Abstract
The study presented here demonstrates the benefits of using a repeatability file for near infrared (NIR) spectroscopy calibration development. Calibrations were developed from rapeseed samples of a narrow moisture content (2.5–6.0%) and used on a validation set with an extended moisture content (3.6–13.0%). The elevated moisture content of the validation samples led to increased standard errors of prediction (SEP) for the calibrations predicting oil, protein, GSL and C18:1 content. Two methods were investigated to reduce the moisture sensitivity of the NIR spectroscopy calibrations: (a) the exclusion of water bands in the NIR spectral region during calibration development and (b) the use of a repeatability file as proposed by Westerhaus (1990). The increased SEPs could be decreased by up to 66% by either the exclusion of the water bands or the use of a repeatability file containing spectra of moist and dry samples. The best results were obtained with a repeatability file using spectra from a single sample. A spectral interpretation is given.
© 1998 NIR Publications
PDF Article
More Like This
Cited By
You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.
Contact your librarian or system administrator
or
Login to access Optica Member Subscription