) an Er3+-Yb3+ co-doped tellurite glass microsphere integrated inside a section of suspended tri-core hollow fiber (STCHF) and (ii) the pH indicator phenol red. When 980 nm pump is coupled into the microsphere, the Er3+ ions produce green and red UC emissions. Exposure to ammonia results in a strong increase in the 560 nm absorption of the phenol red, which acts as a filter for the green emission, while the red emission is unaffected. A simple linear relation between the FIR and the ammonia aqueous concentration has been established.

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